6,622 research outputs found

    Kinetic Theory for Electron Dynamics Near a Positive Ion

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    A theoretical description of time correlation functions for electron properties in the presence of a positive ion of charge number Z is given. The simplest case of an electron gas distorted by a single ion is considered. A semi-classical representation with a regularized electron - ion potential is used to obtain a linear kinetic theory that is asymptotically exact at short times. This Markovian approximation includes all initial (equilibrium) electron - electron and electron - ion correlations through renormalized pair potentials. The kinetic theory is solved in terms of single particle trajectories of the electron - ion potential and a dielectric function for the inhomogeneous electron gas. The results are illustrated by a calculation of the autocorrelation function for the electron field at the ion. The dependence on charge number Z is shown to be dominated by the bound states of the effective electron - ion potential. On this basis, a very simple practical representation of the trajectories is proposed and shown to be accurate over a wide range including strong electron - ion coupling. This simple representation is then used for a brief analysis of the dielectric function for the inhomogeneous electron gas.Comment: 30 pages, 5 figures, submitted to Journal of Statistical Mechanics: Theory and Experimen

    Evidence-Based Insurance Development for Nigeria’s Farmers: Briefing paper for Nigerian Federal Ministry of Agriculture and Rural Development (FMARD)-CCAFS Knowledge-Sharing Workshop, London, 27-28 January 2015

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    Agricultural insurance has been a feature in Nigeria for over two decades. The Federal Government has plans to expand agricultural insurance in the Country as part of several initiatives under the Agricultural Transformation Agenda (ATA). The Government wishes to extend crop insurance to those farmers benefiting from fertilizer subsidies under the Growth Enhancement Support Scheme (GES). The Government also wishes to implement weather index insurance (parametric insurance) in selected parts of the country susceptible droughts and floods. Experiences from index insurance initiatives worldwide provide important lessons for the development of crop index insurance in Nigeria. Experiences from India, Kenya, Rwanda, Ethiopia and Senegal suggest that there is demand for index insurance; that the bundling of insurance with key farm inputs e.g. improved seed and fertilizer, makes the insurance package more attractive to farmers; but that several challenges still to overcome, including data management, basis risk, logistical and client communication. CCAFS could play a role in working with the Federal Government to overcome some of these challenges

    Development of Monsoonal Asia Climate Risk Analysis Maprooms

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    The Asian monsoon plays a major role in the variability of seasonal temperature and precipitation and the sub-seasonal statistics of these and other climate variables.  Due to its considerable impact on the quality and quantity of agricultural output, there is an essential need for greater understanding of the historical risk associated with the Asian monsoon, with the ultimate goal being better climate risk analysis to support agricultural decision-making in South and South East Asia. In response to partner demand expressed by the CCAFS South Asia Regional Program, CCAFS worked with the International Research Institute for Climate and Society (IRI) to develop a suite of online “Maproom” tools for analyzing agriculturally important aspects of climate variability, based on gridded historical daily precipitation and temperature data. This report documents the rationale, development of, and use of the Monsoon Asia Historical Precipitation and Temperature Monitoring Maprooms. These tools aim to provide enough flexibility to support a demanding range of analysis and decision support needs. The weather factors that impact agriculture, and the analyses that are needed to support agricultural decision-making, vary considerably by location, production system and time of year. These Maprooms serve as the precursors to the later developed of the Daily Climate Analysis Maprooms

    A dynamical theory of homogeneous nucleation for colloids and macromolecules

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    Homogeneous nucleation is formulated within the context of fluctuating hydrodynamics. It is shown that for a colloidal or macromolecular system in the strong damping limit the most likely path for nucleation can be determined by gradient descent in density space governed by a nontrivial metric fixed by the dynamics. The theory provides a justification and extension of more heuristic equilibrium approaches based solely on the free energy. It is illustrated by application to liquid-vapor nucleation where it is shown that, in contrast to most free energy-based studies, the smallest clusters correspond to long wavelength, small amplitude perturbations.Comment: final version; 4 pages, 2 figure

    Density Functional Theory of Inhomogeneous Liquids: II. A Fundamental Measure Approach

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    Previously, it has been shown that the direct correlation function for a Lennard-Jones fluid could be modeled by a sum of that for hard-spheres, a mean-field tail and a simple linear correction in the core region constructed so as to reproduce the (known) bulk equation of state of the fluid(Lutsko, JCP 127, 054701 (2007)). Here, this model is combined with ideas from Fundamental Measure Theory to construct a density functional theory for the free energy. The theory is shown to accurately describe a range of inhomogeneous conditions including the liquid-vapor interface, the fluid in contact with a hard wall and a fluid confined in a slit pore. The theory gives quantitatively accurate predictions for the surface tension, including its dependence on the potential cutoff. It also obeys two important exact conditions: that relating the direct correlation function to the functional derivative of the free energy with respect to density, and the wall theorem.Comment: to appear in J. Chem. Phy
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