Magnetic Properties of the Novel Low-Dimensional Cuprate Na5RbCu4(AsO4)4Cl2

The magnetic properties of a new compound, Na5RbCu4(AsO4)4Cl2 are reported. The material has a layered structure comprised of square Cu4O4 tetramers. The Cu ions are divalent and the system behaves as a low-dimensional S=1/2 antiferromagnet. Spin exchange in Na5RbCu4(AsO4)4Cl2 appears to be quasi-two-dimensional and non-frustrated. Measurements of the bulk magnetic susceptibility and heat capacity are consistent with low-dimensional magnetism. The compound has an interesting, low-entropy, magnetic transition at T = 17 K.Comment: 4 pages, 5 figure

Quantitative study of molecular N_2 trapped in disordered GaN:O films

The structure of disordered GaN:O films grown by ion-assisted deposition is investigated using x-ray absorption near-edge spectroscopy and Raman spectroscopy. It is found that between 4 and 21 % of the nitrogen in the films is in the form of molecular N_2 that interacts only weakly with the surrounding matrix. The anion to cation ratio in the GaN:O host remains close to unity, and there is a close correlation between the N_2 fraction, the level of oxygen impurities, and the absence of short-range order in the GaN:O matrix.Comment: 5 pages, 3 figure

Optical Morphology Evolution of Infrared Luminous Galaxies in GOODS-N

We combine optical morphologies and photometry from HST, redshifts from Keck, and mid-infrared luminosities from Spitzer for an optically selected sample of~800 galaxies in GOODS-N to track morphology evolution of infrared luminous galaxies (LIRGs) since redshift z=1. We find a 50% decline in the number of LIRGs from z~1 to lower redshift, in agreement with previous studies. In addition, there is evidence for a morphological evolution of the populations of LIRGs. Above z=0.5, roughly half of all LIRGs are spiral, the peculiar/irregular to spiral ratio is ~0.7, and both classes span a similar range of L_{IR} and M_B. At low-z, spirals account for one-third of LIRGs, the peculiar to spiral fraction rises to 1.3, and for a given M_B spirals tend to have lower IR luminosity than peculiars. Only a few percent of LIRGs at any redshift are red early-type galaxies. For blue galaxies (U-B < 0.2), M_B is well correlated with log(L_{IR}) with an RMS scatter (about a bivariate linear fit) of ~0.25 dex in IR luminosity. Among blue galaxies that are brighter than M_B = -21, 75% are LIRGs, regardless of redshift. These results can be explained by a scenario in which at high-z, most large spirals experience an elevated star formation rate as LIRGs. Gas consumption results in a decline of LIRGs, especially in spirals, to lower redshifts.Comment: 6 pages, 2 figures, accepted ApJ

Comparison of Material Properties and Microstructure of Specimens Built Using the 3D Systems Vanguard HS and Vanguard HiQ+HSSLS Systems

The HiQ upgrade to the 3D Systems Vanguard selective laser sintering (SLS) machine incorporates a revised thermal calibration system and new control software. The paper compares the tensile modulus, tensile strength, elongation at break, flexural modulus, Izod impact resistance and microstructure of two batteries of standard specimens built from recycled Duraform PA (Nylon 12). The first set is built on a Vanguard HS system and the second on the same system with the HiQ upgrade installed. The upgrade reduces user intervention, decreases total build time and improves surface finish. However, using the default processing parameters, tensile, flexure and impact properties are all found to decline after the upgrade is installed.Mechanical Engineerin

Resonant x-ray scattering study on multiferroic BiMnO3

Resonant x-ray scattering is performed near the Mn K-absorption edge for an epitaxial thin film of BiMnO3. The azimuthal angle dependence of the resonant (003) peak (in monoclinic indices) is measured with different photon polarizations; for the $\sigma\to\pi'$ channel a 3-fold symmetric oscillation is observed in the intensity variation, while the $\sigma\to\sigma'$ scattering intensity remains constant. These features are accounted for in terms of the peculiar ordering of the manganese 3d orbitals in BiMnO3. It is demonstrated that the resonant peak persists up to 770 K with an anomaly around 440 K; these high and low temperatures coincide with the structural transition temperatures, seen in bulk, with and without a symmetry change, respectively. A possible relationship of the orbital order with the ferroelectricity of the system is discussed.Comment: 14 pages, 4 figure

Polyamide Nanocomposites for Selective Laser Sintering

Current polyamide 11 and 12 are lacking in fire retardancy and high strength/high heat resistance characteristics for a plethora of finished parts that are desired and required for performance driven applications. It is anticipated that nanomodification of polyamide 11 and 12 will result in enhanced polymer performance, i.e., fire retardancy, high strength and high heat resistance for polyamide 11 and 12. It is expected that these findings will expand the market opportunities for polyamide 11 and 12 resin manufacturers. The objective of this research is to develop improved polyamide 11 and 12 polymers with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering (SLS) rapid manufacturing (RM). A nanophase was introduced into the polyamide 11 and 12 via twin screw extrusion to provide improved material properties of the polymer blends. Arkema RILSAN® polyamide 11 molding polymer pellets and Degussa VESTAMID® L1670 polyamide 12 were examined with three types of nanoparticles: chemically modified montmorillonite (MMT) organoclays, surface modified nanosilica, and carbon nanofibers (CNFs) to create polyamide 11 and 12 nanocomposites. Wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM) were used to determine the degree of dispersion. Injection molded test specimens were fabricated for physical, thermal, mechanical properties, and flammability tests. Thermal stability of these polyamide 11 and 12 nanocomposites was examined by TGA. Mechanical properties such as tensile, flexural, and elongation at break were measured. Flammability properties were also obtained using the Cone Calorimeter at an external heat flux of 50 kW/m2. TEM micrographs, physical, mechanical, and flammability properties are included in the paper. Polyamide 11 and 12 nanocomposites properties are compared with polyamide 11 and 12 baseline polymers. Based on flammability and mechanical material performance, selective polymers including polyamide 11 nanocomposites and control polyamide 11 were cryogenically ground into fine powders and fabricated into SLS parts.Mechanical Engineerin

Substructural Identification of Flexural Rigidity for Beam-Like Structures

This study proposes a novel substructural identification method based on the Bernoulli-Euler beam theory with a single variable optimization scheme to estimate the flexural rigidity of a beam-like structure such as a bridge deck, which is one of the major structural integrity indices of a structure. In ordinary bridges, the boundary condition of a superstructure can be significantly altered by aging and environmental variations, and the actual boundary conditions are generally unknown or difficult to be estimated correctly. To efficiently bypass the problems related to boundary conditions, a substructural identification method is proposed to evaluate the flexural rigidity regardless of the actual boundary conditions by isolating an identification region within the internal substructure. The proposed method is very simple and effective as it utilizes the single variable optimization based on the transfer function formulated utilizing Bernoulli Euler beam theory for the inverse analysis to obtain the flexural rigidity. This novel method is also rigorously investigated by applying it for estimating the flexural rigidity of a simply supported beam model with different boundary conditions, a concrete plate-girder bridge model with different length of an internal substructure, a cantilever-type wind turbine tower structure with different type of excitation, and a steel box-girder bridge model with internal structural damages.This research was financially supported by the Ministry of Land, Infrastructure and Transport (MOLIT) of the Korea government (code 12 Technology Innovation E09)