2,549 research outputs found
Dissociative electron attachment to the H2O molecule. II. Nuclear dynamics on coupled electronic surfaces within the local complex potential model
We report the results of a first-principles study of dissociative electron
attachment to H2O. The cross sections are obtained from nuclear dynamics
calculations carried out in full dimensionality within the local complex
potential model by using the multi-configuration time-dependent Hartree method.
The calculations employ our previously obtained global, complex-valued,
potential-energy surfaces for the three (doublet B1, doublet A1, and doublet
B2) electronic Feshbach resonances involved in this process. These three
metastable states of H2O- undergo several degeneracies, and we incorporate both
the Renner-Teller coupling between the B1 and A1 states as well as the conical
intersection between the A1 and B2 states into our treatment. The nuclear
dynamics are inherently multidimensional and involve branching between
different final product arrangements as well as extensive excitation of the
diatomic fragment. Our results successfully mirror the qualitative features of
the major fragment channels observed, but are less successful in reproducing
the available results for some of the minor channels. We comment on the
applicability of the local complex potential model to such a complicated
resonant system.Comment: Corrected version of Phys Rev A 75, 012711 (2007
Estimation of the hydraulic parameters of unsaturated samples by electrical resistivity tomography
In situ and laboratory experiments have shown that electrical resistivity tomography (ERT) is an effective tool to image transient phenomena in soils. However, its application in quantifying soil hydraulic parameters has been limited. In this study, experiments of water inflow in unsaturated soil samples were conducted in an oedometer equipped to perform three-dimensional electrical measurements. Reconstructions of the electrical conductivity at different times confirmed the usefulness of ERT for monitoring the evolution of water content. The tomographic reconstructions were subsequently used in conjunction with a finite-element simulation to infer the water retention curve and the unsaturated hydraulic conductivity. The parameters estimated with ERT agree satisfactorily with those determined using established techniques, hence the proposed approach shows good potential for relatively fast characterisations. Similar experiments could be carried out on site to study the hydraulic behaviour of the entire soil deposi
A 23 GHz Survey of GRB Error Boxes
The Haystack 37-meter telescope was used in a pilot project in May 1995 to
observe GRB error boxes at 23~GHz. Seven BATSE error boxes and two IPN arcs
were scanned by driving the beam of the telescope rapidly across their area.
For the BATSE error boxes, the radio observations took place two to eighteen
days after the BATSE detection, and several boxes were observed more than once.
Total power data were recorded continuously as the telescope was driven at a
rate of 0.2~degrees/second, yielding Nyquist sampling of the beam with an
integration time of 50~milliseconds, corresponding to a theoretical rms
sensitivity of 0.5~Jy. Under conditions of good weather, this sensitivity was
achieved. In a preliminary analysis of the data we detect only two sources,
3C273 and 0552+398, both catalogued sources that are known to be variable at
23~GHz. Neither had a flux density that was unusally high or low at the time of
our observations.Comment: 5 pages, 1 postscript figure. To appear in Proceedings of the Third
Huntsville Symposium on Gamma-Ray Bursts (eds. C. Kouveliotou, M. S. Briggs,
and G. J. Fishman
Preparation of anti-vicinal amino alcohols: asymmetric synthesis of D-erythro-Sphinganine, (+)-spisulosine and D-ribo-phytosphingosine
Two variations of the Overman rearrangement have been developed for the highly selective synthesis of anti-vicinal amino alcohol natural products. A MOM-ether directed palladium(II)-catalyzed rearrangement of an allylic trichloroacetimidate was used as the key step for the preparation of the protein kinase C inhibitor D-erythro-sphinganine and the antitumor agent (+)-spisulosine, while the Overman rearrangement of chiral allylic trichloroacetimidates generated by asymmetric reduction of an alpha,beta-unsaturated methyl ketone allowed rapid access to both D-ribo-phytosphingosine and L-arabino-phytosphingosine
Self-tuning to the Hopf bifurcation in fluctuating systems
The problem of self-tuning a system to the Hopf bifurcation in the presence
of noise and periodic external forcing is discussed. We find that the response
of the system has a non-monotonic dependence on the noise-strength, and
displays an amplified response which is more pronounced for weaker signals. The
observed effect is to be distinguished from stochastic resonance. For the
feedback we have studied, the unforced self-tuned Hopf oscillator in the
presence of fluctuations exhibits sharp peaks in its spectrum. The implications
of our general results are briefly discussed in the context of sound detection
by the inner ear.Comment: 37 pages, 7 figures (8 figure files
Random Packings of Frictionless Particles
We study random packings of frictionless particles at T=0.
