14 research outputs found
High Magnetic Field NMR Studies of LiVGeO, a quasi 1-D Spin System
We report Li pulsed NMR measurements in polycrystalline and single
crystal samples of the quasi one-dimensional S=1 antiferromagnet
LiVGeO, whose AF transition temperature is K.
The field () and temperature () ranges covered were 9-44.5 T and
1.7-300 K respectively. The measurements included NMR spectra, the spin-lattice
relaxation rate (), and the spin-phase relaxation rate (),
often as a function of the orientation of the field relative to the crystal
axes. The spectra indicate an AF magnetic structure consistent with that
obtained from neutron diffraction measurements, but with the moments aligned
parallel to the c-axis. The spectra also provide the -dependence of the AF
order parameter and show that the transition is either second order or weakly
first order. Both the spectra and the data show that has at
most a small effect on the alignment of the AF moment. There is no spin-flop
transition up to 44.5 T. These features indicate a very large magnetic
anisotropy energy in LiVGeO with orbital degrees of freedom playing an
important role. Below 8 K, varies substantially with the orientation
of in the plane perpendicular to the c-axis, suggesting a small energy
gap for magnetic fluctuations that is very anisotropic.Comment: submitted to Phys. Rev.
Anomalous NMR Spin-Lattice Relaxation in SrB_{6} and Ca_{1-x}La_{x}B_{6}
We report the results of {11}B nuclear magnetic resonance (NMR) measurements
of SrB_{6} and Ca_{0.995}La_{0.05}B_{6} below room temperature. Although the
electrical resistivities of these two materials differ substantially, their
{11}B-NMR responses exhibit some strikingly common features. Both materials
exhibit ferromagnetic order, but their {11}B-NMR spectra reveal very small
hyperfine fields at the Boron sites. The spin lattice relaxation T_{1}^{-1}
varies considerably with external field but changes with temperature only below
a few K. We discuss these unusual results by considering various different
scenarios for the electronic structure of these materials.Comment: Accepted for publication in Phys. Rev. B Rapid communication, 4
pages, 3 figures. This manuscript replaces an earlier version and includes
some minor changes in the text and in Fig.
Theory of High \tc Ferromagnetism in family: A case of Doped Spin-1 Mott insulator in a Valence Bond Solid Phase
Doped divalent hexaborides such as exhibit high \tc
ferromagnetism. We isolate a degenerate pair of -orbitals of boron with two
valence electrons, invoke electron correlation and Hund coupling, to suggest
that the undoped state is better viewed as a spin-1 Mott insulator; it is
predicted to be a type of 3d Haldane gap phase with a spin gap ,
much smaller than the charge gap of seen in ARPES. The
experimentally seen high \tc `ferromagnetism' is argued to be a complex
magnetic order in disguise - either a canted 6-sublattice AFM ()
order or its quantum melted version, a chiral spin liquid state, arising from a
type of double exchange mechanism.Comment: 4 pages, 2 figures; minor corrections, references adde
Comment on "Atomic jumps in quasiperiodic AlNiCo and related crystalline material"
We disagree with a number of statements by Dolinsek et al. about the
specificity of phason dynamics in quasicrystals (QCs).Comment: 2 pages, 0 figures, submitted to Physical Review
Electronic Structure of Calcium Hexaboride within the Weighted Density Approximation
We report calculations of the electronic structure of CaB using the
weighted density approximation (WDA) to density functional theory. We find a
semiconducting band structure with a sizable gap, in contrast to local density
approximation (LDA) results, but in accord with recent experimental data. In
particular, we find an -point band gap of 0.8 eV. The WDA correction of the
LDA error in describing the electronic structure of CaB is discussed in
terms of the orbital character of the bands and the better cancelation of
self-interactions within the WDA.Comment: 1 figur
Sr2V3O9 and Ba2V3O9: quasi one-dimensional spin-systems with an anomalous low temperature susceptibility
The magnetic behaviour of the low-dimensional Vanadium-oxides Sr2V3O9 and
Ba2V3O9 was investigated by means of magnetic susceptibility and specific heat
measurements. In both compounds, the results can be very well described by an
S=1/2 Heisenberg antiferromagnetic chain with an intrachain exchange of J = 82
K and J = 94 K in Sr2V3O9 and Ba2V3O9, respectively. In Sr2V3O9,
antiferromagnetic ordering at T_N = 5.3 K indicate a weak interchain exchange
of the order of J_perp ~ 2 K. In contrast, no evidence for magnetic order was
found in Ba2V3O9 down to 0.5 K, pointing to an even smaller interchain
coupling. In both compounds, we observe a pronounced Curie-like increase of the
susceptibility below 30 K, which we tentatively attribute to a staggered field
effect induced by the applied magnetic field. Results of LDA calculations
support the quasi one-dimensional character and indicate that in Sr2V3O9, the
magnetic chain is perpendicular to the structural one with the magnetic
exchange being transferred through VO4 tetrahedra.Comment: Submitted to Phy. Rev.
Bulk Electronic structure of NaCoO.1.3HO
High-energy (h = 5.95 keV) synchrotron Photoemission spectroscopy (PES)
is used to study bulk electronic structure of NaCoO.1.3HO,
the layered superconductor. In contrast to 3-dimensional doped Co oxides, Co
core level spectra show well-separated Co and Co ions.
Cluster calculations suggest low spin Co and Co character, and a
moderate on-site Coulomb correlation energy U3-5.5 eV. Photon
dependent valence band PES identifies Co and O derived
states, in near agreement with band structure calculations.Comment: 4 pages 4 figures Revised text added referenc
Na2V3O7: An unusual low-dimensional quantum magnet
Results of present and previous measurements of the23Na NMR response, dc- and ac-magnetic susceptibilities and the specific heat ofNa2V3O7at low temperatures suggest that this material is close to a quantum critical point (QCP) atm0HÂŒ0 T. The experimental datacan be explained by assuming that below 100 K the localizedVmagnetic momentsĂ°SÂŒ12Ăform a collection of dimers, with a broaddistribution of singletâtriplet gaps. Most of the dimers adopt a singlet ground state with gaps between 0 and 350 K. A small fraction ofthem forms triplet ground states with gaps between 0 and 15 K. The degeneracy of the triplet ground states is lifted by a phase transitionat an unusually low temperature of 0.086 K. Modest magnetic fields effectively quench this low-temperature state and the system is drivenaway from the QCP as the applied fields are enhanced to above 1