High power diode laser surface glazing of concrete

This present work describes the utilisation of the relatively novel high power diode laser (HPDL) to generate a surface glaze on the ordinary Portland cement (OPC) surface of concrete. The value of such an investigation would be to facilitate the hitherto impossible task of generating a durable and long-lasting surface seal on the concrete, thereby extending the life and applications base of the concrete. The basic process phenomena are investigated and the laser effects in terms of glaze morphology, composition and microstructure are presented. Also, the resultant heat affects are analysed and described, as well as the effects of the shield gases, O2 and Ar, during laser processing. HPDL glazing of OPC was successfully demonstrated with power densities as low as 750 W cm-2 and at scanning rates up to 480 mm min-1. The work showed that the generation of the surface glaze resulted in improved mechanical and chemical properties over the untreated OPC surface of concrete. Both untreated and HPDL glazed OPC were tested for pull-off strength, rupture strength, water absorption, wear resistance and corrosion resistance. The OPC laser glaze exhibited clear improvements in wear, water sorptivity, and resistance (up to 80% concentration) to nitric acid, sodium hydroxide and detergent. Life assessment testing revealed that the OPC laser glaze had an increase in actual wear life of 1.3 to 14.8 times over the untreated OPC surface of concrete, depending upon the corrosive environment

Agrin isoforms and their role in synaptogenesis

Agrin is thought to mediate the motor neuron-induced aggregation of synaptic proteins on the surface of muscle fibers at neuromuscular junctions. Recent experiments provide direct evidence in support of this hypothesis, reveal the nature of agrin immunoreactivity at sites other than neuromuscular junctions, and have resulted in findings that are consistent with the possibility that agrin plays a role in synaptogenesis throughout the nervous system

Nonequilibrium steady states of driven magnetic flux lines in disordered type-II superconductors

We investigate driven magnetic flux lines in layered type-II superconductors subject to various configurations of strong point or columnar pinning centers by means of a three-dimensional elastic line model and Metropolis Monte Carlo simulations. We characterize the resulting nonequilibrium steady states by means of the force-velocity / current-voltage curve, static structure factor, mean vortex radius of gyration, number of double-kink and half-loop excitations, and velocity / voltage noise spectrum. We compare the results for the above observables for randomly distributed point and columnar defects, and demonstrate that the three-dimensional flux line structures and their fluctuations lead to a remarkable variety of complex phenomena in the steady-state transport properties of bulk superconductors.Comment: 23 pages, IOP style, 18 figures include

Circularly polarized resonant soft x-ray diffraction study of helical magnetism in hexaferrite

Magnetic spiral structures can exhibit ferroelectric moments as recently demonstrated in various multiferroic materials. In such cases the helicity of the magnetic spiral is directly correlated with the direction of the ferroelectric moment and measurement of the helicity of magnetic structures is of current interest. Soft x-ray resonant diffraction is particularly advantageous because it combines element selectivity with a large magnetic cross-section. We calculate the polarization dependence of the resonant magnetic x-ray cross-section (electric dipole transition) for the basal plane magnetic spiral in hexaferrite Ba0.8Sr1.2Zn2Fe12O22 and deduce its domain population using circular polarized incident radiation. We demonstrate there is a direct correlation between the diffracted radiation and the helicity of the magnetic spiral.Comment: 4 pages, 4 figure

Improved prediction of clay soil expansion using machine learning algorithms and meta-heuristic dichotomous ensemble classifiers

Soil swelling-related disaster is considered as one of the most devastating geo-hazards in modern history. Hence, proper determination of a soil's ability to expand is very vital for achieving a secure and safe ground for infrastructures. Accordingly, this study has provided a novel and intelligent approach that enables an improved estimation of swelling by using kernelised machines (Bayesian linear regression (BLR) & bayes point machine (BPM) support vector machine (SVM) and deep-support vector machine (D-SVM)); (multiple linear regressor (REG), logistic regressor (LR) and artificial neural network (ANN)), tree-based algorithms such as decision forest (RDF) & boosted trees (BDT). Also, and for the first time, meta-heuristic classifiers incorporating the techniques of voting (VE) and stacking (SE) were utilised. Different independent scenarios of explanatory features’ combination that influence soil behaviour in swelling were investigated. Preliminary results indicated BLR as possessing the highest amount of deviation from the predictor variable (the actual swell-strain). REG and BLR performed slightly better than ANN while the meta-heuristic learners (VE and SE) produced the best overall performance (greatest R2 value of 0.94 and RMSE of 0.06% exhibited by VE). CEC, plasticity index and moisture content were the features considered to have the highest level of importance. Kernelized binary classifiers (SVM, D-SVM and BPM) gave better accuracy (average accuracy and recall rate of 0.93 and 0.60) compared to ANN, LR and RDF. Sensitivity-driven diagnostic test indicated that the meta-heuristic models’ best performance occurred when ML training was conducted using k-fold validation technique. Finally, it is recommended that the concepts developed herein be deployed during the preliminary phases of a geotechnical or geological site characterisation by using the best performing meta-heuristic models via their background coding resource

