94 research outputs found
Relating the thermodynamic arrow of time to the causal arrow
Consider a Hamiltonian system that consists of a slow subsystem S and a fast
subsystem F. The autonomous dynamics of S is driven by an effective
Hamiltonian, but its thermodynamics is unexpected. We show that a well-defined
thermodynamic arrow of time (second law) emerges for S whenever there is a
well-defined causal arrow from S to F and the back-action is negligible. This
is because the back-action of F on S is described by a non-globally Hamiltonian
Born-Oppenheimer term that violates the Liouville theorem, and makes the second
law inapplicable to S. If S and F are mixing, under the causal arrow condition
they are described by microcanonic distributions P(S) and P(S|F). Their
structure supports a causal inference principle proposed recently in machine
learning.Comment: 10 page
Thermodynamic efficiency of information and heat flow
A basic task of information processing is information transfer (flow). Here
we study a pair of Brownian particles each coupled to a thermal bath at
temperature and , respectively. The information flow in such a
system is defined via the time-shifted mutual information. The information flow
nullifies at equilibrium, and its efficiency is defined as the ratio of flow
over the total entropy production in the system. For a stationary state the
information flows from higher to lower temperatures, and its the efficiency is
bound from above by . This upper bound is
imposed by the second law and it quantifies the thermodynamic cost for
information flow in the present class of systems. It can be reached in the
adiabatic situation, where the particles have widely different characteristic
times. The efficiency of heat flow|defined as the heat flow over the total
amount of dissipated heat|is limited from above by the same factor. There is a
complementarity between heat- and information-flow: the setup which is most
efficient for the former is the least efficient for the latter and {\it vice
versa}. The above bound for the efficiency can be [transiently] overcome in
certain non-stationary situations, but the efficiency is still limited from
above. We study yet another measure of information-processing [transfer
entropy] proposed in literature. Though this measure does not require any
thermodynamic cost, the information flow and transfer entropy are shown to be
intimately related for stationary states.Comment: 19 pages, 1 figur
Complexity of decoupling and time-reversal for n spins with pair-interactions: Arrow of time in quantum control
Well-known Nuclear Magnetic Resonance experiments show that the time
evolution according to (truncated) dipole-dipole interactions between n spins
can be inverted by simple pulse sequences. Independent of n, the reversed
evolution is only two times slower than the original one. Here we consider more
general spin-spin couplings with long range. We prove that some are
considerably more complex to invert since the number of required time steps and
the slow-down of the reversed evolutions are necessarily of the order n.
Furthermore, the spins have to be addressed separately. We show for which
values of the coupling parameters the phase transition between simple and
complex time-reversal schemes occurs.Comment: Completely rewritten, new lower bounds on the number of time steps,
applications and references adde
A measure of majorisation emerging from single-shot statistical mechanics
The use of the von Neumann entropy in formulating the laws of thermodynamics
has recently been challenged. It is associated with the average work whereas
the work guaranteed to be extracted in any single run of an experiment is the
more interesting quantity in general. We show that an expression that
quantifies majorisation determines the optimal guaranteed work. We argue it
should therefore be the central quantity of statistical mechanics, rather than
the von Neumann entropy. In the limit of many identical and independent
subsystems (asymptotic i.i.d) the von Neumann entropy expressions are recovered
but in the non-equilbrium regime the optimal guaranteed work can be radically
different to the optimal average. Moreover our measure of majorisation governs
which evolutions can be realized via thermal interactions, whereas the
nondecrease of the von Neumann entropy is not sufficiently restrictive. Our
results are inspired by single-shot information theory.Comment: 54 pages (15+39), 9 figures. Changed title / changed presentation,
same main results / added minor result on pure bipartite state entanglement
(appendix G) / near to published versio
The Feasibility of High-Resolution Peripheral Quantitative Computed Tomography (HR-pQCT) in Patients with Suspected Scaphoid Fractures
Introduction: Diagnosing scaphoid fractures remains challenging. High-resolution peripheral quantitative computed tomography (HR-pQCT) might be a potential imaging technique, but no data are available on its feasibility to scan the scaphoid bone in vivo. Methodology: Patients (≥18 years) with a clinically suspected scaphoid fracture received an HR-pQCT scan of the scaphoid bone (three 10.2-mm stacks, 61-μm voxel size) with their wrist immobilized with a cast. Scan quality assessment and bone contouring were performed using methods originally developed for HR-pQCT scans of radius and tibia. The contouring algorithm was applied on coarse hand-drawn pre-contours of the scaphoid bone, and the resulting contours (AUTO) were manually corrected (sAUTO) when visually deviating from bone margins. Standard morphologic analyses were performed on the AUTO- and sAUTO-contoured bones. Results: Ninety-one patients were scanned. Two out of the first five scans were repeated due to poor scan quality (40%) based on standard quality assessment during scanning, which decreased to three out of the next 86 scans (3.5%) when using an additional thumb cast. Nevertheless, after excluding one scan with an incompletely scanned scaphoid bone, post hoc grading revealed a poor quality in 14.9% of the stacks and 32.9% of the scans in the remaining 85 patients. After excluding two scans with contouring problems due to scan quality, bone indices obtained by AUTO- and sAUTO-contouring were compared in 83 scans. All AUTO-contours were manually corrected, resulting in significant but small differences in densitometric and trabecular indices (<1.0%). Conclusions: In vivo HR-pQCT scanning of the scaphoid bone is feasible in patients with a clinically suspected scaphoid fracture when using a cast with thumb part. The proportion of poor-quality stacks is similar to radius scans, and AUTO-contouring appears appropriate in good- and poor-quality scans. Thus, HR-pQCT may be promising for diagnosis of and microarchitectural evaluations in suspected scaphoid fractures
Work extraction in the spin-boson model
We show that work can be extracted from a two-level system (spin) coupled to
a bosonic thermal bath. This is possible due to different initial temperatures
of the spin and the bath, both positive (no spin population inversion) and is
realized by means of a suitable sequence of sharp pulses applied to the spin.
