97 research outputs found
Oxygen impurities in NiAl: Relaxation effects
We have used a full-potential linear muffin-tin orbital method to calculate
the effects of oxygen impurities on the electronic structure of NiAl. Using the
supercell method with a 16-atom supercell we have investigated the cases where
an oxygen atom is substitutionally placed at either a nickel or an aluminum
site. Full relaxation of the atoms within the supercell was allowed. We found
that oxygen prefers to occupy a nickel site over an aluminum site with a site
selection energy of 138 mRy (21,370 K). An oxygen atom placed at an aluminum
site is found to cause a substantial relaxation of its nickel neighbors away
from it. In contrast, this steric repulsion is hardly present when the oxygen
atom occupies the nickel site and is surrounded by aluminum neighbors. We
comment on the possible relation of this effect to the pesting degradation
phenomenon (essentially spontaneous disintegration in air) in nickel
aluminides.Comment: To appear in Phys. Rev. B (Aug. 15, 2001
Feeding dihydroquercetin and vitamin E to broiler chickens reared at standard and high ambient temperatures
The use of natural antioxidants, in particular polyphenols such as dihydroquercetin (DHQ), in animal nutrition has recently increased in popularity. This may partly be due to the risk of increased incidences of heat stress associated with raising livestock in warmer ambient temperatures, facilitated by global warming, reducing antioxidant capacity. The current research demonstrates the effect of dietary DHQ, vitaminEand standard or high ambient temperatures on growth performance, energy and nutrient metabolism, gastrointestinal tract (GIT) development, jejunal villus morphometry and antioxidant status in broiler chickens. Each of the four experimental diets was fed to 16 pens of five birds, which were allocated to four rooms (four pens in each room). The temperature in two rooms was maintained at aconstant 35°C (high temperature; HT), and the temperature in the other two rooms was gradually reduced from 27°C at 7 dof age to 22°C at 20 dof age (standard temperature; ST). Rearing birds at HT reduced feed intake, weight gain, weight of small intestine, total GIT, liver, spleen, heart, villus height, villus surface area and lowered blood glutationperoxidase (GSH-Px). Dietary DHQ increased blood GSH-Px and total antioxidant status, increased heart weight and reduced caecal size. When fed separately, DHQ and vitamin E improved hepatic vitamin E concentration. Feeding vitamin Eincreased spleen and liver weights. When fed together, DHQ and vitamin Ereduced villus height, villus height to crypt depth ratio and villus surface area. Temperature and antioxidants did not affect energy and nutrient metabolism. There were no effects of dietary antioxidants on growth performance of broiler chickens and there were no mortalities. At present, it is unclear if feeding antioxidants (in particular DHQ) at different levels, using different dietary formulations, and rearing birds under arange of environmental conditions may be effective at enhancing production performance and bird health in hot ambient climates
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