Doping and temperature dependence of Mn 3d states in A-site ordered manganites

We present a systematic study of the electronic structure in A-site ordered manganites as function of doping and temperature. The energy dependencies observed with soft x-ray resonant diffraction (SXRD) at the Mn L_{2,3} edges are compared with structural investigations using neutron powder diffraction as well as with cluster calculations. The crystal structures obtained with neutron powder diffraction reflect the various orbital and charge ordered phases and show an increase of the Mn-O-Mn bond angle as function of doping and temperature. Cluster calculations show that the observed spectral changes in SXRD as a function of doping are more pronounced than expected from an increase in bandwitdh due to the increase in Mn-O-Mn bond angle, and are best described by holes that are distributed at the neighbouring oxygen ions. These holes are not directly added to the Mn 3d shell, but centered at the Mn site. In contrast, the spectral changes in SXRD as function of temperature are best described by an increase of magnetic correlations. This demonstrates the strong correlations between orbitals and magnetic moments of the 3d states

Indirect detection of light neutralino dark matter in the NMSSM

We explore the prospects for indirect detection of neutralino dark matter in supersymmetric models with an extended Higgs sector (NMSSM). We compute, for the first time, one-loop amplitudes for NMSSM neutralino pair annihilation into two photons and two gluons, and point out that extra diagrams (with respect to the MSSM), featuring a potentially light CP-odd Higgs boson exchange, can strongly enhance these radiative modes. Expected signals in neutrino telescopes due to the annihilation of relic neutralinos in the Sun and in the Earth are evaluated, as well as the prospects of detection of a neutralino annihilation signal in space-based gamma-ray, antiproton and positron search experiments, and at low-energy antideuteron searches. We find that in the low mass regime the signals from capture in the Earth are enhanced compared to the MSSM, and that NMSSM neutralinos have a remote possibility of affecting solar dynamics. Also, antimatter experiments are an excellent probe of galactic NMSSM dark matter. We also find enhanced two photon decay modes that make the possibility of the detection of a monochromatic gamma-ray line within the NMSSM more promising than in the MSSM.Comment: 26 pages, 12 figures. Updated references and corrected discussion of Upsilon decay

Space-Time Distribution of G-Band and Ca II H-Line Intensity Oscillations in Hinode/SOT-FG Observations

We study the space-time distributions of intensity fluctuations in 2 - 3 hour sequences of multi-spectral, high-resolution, high-cadence broad-band filtergram images (BFI) made by the SOT-FG system aboard the Hinode spacecraft. In the frequency range 5.5 < f < 8.0 mHz both G-band and Ca II H-line oscillations are suppressed in the presence of magnetic fields, but the suppression disappears for f > 10 mHz. By looking at G-band frequencies above 10 mHz we find that the oscillatory power, both at these frequencies and at lower frequencies too, lies in a mesh pattern with cell scale 2 - 3 Mm, clearly larger than normal granulation, and with correlation times on the order of hours. The mesh pattern lies in the dark lanes between stable cells found in time-integrated G-band intensity images. It also underlies part of the bright pattern in time-integrated H-line emission. This discovery may reflect dynamical constraints on the sizes of rising granular convection cells together with the turbulence created in strong intercellular downflows.Comment: 24 pages, 15 figure

The Cosmological Constant is Back

A diverse set of observations now compellingly suggest that Universe possesses a nonzero cosmological constant. In the context of quantum-field theory a cosmological constant corresponds to the energy density of the vacuum, and the wanted value for the cosmological constant corresponds to a very tiny vacuum energy density. We discuss future observational tests for a cosmological constant as well as the fundamental theoretical challenges---and opportunities---that this poses for particle physics and for extending our understanding of the evolution of the Universe back to the earliest moments.Comment: latex, 8 pages plus one ps figure available as separate compressed uuencoded fil

High field x-ray diffraction study on a magnetic-field-induced valence transition in YbInCu4

We report the first high-field x-ray diffraction experiment using synchrotron x-rays and pulsed magnetic fields exceeding 30 T. Lattice deformation due to a magnetic-field-induced valence transition in YbInCu4 is studied. It has been found that the Bragg reflection profile at 32 K changes significantly at around 27 T due to the structural transition. In the vicinity of the transition field the low-field and the high-field phases are observed simultaneously as the two distinct Bragg reflection peaks: This is a direct evidence of the fact that the field-induced valence state transition is the first order phase transition. The field-dependence of the low-field-phase Bragg peak intensity is found to be scaled with the magnetization.Comment: 5 pages, 6 figures, submitted to J. Phys. Soc. Jp