125 research outputs found

    Stress-driven phase transformation and the roughening of solid-solid interfaces

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    The application of stress to multiphase solid-liquid systems often results in morphological instabilities. Here we propose a solid-solid phase transformation model for roughening instability in the interface between two porous materials with different porosities under normal compression stresses. This instability is triggered by a finite jump in the free energy density across the interface, and it leads to the formation of finger-like structures aligned with the principal direction of compaction. The model is proposed as an explanation for the roughening of stylolites - irregular interfaces associated with the compaction of sedimentary rocks that fluctuate about a plane perpendicular to the principal direction of compaction.Comment: (4 pages, 4 figures

    Constraints on Earth system functioning at the Paleocene-Eocene Thermal Maximum from the marine silicon cycle

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    The Paleocene‐Eocene Thermal Maximum (PETM, ca. 56 Ma) is marked by a negative carbon isotope excursion (CIE) and increased global temperatures. The CIE is thought to result from the release of 13C‐depleted carbon, although the source(s) of carbon and triggers for its release, its rate of release, and the mechanisms by which the Earth system recovered are all debated. Many of the proposed mechanisms for the onset and recovery phases of the PETM make testable predictions about the marine silica cycle, making silicon isotope records a promising tool to address open questions about the PETM. We analyzed silicon isotope ratios (δ30Si) in radiolarian tests and sponge spicules from the Western North Atlantic (ODP Site 1051) across the PETM. Radiolarian δ30Si decreases by 0.6‰ from a background of 1‰ coeval with the CIE, while sponge δ30Si remains consistent at 0.2‰. Using a box model to test the Si cycle response to various scenarios, we find the data are best explained by a weak silicate weathering feedback, implying the recovery was mostly driven by nondiatom organic carbon burial, the other major long‐term carbon sink. We find no resolvable evidence for a volcanic trigger for carbon release, or for a change in regional oceanography. Better understanding of radiolarian Si isotope fractionation and more Si isotope records spanning the PETM are needed to confirm the global validity of these conclusions, but they highlight how the coupling between the silica and carbon cycles can be exploited to yield insight into the functioning of the Earth system

    The Effects of Earthquakes and Fluids on the Metamorphism of the Lower Continental Crust

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    Rock rheology and density have first‐order effects on the lithosphere's response to plate tectonic forces at plate boundaries. Changes in these rock properties are controlled by metamorphic transformation processes that are critically dependent on the presence of fluids. At the onset of a continental collision, the lower crust is in most cases dry and strong. However, if exposed to internally produced or externally supplied fluids, the thickened crust will react and be converted into a mechanically weaker lithology by fluid‐driven metamorphic reactions. Fluid introduction is often associated with deep crustal earthquakes. Microstructural evidence, suggest that in strong highly stressed rocks, seismic slip may be initiated by brittle deformation and that wall‐rock damage caused by dynamic ruptures plays a very important role in allowing fluids to enter into contact with dry and highly reactive lower crustal rocks. The resulting metamorphism produces weaker rocks which subsequently deform by viscous creep. Volumes of weak rocks contained in a highly stressed environment of strong rocks may experience significant excursions toward higher pressure without any associated burial. Slow and highly localized creep processes in a velocity strengthening regime may produce mylonitic shear zones along faults initially characterized by earthquake‐generated frictional melting and wall rock damage. However, stress pulses from earthquakes in the shallower brittle regime may kick start new episodes of seismic slip at velocity weakening conditions. These processes indicate that the evolution of the lower crust during continental collisions is controlled by the transient interplay between brittle deformation, fluid‐rock interactions, and creep flow

    Earthquake nucleation in the lower crust by local stress amplification

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    Deep intracontinental earthquakes are poorly understood, despite their potential to cause significant destruction. Although lower crustal strength is currently a topic of debate, dry lower continental crust may be strong under high-grade conditions. Such strength could enable earthquake slip at high differential stress within a predominantly viscous regime, but requires further documentation in nature. Here, we analyse geological observations of seismic structures in exhumed lower crustal rocks. A granulite facies shear zone network dissects an anorthosite intrusion in Lofoten, northern Norway, and separates relatively undeformed, microcracked blocks of anorthosite. In these blocks, pristine pseudotachylytes decorate fault sets that link adjacent or intersecting shear zones. These fossil seismogenic faults are rarely >15 m in length, yet record single-event displacements of tens of centimetres, a slip/length ratio that implies >1 GPa stress drops. These pseudotachylytes represent direct identification of earthquake nucleation as a transient consequence of ongoing, localised aseismic creep