The packing fraction where the pressure becomes nonzero is the same as the
jamming threshold, where the static shear modulus becomes nonzero. The
distribution of threshold packing fractions narrows and its peak approaches
random close-packing as the system size increases. For packing fractions within
the peak, there is no self-averaging, leading to exponential decay of the
interparticle force distribution.Comment: 4 pages, 3 figure
Lyapunov spectral analysis of a nonequilibrium Ising-like transition
By simulating a nonequilibrium coupled map lattice that undergoes an
Ising-like phase transition, we show that the Lyapunov spectrum and related
dynamical quantities such as the dimension correlation length~ are
insensitive to the onset of long-range ferromagnetic order. As a function of
lattice coupling constant~ and for certain lattice maps, the Lyapunov
dimension density and other dynamical order parameters go through a minimum.
The occurrence of this minimum as a function of~ depends on the number of
nearest neighbors of a lattice point but not on the lattice symmetry, on the
lattice dimensionality or on the position of the Ising-like transition. In
one-space dimension, the spatial correlation length associated with magnitude
fluctuations and the length~ are approximately equal, with both
varying linearly with the radius of the lattice coupling.Comment: 29 pages of text plus 15 figures, uses REVTeX macros. Submitted to
Phys. Rev. E
Force distributions near the jamming and glass transitions
We calculate the distribution of interparticle normal forces near the
glass and jamming transitions in model supercooled liquids and foams,
respectively. develops a peak that appears near the glass or jamming
transitions, whose height increases with decreasing temperature, decreasing
shear stress and increasing packing density. A similar shape of was
observed in experiments on static granular packings. We propose that the
appearance of this peak signals the development of a yield stress. The
sensitivity of the peak to temperature, shear stress and density lends credence
to the recently proposed generalized jamming phase diagram.Comment: 4 pages, 3 postscript figures;Version 3 replaces figure 1 and removes
figure 2 from version 1. Significant rewording of version 1 to emphasize the
formation of peak in P(F) when these systems jam along five different routes
of the recently proposed jamming phase diagram. Version 2 displayed the
incorrect abstrac
Spin dynamics and ordering of a cuprate stripe-antiferromagnet
In La1.48Nd0.4Sr0.12CuO4 the 139La and 63Cu NQR relaxation rates and signal
wipe-out upon lowering temperature are shown to be due to purely magnetic
fluctuations. They follow the same renormalized classical behavior as seen in
neutron data, when the electronic spins order in stripes, with a small spread
in spin stiffness (15% spread in activation energy). The La signal, which
reappears at low temperatures, is magnetically broadened and experiences
additional wipe-out due to slowing down of the Nd fluctuations.Comment: 4 pages including 3 figures - ref. 16 adde
Trait and state authenticity across cultures
We examined the role of culture in both trait and state authenticity, asking whether the search for and experience of the 'true self' is a uniquely Western phenomenon or is relevant cross-culturally. We tested participants from the US, China, India, and Singapore. US participants reported higher average levels of trait authenticity than those from Eastern cultures (i.e., China, India, Singapore), but this effect was partially explained by cultural differences in self-construal and thinking style. Importantly, the experience of state authenticity, and especially state inauthenticity, was more similar than different across cultures. In all, people from different cultures do experience authenticity, even if they do not endorse the (Western) value of “independence.” The findings contribute to a more nuanced understanding of state authenticity
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