Differentiation of silane adsorption onto model E-glass surfaces from mixed solutions of amino and glycidyl silanes

Mixed silanes are often used as coupling agents in sizings for glass fibres. A technique has been developed which enables the preferential adsorption of a particular silane onto a model E-glass from a mixed aqueous silane solution to be probed. It is shown that γ-Aminopropyltriethoxysilane (APS) is preferentially adsorbed over γ-glycidoxypropyltrimethoxysilane (GPS) onto model E-glass fibres. High resolution X-ray photoelectron spectroscopy (XPS) has been employed to investigate the nature of silane deposits. Differentiation between the hydrolysed silane deposit and the model silica-based glass substrate was achieved by Si2p curve fitting. The extent of total silane adsorption onto model E-glass fibres was determined from the intensity of CSiO3 peak. In the case of APS/GPS mixed silanes, the N1s peak intensity provides the concentration of APS in the deposit. By comparing the relative intensities of the components in the Si2p3/2 and Si2p1/2 peaks for SiO4 and CSiO3 with the intensity of the N1s peak an assessment of differential adsorption proved possible

The differential adsorption of silanes from solution onto model E-glass surfaces using high resolution XPS

γ-aminopropyltriethoxysilane (APS), γ-mercaptopropyltrimethoxysilane (MPS) and their mixture have been adsorbed onto acid-treated model E-glass fibres from aqueous solution with different concentrations. High resolution X-ray photoelectron spectroscopy (XPS) has been employed to characterize APS and MPS single silane coatings and the selective adsorption of APS/MPS mixed silane coating. It is found that the Si contribution from the silane can be distinguished from the Si contribution from the acid-treated E-glass fibres by fitting Si2p1/2 and Si2p3/2 peaks with components for CSiO3 and SiO4 environments. The adsorption isotherms of APS and MPS have been obtained by comparing the atomic concentrations of N, S and CSiO3 groups. APS and MPS are equally adsorbed from 0.1% APS/MPS mixed silane solution, however, MPS dominates the deposit on model E-glass fibres to a depth corresponding to the take-off-angle of 45º when it is adsorbed from 0.5% and 1.0% APS/MPS mixed silane solutions

Conformal Field Theory Approach to the 2-Impurity Kondo Problem: Comparison with Numerical Renormalization Group Results

Numerical renormalization group and conformal field theory work indicate that the two impurity Kondo Hamiltonian has a non-Fermi liquid critical point separating the Kondo-screening phase from the inter-impurity singlet phase when particle-hole (P-H) symmetry is maintained. We clarify the circumstances under which this critical point occurs, pointing out that there are two types of P-H symmetry. Only one of them guarantees the occurance of the critical point. Much of the previous numerical work was done on models with the other type of P-H symmetry. We analyse this critical point using the boundary conformal field theory technique. The finite-size spectrum is presented in detail and compared with about 50 energy levels obtained using the numerical renormalization group. Various Green's functions, general renormalization group behaviour, and a hidden $SO(7)$ are analysed.Comment: 38 pages, RevTex. 2 new sections clarify the circumstances under which a model will exhibit the non-trivial critical point (hence potentially resolving disagreements with other Authors) and explain the hidden SO(7) symmetry of the model, relating it to an alternative approach of Sire et al. and Ga

STM: Seeing is believing

AbstractIn the last ten years the scanning tunnelling microscope (STM) has completely changed the way in which we look at the surfaces of semiconductor materials. However, due to the conflicting experimental geometries of the two techniques, it is only recently that it has been possible to combine high resolution STM imaging with a full scale MBE system. In this article we demonstrate the application of this technique in obtaining both morphological and atomic resolution images of MBE grown GaAs(001) surfaces and the same surfaces after deposition of Si

Using a cognitive architecture to examine what develops

Different theories of development propose alternative mechanisms by which development occurs. Cognitive architectures can be used to examine the influence of each proposed mechanism of development while keeping all other mechanisms constant. An ACT-R computational model that matched adult behavior in solving a 21-block pyramid puzzle was created. The model was modified in three ways that corresponded to mechanisms of development proposed by developmental theories. The results showed that all the modifications (two of capacity and one of strategy choice) could approximate the behavior of 7-year-old children on the task. The strategy-choice modification provided the closest match on the two central measures of task behavior (time taken per layer, r = .99, and construction attempts per layer, r = .73). Modifying cognitive architectures is a fruitful way to compare and test potential developmental mechanisms, and can therefore help in specifying “what develops.

Library Services in Land-Grant Colleges Teaching Agriculture

published or submitted for publicatio

Detection of pulsed, bremsstrahlung-induced, prompt neutron capture gamma-rays with HPGe detector

The Idaho National Engineering Laboratory (INEL) is developing a novel photoneutron-based nondestructive evaluation technique which uses a pulsed, high-energy (up to 8-MeV) electron accelerator and gamma-ray spectrometry. Highly penetrating pulses of bremsstrahlung photons are produced by each pulse of electrons. Interrogating neutrons are generated by the bremsstrahlung photons interacting within a photoneutron source material. The interactions of the neutrons within a target result in the emission of elemental characteristic gamma-rays. Spectrometry is performed by analyzing the photoneutron-induced prompt gamma-rays acquired between accelerator pulses with a unique, high-purity germanium (HPGe) gamma-ray detection system using a modified transistor reset preamplifier. The detection system, the experimental configuration, and the accelerator operation used to characterize the detection system performance are described. Using a 6.5 MeV electron accelerator and a beryllium metal photoneutron source, gamma-ray spectra were successfully acquired for Al, Cu, polyethylene, NaC1, and depleted uranium targets as soon as 30 {mu}s after each bremsstrahlung (or x-ray) flash