60 research outputs found
Collision photography: polarization imaging of atom-molecule collisions
We report differential scattering experiments on the laser excitation of Na+Mcollision pairs with M=Nâ‚‚, CO, Câ‚‚Hâ‚‚, and COâ‚‚. The collision event is probed by the laser polarization revealing geometric and electronic properties of the collision pair. The experimental data are compared to the results of a Monte Carlo trajectory simulation using ab initio quantum chemical data.Financial support from the Deutsche Forschungsgemeinschaft
and the Schweizerischer Nationalfond (Project No. 20-
065290.01) is gratefully acknowledged
Optimization of Generalized Multichannel Quantum Defect reference functions for Feshbach resonance characterization
This work stresses the importance of the choice of the set of reference
functions in the Generalized Multichannel Quantum Defect Theory to analyze the
location and the width of Feshbach resonance occurring in collisional
cross-sections. This is illustrated on the photoassociation of cold rubidium
atom pairs, which is also modeled using the Mapped Fourier Grid Hamiltonian
method combined with an optical potential. The specificity of the present
example lies in a high density of quasi-bound states (closed channel)
interacting with a dissociation continuum (open channel). We demonstrate that
the optimization of the reference functions leads to quantum defects with a
weak energy dependence across the relevant energy threshold. The main result of
our paper is that the agreement between the both theoretical approaches is
achieved only if optimized reference functions are used.Comment: submitte to Journal of Physics
Perception populaire de l'Etat-providence en Angleterre des années soixante à 2001
TOULOUSE2-BUC Mirail (315552102) / SudocTOULOUSE2-BUFR Anglais (315552208) / SudocSudocFranceF
Direct observation of atom-molecule collisions by optical excitation
We report experimental studies of atom-molecule collision complexes based on the optical excitation of collision pairs in a crossed beam experiment with differential detection
A theoretical study of the dissociative recombination of SH + with electrons through the 2 Î states of SH
International audienceA quantitative theoretical study of the dissociative recombination of SH+ with electrons has been carried out. Multireference, configuration interaction calculations were used to determine accurate potential energy curves for SH+ and SH. The block diagonalization method was used to disentangle strongly interacting SH valence and Rydberg states and to construct a diabatic Hamiltonian whose diagonal matrix elements provide the diabatic potential energy curves. The off-diagonal elements are related to the electronic valence-Rydberg couplings. Cross sections and rate coefficients for the dissociative recombination reaction were calculated with a stepwise version of the multichannel quantum defect theory, using the molecular data provided by the block diagonalization method. The calculated rates are compared with the most recent measurements performed on the ion Test Storage Ring (TSR) in Heidelberg, Germany
Disruption of cardiac cholinergic neurons enhances susceptibility to ventricular arrhythmias
The parasympathetic nervous system plays an important role in the pathophysiology of atrial fibrillation. Catheter ablation, a minimally invasive procedure deactivating abnormal firing cardiac tissue, is increasingly becoming the therapy of choice for atrial fibrillation. This is inevitably associated with the obliteration of cardiac cholinergic neurons. However, the impact on ventricular electrophysiology is unclear. Here we show that cardiac cholinergic neurons modulate ventricular electrophysiology. Mechanical disruption or pharmacological blockade of parasympathetic innervation shortens ventricular refractory periods, increases the incidence of ventricular arrhythmia and decreases ventricular cAMP levels in murine hearts. Immunohistochemistry confirmed ventricular cholinergic innervation, revealing parasympathetic fibres running from the atria to the ventricles parallel to sympathetic fibres. In humans, catheter ablation of atrial fibrillation, which is accompanied by accidental parasympathetic and concomitant sympathetic denervation, raises the burden of premature ventricular complexes. In summary, our results demonstrate an influence of cardiac cholinergic neurons on the regulation of ventricular function and arrhythmogenesi
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