An equation of state for oxygen and nitrogen

Recent measurements of thermodynamic properties of oxygen and nitrogen have provided data necessary for development of a single equation of state for both fluids. Data are available in summary report and two-part detailed study on thermodynamic properties of oxygen and nitrogen. Same data are used to develop vapor-pressure equation and heat-capacity equation

The thermodynamic properties of oxygen and nitrogen. Part 2: Thermodynamic properties of oxygen from 100 R to 600 R with pressure to 5000 psia

An equation of state is presented for liquid and gaseous oxygen for temperatures from 100 R to 600 R and pressures to 5000 psia. The pressure-density-temperature data available from the published literature have been reviewed, and appropriate corrections have been applied to bring experimental temperatures into accord with the International Practical Temperature Scale of 1968. Representative comparisons of property values calculated from the equation of state to measured values are included to illustrate the accuracy of the equation of state. The coefficients of the equation of state were determined by a weighted least squares fit to selected published data, and simultaneously to isochoric heat capacity data, and to data which define the phase equilibrium for the saturated liquid and saturated vapor. The equation of state is estimated to be accurate for the liquid to within 0.1 percent in density, to within 0.2 percent for the vapor below the critical temperature and for states above the critical temperatures to 250 K, and within 0.1 percent for supercritical states at temperatures from 250 K to 300 K. The vapor pressure equation is accurate to within + or - 0.01 K between the triple point and the critical point

An equation of state for oxygen and nitrogen

Preliminary equations of state are presented for oxygen and nitrogen which provide accurate representations of the available P-density-T data for both fluids. The equation for nitrogen is applicable for temperatures from 70 K to 1300 K at pressures to 10,000 atmospheres, and the equation for oxygen for temperatures from 70 K to 323 K at pressures to 350 atmospheres. Deviations of calculated densities from representative experimental data are included. A volume-explicit equation of state for oxygen to be used in estimating density values in the range of applicability of the equation of state is also presented

The thermodynamic properties of oxygen and nitrogen. Part 1: Thermodynamic properties of nitrogen from 115 R to 3500 R with pressures to 150000 psia

An equation of state is presented for liquid and gaseous nitrogen for temperatures from 115 R to 3500 R and pressures to 150,000 psia. All of the pressure-density-temperature data available from the published literature have been reviewed, and appropriate corrections have been identified and applied to bring experimental temperatures into accord with the International Practical Temperature Scale of 1968. Comparisons of property values calculated from the equation of state to measured values are included to illustrate the accuracy of the equation in representing the data. The coefficients of the equation of state were determined by a weighted least squares fit to selected published data and, simultaneously, to constant volume data determined by corresponding states analysis from oxygen data, and to data which define the phase equilibrium criteria for the saturated liquid and saturated vapor. The methods of weighting the various data for simultaneous fitting are presented and discussed. The equation of state is estimated to be accurate to within 0.5 percent in the liquid region, to within 0.1 percent for supercritical isotherms up to 15,000 psia, and to within 0.3 percent from 15,000 to 150,000 psia

Rate theory for correlated processes: Double-jumps in adatom diffusion

We study the rate of activated motion over multiple barriers, in particular the correlated double-jump of an adatom diffusing on a missing-row reconstructed Platinum (110) surface. We develop a Transition Path Theory, showing that the activation energy is given by the minimum-energy trajectory which succeeds in the double-jump. We explicitly calculate this trajectory within an effective-medium molecular dynamics simulation. A cusp in the acceptance region leads to a sqrt{T} prefactor for the activated rate of double-jumps. Theory and numerical results agree

The thermodynamic properties of nitrogen from 65 to 2000 K with pressures to 10,000 atmospheres

An equation of state is presented for liquid and gaseous nitrogen for temperatures from 65 degrees K to 2000 degrees K and pressures to 10,000 atmospheres. All the pressure-density-temperature data available from published literature have been corrected and applied to bring experimental temperatures into accord with the International Practical Temperature Scale of 1968. The coefficients of the equation of state were determined by a weighted least squares fit to selected published pressure-density-temperature data. The methods of weighting the various data for simultaneous fitting are presented and discussed

The packing of two species of polygons on the square lattice

We decorate the square lattice with two species of polygons under the constraint that every lattice edge is covered by only one polygon and every vertex is visited by both types of polygons. We end up with a 24 vertex model which is known in the literature as the fully packed double loop model. In the particular case in which the fugacities of the polygons are the same, the model admits an exact solution. The solution is obtained using coordinate Bethe ansatz and provides a closed expression for the free energy. In particular we find the free energy of the four colorings model and the double Hamiltonian walk and recover the known entropy of the Ice model. When both fugacities are set equal to two the model undergoes an infinite order phase transition.Comment: 21 pages, 4 figure

A tree-decomposed transfer matrix for computing exact Potts model partition functions for arbitrary graphs, with applications to planar graph colourings

Combining tree decomposition and transfer matrix techniques provides a very general algorithm for computing exact partition functions of statistical models defined on arbitrary graphs. The algorithm is particularly efficient in the case of planar graphs. We illustrate it by computing the Potts model partition functions and chromatic polynomials (the number of proper vertex colourings using Q colours) for large samples of random planar graphs with up to N=100 vertices. In the latter case, our algorithm yields a sub-exponential average running time of ~ exp(1.516 sqrt(N)), a substantial improvement over the exponential running time ~ exp(0.245 N) provided by the hitherto best known algorithm. We study the statistics of chromatic roots of random planar graphs in some detail, comparing the findings with results for finite pieces of a regular lattice.Comment: 5 pages, 3 figures. Version 2 has been substantially expanded. Version 3 shows that the worst-case running time is sub-exponential in the number of vertice

On the universality of compact polymers

Fully packed loop models on the square and the honeycomb lattice constitute new classes of critical behaviour, distinct from those of the low-temperature O(n) model. A simple symmetry argument suggests that such compact phases are only possible when the underlying lattice is bipartite. Motivated by the hope of identifying further compact universality classes we therefore study the fully packed loop model on the square-octagon lattice. Surprisingly, this model is only critical for loop weights n < 1.88, and its scaling limit coincides with the dense phase of the O(n) model. For n=2 it is exactly equivalent to the selfdual 9-state Potts model. These analytical predictions are confirmed by numerical transfer matrix results. Our conclusions extend to a large class of bipartite decorated lattices.Comment: 13 pages including 4 figure

An integrable spin chain for the SL(2,R)/U(1) black hole sigma model

We introduce a spin chain based on finite-dimensional spin-1/2 SU(2) representations but with a non-hermitian `Hamiltonian' and show, using mostly analytical techniques, that it is described at low energies by the SL(2,R)/U(1) Euclidian black hole Conformal Field Theory. This identification goes beyond the appearance of a non-compact spectrum: we are also able to determine the density of states, and show that it agrees with the formulas in [J. Math. Phys. 42, 2961 (2001)] and [JHEP 04, 014 (2002)], hence providing a direct `physical measurement' of the associated reflection amplitude.Comment: 6 pages, 3 figures, in RevTeX. Corrected some typo