6,106 research outputs found
Solid acid catalysts in heterogeneous n-alkanes hydroisomerisation for increasing octane number of gasoline
As the current global environmental concerns have prompted regulations to reduce the level of aromatic compounds, particularly benzene and its derivatives in gasoline, ydroisomerisation of n-alkanes is becoming a major alternative for enhancing octane number. Series of solid acid catalysts comprising of Freidel crafts, zirconias, MoO3-based (MOB), chlorinated Al2O3, heteropoly acids and bifunctional zeolite based catalysts have been tested in this respect. This paper reviewed important studies conducted on these catalysts with the aim of identifying areas requiring further investigation(s). Freidel craft catalysts are currently abandoned due to corrosion and disposal problems. MOB and heteropoly acids have good resistance to nitrogen and sulphur in a reaction stream but have poor thermal stability, difficult to regenerate and with mechanism their action only partly resolved. Bifunctional zeolites on the other hand are increasingly becoming promising catalysts due to resulting high acidity, activity and easy regeneration properties. Both solid and gaseous acid modifiers could similarly modify their textural characteristics. The activities of all catalysts could under uncontrolled conditions lead to side reactions such as cracking, aromatisation and dehydrogenation.
Keywords; Solid acids, n-alkanes, hydroisomerisation catalysts,
gasoline, octane number
Harvesting graphics power for MD simulations
We discuss an implementation of molecular dynamics (MD) simulations on a
graphic processing unit (GPU) in the NVIDIA CUDA language. We tested our code
on a modern GPU, the NVIDIA GeForce 8800 GTX. Results for two MD algorithms
suitable for short-ranged and long-ranged interactions, and a congruential
shift random number generator are presented. The performance of the GPU's is
compared to their main processor counterpart. We achieve speedups of up to 80,
40 and 150 fold, respectively. With newest generation of GPU's one can run
standard MD simulations at 10^7 flops/$.Comment: 12 pages, 5 figures. Submitted to Mol. Si
Ultrasonic characterization of the pulmonary venous wall: echographic and histological correlation
Background: Pulmonary vein isolation with radiofrequency catheter ablation techniques is used to prevent recurrences of human atrial fibrillation. Visualization of the architecture at the venoatrial junction could be crucial for these ablative techniques. Our study assesses the potential for intravascular ultrasound to provide this information.
Methods and Results: We retrieved 32 pulmonary veins from 8 patients dying from noncardiac causes. We obtained cross-sectional intravascular ultrasound (IVUS) images with a 3.2F, 30-MHz ultrasound catheter at intervals on each vein. Histological cross-sections at the intervals allowed comparisons with ultrasonic images. The pulmonary venous wall at the venoatrial junction revealed a 3-layered ultrasonic pattern. The inner echogenic layer represents both endothelium and connective tissue of the media (mean maximal thickness, 1.4±0.3 mm). The middle hypoechogenic stratum corresponds to the sleeves of left atrial myocardium surrounding the external aspect of the venous media. This layer was thickest at the venoatrial junction (mean maximal thickness, 2.6±0.8 mm) and decreased toward the lung hilum. The outer echodense layer corresponds to fibro-fatty adventitial tissue (mean maximal thickness, 2.15±0.36 mm). We found a close agreement among the IVUS and histological measurements for maximal luminal diameter (mean difference, -0.12±1.3 mm) and maximal muscular thickness (mean difference, 0.17±0.13 mm) using the Bland and Altman method.
