5,257 research outputs found
Aerodynamic analysis of a horizontal axis wind turbine by use of helical vortex theory, volume 2: Computer program users manual
A description of a computer program entitled VORTEX that may be used to determine the aerodynamic performance of horizontal axis wind turbines is given. The computer code implements a vortex method from finite span wind theory and determines the induced velocity at the rotor disk by integrating the Biot-Savart law. It is assumed that the trailing helical vortex filaments form a wake of constant diameter (the rigid wake assumption) and travel downstream at the free stream velocity. The program can handle rotors having any number of blades which may be arbitrarily shaped and twisted. Many numerical details associated with the program are presented. A complete listing of the program is provided and all program variables are defined. An example problem illustrating input and output characteristics is solved
The para-substituent effect and pH-dependence of the organometallic Baeyer–Villiger oxidation of rhenium–carbon bonds
We studied the Baeyer–Villiger (BV) type oxidation of phenylrhenium trioxide (PTO) by H2O2 in the aqueous phase using Quantum Mechanics (density functional theory with the M06 functional) focusing on how the solution pH and the para-substituent affect the Gibbs free energy surfaces. For both PTO and MTO (methylrhenium trioxide) cases, we find that for pH > 1 the BV pathway having OH− as the leaving group is lower in energy than the one involving simultaneous protonation of hydroxide. We also find that during this organometallic BV oxidation, the migrating phenyl is a nucleophile so that substituting functional groups in the para-position of phenyl with increased electron-donating character lowers the migration barrier, just as in organic BV reactions. However, this substituent effect also pushes electron density to Re, impeding HOO− coordination and slowing down the reaction. This is in direct contrast to the organic analog, in which para-substitution has an insignificant influence on 1,2-addition of peracids. Due to the competition of the two opposing effects and the dependence of the resting state on pH and concentration, the reaction rate of the organometallic BV oxidation is surprisingly unaffected by para-substitution
Functionalization of Rhenium Aryl Bonds by O-Atom Transfer
Aryltrioxorhenium (ArReO_3) has been demonstrated to show rapid oxy-functionalization upon reaction with O-atom donors, YO, to selectively generate the corresponding phenols in near quantitative yields. (18)^O-Labeling experiments show that the oxygen in the products is exclusively from YO. DFT studies reveal a 10.7 kcal/mol barrier (Ar = Ph) for oxy-functionalization with H_2O_2 via a Baeyer-Villiger type mechanism involving nudeophilic attack of the aryl group on an electrophilic oxygen of YO coordinated to rhenium
Surface electronic structure of a topological Kondo insulator candidate SmB6: insights from high-resolution ARPES
The Kondo insulator SmB6 has long been known to exhibit low temperature (T <
10K) transport anomaly and has recently attracted attention as a new
topological insulator candidate. By combining low-temperature and high
energy-momentum resolution of the laser-based ARPES technique, for the first
time, we probe the surface electronic structure of the anomalous conductivity
regime. We observe that the bulk bands exhibit a Kondo gap of 14 meV and
identify in-gap low-lying states within a 4 meV window of the Fermi level on
the (001)-surface of this material. The low-lying states are found to form
electron-like Fermi surface pockets that enclose the X and the Gamma points of
the surface Brillouin zone. These states disappear as temperature is raised
above 15K in correspondence with the complete disappearance of the 2D
conductivity channels in SmB6. While the topological nature of the in-gap
metallic states cannot be ascertained without spin (spin-texture) measurements
our bulk and surface measurements carried out in the
transport-anomaly-temperature regime (T < 10K) are consistent with the
first-principle predicted Fermi surface behavior of a topological Kondo
insulator phase in this material.Comment: 4 Figures, 6 Page
Selective interlayer ferromagnetic coupling between the Cu spins in YBa Cu O grown on top of La Ca MnO
Studies to date on ferromagnet/d-wave superconductor heterostructures focus
mainly on the effects at or near the interfaces while the response of bulk
properties to heterostructuring is overlooked. Here we use resonant soft x-ray
scattering spectroscopy to reveal a novel c-axis ferromagnetic coupling between
the in-plane Cu spins in YBa Cu O (YBCO) superconductor when it
is grown on top of ferromagnetic La Ca MnO (LCMO) manganite
layer. This coupling, present in both normal and superconducting states of
YBCO, is sensitive to the interfacial termination such that it is only observed
in bilayers with MnO_2but not with La Ca interfacial
termination. Such contrasting behaviors, we propose, are due to distinct
energetic of CuO chain and CuO plane at the La Ca and
MnO terminated interfaces respectively, therefore influencing the transfer
of spin-polarized electrons from manganite to cuprate differently. Our findings
suggest that the superconducting/ferromagnetic bilayers with proper interfacial
engineering can be good candidates for searching the theorized
Fulde-Ferrel-Larkin-Ovchinnikov (FFLO) state in cuprates and studying the
competing quantum orders in highly correlated electron systems.Comment: Please note the change of the title. Text might be slightly different
from the published versio
Lifshitz transition and van Hove singularity in a Topological Dirac Semimetal
A topological Dirac semimetal is a novel state of quantum matter which has
recently attracted much attention as an apparent 3D version of graphene. In
this paper, we report critically important results on the electronic structure
of the 3D Dirac semimetal Na3Bi at a surface that reveals its nontrivial
groundstate. Our studies, for the first time, reveal that the two 3D Dirac
cones go through a topological change in the constant energy contour as a
function of the binding energy, featuring a Lifshitz point, which is missing in
a strict 3D analog of graphene (in other words Na3Bi is not a true 3D analog of
graphene). Our results identify the first example of a band saddle point
singularity in 3D Dirac materials. This is in contrast to its 2D analogs such
as graphene and the helical Dirac surface states of a topological insulator.
The observation of multiple Dirac nodes in Na3Bi connecting via a Lifshitz
point along its crystalline rotational axis away from the Kramers point serves
as a decisive signature for the symmetry-protected nature of the Dirac
semimetal's topological groundstate.Comment: 5 pages, 4 Figures, Related papers on topological Fermi arcs and Weyl
Semimetals (WSMs) are at
http://physics.princeton.edu/zahidhasangroup/index.htm
Transport properties in FeSe0.5Te0.5 nanobridges
FeSeTe nanobridges of different widths have been fabricated on MgO substrates using focused ion beams. These nanobridges exhibit the Josephson effects. The current-voltage curves of junctions with 248–564 nm wide follow the resistively and capacitatively shunted junction model. Shapiro steps under microwave radiation were clearly observed in these nanobridges. The products of the critical current and normal state resistance (I c R n) are remarkably high. The temperature dependence of I c R n product followed the Ambegaokar-Baratoff (A-B) relation. The value of energy gap of FeSeTe calculated from the A-B relation is 3.5kBTc. The nanobridge junctions have a strong potential for high frequency applications
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