11 research outputs found
Testing the neutrality of matter by acoustic means in a spherical resonator
New measurements to test the neutrality of matter by acoustic means are
reported. The apparatus is based on a spherical capacitor filled with gaseous
SF excited by an oscillating electric field. The apparatus has been
calibrated measuring the electric polarizability. Assuming charge conservation
in the decay of the neutron, the experiment gives a limit of
for the electron-proton charge
difference, the same limit holding for the charge of the neutron. Previous
measurements are critically reviewed and found incorrect: the present result is
the best limit obtained with this technique
Description of Polar Chemical Bonds from the Quantum Mechanical Interference Perspective
The Generalized Product Function Energy Partitioning (GPF-EP) method has been applied to a set of molecules, AH (A = Li, Be, B, C, N, O, F), CO and LiF with quite different dipole moments, in order to investigate the role played by the quantum interference effect in the formation of polar chemical bonds. The calculations were carried out with GPF wave functions treating all the core electrons as a single HartreeâFock group and the bonding electrons at the Generalized Valence Bond Perfect-Pairing (GVB-PP) level, with the cc-pVTZ basis set. The results of the energy partitioning into interference and quasi-classical contributions along the respective Potential Energy Surfaces (PES) show that the main contribution to the depth of the potential wells comes from the interference term, which is an indication that all the molecules mentioned above form typical covalent bonds. In all cases, the stabilization promoted by the interference term comes from the kinetic contribution, in agreement with previous results. The analysis of the effect of quantum interference on the electron density reveals that while polarization effects (quasi-classical) tend to displace electronic density from the most polarizable atom toward the less polarizable one, interference (quantum effects) counteracts by displacing electronic density to the bond region, giving rise to the right electronic density and dipole moment
Table salt and other alkali metal chloride oligomers: structure, stability, and bonding
We have investigated table salt and other alkali metal chloride monomers, CIM, and (distorted) cubic tetramers, (CIM