Conclusions: Our experimental study demonstrates for the first time that IVUS images of the pulmonary veins can provide information on the distal limits and thickness of the myocardial sleeves and can be a valuable tool to help accurate targeting during ablative procedures
The Puzzle of the Flyby Anomaly
Close planetary flybys are frequently employed as a technique to place
spacecraft on extreme solar system trajectories that would otherwise require
much larger booster vehicles or may not even be feasible when relying solely on
chemical propulsion. The theoretical description of the flybys, referred to as
gravity assists, is well established. However, there seems to be a lack of
understanding of the physical processes occurring during these dynamical
events. Radio-metric tracking data received from a number of spacecraft that
experienced an Earth gravity assist indicate the presence of an unexpected
energy change that happened during the flyby and cannot be explained by the
standard methods of modern astrodynamics. This puzzling behavior of several
spacecraft has become known as the flyby anomaly. We present the summary of the
recent anomalous observations and discuss possible ways to resolve this puzzle.Comment: 6 pages, 1 figure. Accepted for publication by Space Science Review
Mechanisms of Spontaneous Current Generation in an Inhomogeneous d-Wave Superconductor
A boundary between two d-wave superconductors or an s-wave and a d-wave
superconductor generally breaks time-reversal symmetry and can generate
spontaneous currents due to proximity effect. On the other hand, surfaces and
interfaces in d-wave superconductors can produce localized current-carrying
states by supporting the T-breaking combination of dominant and subdominant
order parameters. We investigate spontaneous currents in the presence of both
mechanisms and show that at low temperature, counter-intuitively, the
subdominant coupling decreases the amplitude of the spontaneous current due to
proximity effect. Superscreening of spontaneous currents is demonstrated to be
present in any d-d (but not s-d) junction and surface with d+id' order
parameter symmetry. We show that this supercreening is the result of
contributions from the local magnetic moment of the condensate to the
spontaneous current.Comment: 4 pages, 5 figures, RevTe
Mesoscale observations of Joule heating near an auroral arc and ion-neutral collision frequency in the polar cap E region
We report on the first mesoscale combined ionospheric and thermospheric observations, partly in the vicinity of an auroral arc, from Svalbard in the polar cap on 2 February 2010. The EISCAT Svalbard radar employed a novel scanning mode in order to obtain F and E region ion flows over an annular region centered on the radar. Simultaneously, a colocated Scanning Doppler Imager observed the E region neutral winds and temperatures around 110 km altitude using the 557.7 nm auroral optical emission. Combining the ion and neutral data permits the E region Joule heating to be estimated with an azimuthal spatial resolution of âŒ64 km at a radius of âŒ163 km from the radar. The spatial distribution of Joule heating shows significant mesoscale variation. The ion-neutral collision frequency is measured in the E region by combining all the data over the entire field of view with only weak aurora present. The estimated ion-neutral collision frequency at âŒ113 km altitude is in good agreement with the MSIS atmospheric model
Time-frequency detection algorithm for gravitational wave bursts
An efficient algorithm is presented for the identification of short bursts of
gravitational radiation in the data from broad-band interferometric detectors.
The algorithm consists of three steps: pixels of the time-frequency
representation of the data that have power above a fixed threshold are first
identified. Clusters of such pixels that conform to a set of rules on their
size and their proximity to other clusters are formed, and a final threshold is
applied on the power integrated over all pixels in such clusters. Formal
arguments are given to support the conjecture that this algorithm is very
efficient for a wide class of signals. A precise model for the false alarm rate
of this algorithm is presented, and it is shown using a number of
representative numerical simulations to be accurate at the 1% level for most
values of the parameters, with maximal error around 10%.Comment: 26 pages, 15 figures, to appear in PR
Tunneling ``zero-bias'' anomaly in the quasi-ballistic regime
For the first time, we study the tunneling density of states (DOS) of the
interacting electron gas beyond the diffusive limit. A strong correction to the
DOS persists even at electron energies exceeding the inverse transport
relaxation time, which could not be expected from the well-known
Altshuler-Aronov-Lee (AAL) theory. This correction originates from the
interference between the electron waves scattered by an impurity and by the
Friedel oscillation this impurity creates. Account for such processes also
revises the AAL formula for the DOS in the diffusive limit.Comment: 4 pages, 2 .eps figures, submitted to Phys. Rev. Let
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