    Reaction mechanism for the replacement of calcite by dolomite and siderite: Implications for geochemistry, microstructure and porosity evolution during hydrothermal mineralisation

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    Carbonate reactions are common in mineral deposits due to CO2-rich mineralising fluids. This study presents the first in-depth, integrated analysis of microstructure and microchemistry of fluid-mediated carbonate reaction textures at hydrothermal conditions. In doing so, we describe the mechanisms by which carbonate phases replace one another, and the implications for the evolution of geochemistry, rock microstructures and porosity. The sample from the 1.95 Moz Junction gold deposit, Western Australia, contains calcite derived from carbonation of a metamorphic amphibole—plagioclase assemblage that has further altered to siderite and dolomite. The calcite is porous and contains iron-rich calcite blebs interpreted to have resulted from fluid-mediated replacement of compositionally heterogeneous amphiboles. The siderite is polycrystalline but nucleates topotactically on the calcite. As a result, the boundaries between adjacent grains are low-angle boundaries (<10°), which are geometrically similar to those formed by crystal–plastic deformation and recovery. Growth zoning within individual siderite grains shows that the low-angle boundaries are growth features and not due to deformation. Low-angle boundaries develop due to the propagation of defects at grain faces and zone boundaries and by impingement of grains that nucleated with small misorientations relative to each other during grain growth.The cores of siderite grains are aligned with the twin planes in the parent calcite crystal showing that the reactant Fe entered the crystal along the twin boundaries. Dolomite grains, many of which appear to in-fill space generated by the siderite replacement, also show alignment of cores along the calcite twin planes, suggesting that they did not grow into space but replaced the calcite. Where dolomite is seen directly replacing calcite, it nucleates on the Fe-rich calcite due to the increased compatibility of the Fe-bearing calcite lattice relative to the pure calcite. Both reactions are interpreted as fluid-mediated replacement reactions which use the crystallography and elemental chemistry of the calcite. Experiments of fluid-mediated replacement reactions show that they proceed much faster than diffusion-based reactions. This is important when considering the rates of reactions relative to fluid flow in mineralising systems

    Structures Related to the Emplacement of Shallow-Level Intrusions

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    A systematic view of the vast nomenclature used to describe the structures of shallow-level intrusions is presented here. Structures are organised in four main groups, according to logical breaks in the timing of magma emplacement, independent of the scales of features: (1) Intrusion-related structures, formed as the magma is making space and then develops into its intrusion shape; (2) Magmatic flow-related structures, developed as magma moves with suspended crystals that are free to rotate; (3) Solid-state, flow-related structures that formed in portions of the intrusions affected by continuing flow of nearby magma, therefore considered to have a syn-magmatic, non-tectonic origin; (4) Thermal and fragmental structures, related to creation of space and impact on host materials. This scheme appears as a rational organisation, helpful in describing and interpreting the large variety of structures observed in shallow-level intrusions

    Mid-Crustal Focused Fluid Movement: Thermal Consequences and Silica Transport

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    Numerical models have been constructed to assess the thermal consequences and silica transport that would result if water released by regional metamorphic dehydration or cooling plutons were focused into large-scale (10 km) fracture zones. Two fracture zone model geometries have been considered, in one the fracture zone is planar, and in the other the fracture zone is radially symmetric. In both models dispersion and collection of fluids is simulated. The model results indicate that for planar or radially symmetric fracture zones, hydrothermal flow rates must approach 0.1 g/s (per m crack length) or 1 kg/s, respectively, to produce significant thermal effects. Given that regional metamorphic fluid fluxes are probably &lt; 10−9 kg/m2−s, generation of a thermal ano-maly by fluids released during metamorphic dehydration into a planar fracture zone requires an unrealistic degree of lateral flow (&gt;50 km). The collection area required to produce a detectable heating effect about a radially symmetric fracture zone is smaller (a radius of ∼ ∼ 15 km), but also implausibly large. These scales suggest tha
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