The extracted work can be of the order of the response energy of the bath,
therefore much larger than the energy of the spin. Moreover, the efficiency of
extraction can be very close to its maximum, given by the Carnot bound, at the
same time the overall amount of the extracted work is maximal. Therefore, we
get a finite power at efficiency close to the Carnot bound.
The effect comes from the backreaction of the spin on the bath, and it
survives for a strongly disordered (inhomogeneously broadened) ensemble of
spins. It is connected with generation of coherences during the work-extraction
process, and we derived it in an exactly solvable model. All the necessary
general thermodynamical relations are derived from the first principles of
quantum mechanics and connections are made with processes of lasing without
inversion and with quantum heat engines.Comment: 30 pages, 6 figure
Empirical Determination of Bang-Bang Operations
Strong and fast "bang-bang" (BB) pulses have been recently proposed as a
means for reducing decoherence in a quantum system. So far theoretical analysis
of the BB technique relied on model Hamiltonians. Here we introduce a method
for empirically determining the set of required BB pulses, that relies on
quantum process tomography. In this manner an experimenter may tailor his or
her BB pulses to the quantum system at hand, without having to assume a model
Hamiltonian.Comment: 14 pages, 2 eps figures, ReVTeX4 two-colum
Protocol of the Healthy Brain Study: An accessible resource for understanding the human brain and how it dynamically and individually operates in its bio-social context
The endeavor to understand the human brain has seen more progress in the last few decades than in the previous two millennia. Still, our understanding of how the human brain relates to behavior in the real world and how this link is modulated by biological, social, and environmental factors is limited. To address this, we designed the Healthy Brain Study (HBS), an interdisciplinary, longitudinal, cohort study based on multidimensional, dynamic assessments in both the laboratory and the real world. Here, we describe the rationale and design of the currently ongoing HBS. The HBS is examining a population-based sample of 1,000 healthy participants (age 30-39) who are thoroughly studied across an entire year. Data are collected through cognitive, affective, behavioral, and physiological testing, neuroimaging, bio-sampling, questionnaires, ecological momentary assessment, and real-world assessments using wearable devices. These data will become an accessible resource for the scientific community enabling the next step in understanding the human brain and how it dynamically and individually operates in its bio-social context. An access procedure to the collected data and bio-samples is in place and published on https://www.healthybrainstudy.nl/en/data-and-methods. https://www.trialregister.nl/trial/795
Internal fixation treatments for intertrochanteric fracture: A systematic review and meta-Analysis of randomized evidence
The relative effects of internal fixation strategies for intertrochanteric fracture after operation remain uncertain. We conducted a systematic review and meta-Analysis of randomized controlled trials (RCTs) to address this important issue. We searched PubMed, EMBASE and CENTRAL for RCTs that compared different internal fixation implants in patients with intertrochanteric fracture at 6-month follow-up or longer. We ultimately included 43 trials enrolling 6911 patients; most trials were small in sample sizes and events. Their risk of bias was generally unclear due to insufficient reporting. Because of these, no statistically significant differences were present from most of the comparisons across all the outcomes, and no definitive conclusions can be made. However, a number of trials compared two commonly used internal fixation strategies, gamma nail (GN) and sliding hip screw (SHS). There is good evidence suggesting that, compared to SHS, GN may increase the risk of cut out (OR = 1.87, 95% CI, 1.08 to 3.21), re-operation (OR = 1.61, 95% CI, 1.02 to 2.53), intra-operative (OR = 3.14, 95% CI, 1.34 to 7.35) and later fractures (OR = 3.67, 95% CI, 1.37 to 9.83). Future randomized trials or observational studies that are carefully designed and conducted are warranted to establish the effects of alternative internal fixation strategies for intertrochanteric fracture
Description of quantum coherence in thermodynamic processes requires constraints beyond free energy
Recent studies have developed fundamental limitations on nanoscale thermodynamics, in terms of a set of independent free energy relations. Here we show that free energy relations cannot properly describe quantum coherence in thermodynamic processes. By casting time-asymmetry as a quantifiable, fundamental resource of a quantum state, we arrive at an additional, independent set of thermodynamic constraints that naturally extend the existing ones. These asymmetry relations reveal that the traditional Szilárd engine argument does not extend automatically to quantum coherences, but instead only relational coherences in a multipartite scenario can contribute to thermodynamic work. We find that coherence transformations are always irreversible. Our results also reveal additional structural parallels between thermodynamics and the theory of entanglement
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