10,018 research outputs found

    Line-concentrating Flux Analysis of 42kWe High-flux Solar Simulator

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    AbstractHigh-flux solar simulatorscan provide controlled conditions and allow conducting high-temperature solar-driven thermal and thermochemical research without perturbations due to solar resource intermittency. A 42-kWe high-flux solar simulator, KIRAN-42, with seven hexagonal symmetry reflectors has been built at IMDEA Energy Institute, Spain. The reflectors layout of KIRAN-42 provides sufficient separation of units and it is conceived flexible enough to adjust the flux distribution onto the focal plane, which has expanded the application field of the high-flux solar simulator significantly. A model was built with Tracepro© to analyze the optical characterization of line-concentrating flux distribution of KIRAN-42, and the results show that, in spite of the spreading of lamps foci onto a line, thepeak flux is still reaching 1.4 MW/m2. Experimental characterizations were also conducted to study the real flux distribution of KIRAN-42 with line-concentrating, of which the peak flux is about 1 MW/m2. Divergence between experimental results and Tracepro©model should still be improved though the optical characterization of KIRAN-42 confirms the potential use of the solar simulator in a flexible way for different aiming strategies

    Non-Abelian Chern-Simons-Higgs vortices with a quartic potential

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    We have constructed numerically non-Abelian vortices in an SU(2) Chern-Simons-Higgs theory with a quartic Higgs potential. We have analyzed these solutions in detail by means of improved numerical codes and found some unexpected features we did not find when a sixth-order Higgs potential was used. The generic non-Abelian solutions have been generated by using their corresponding Abelian counterparts as initial guess. Typically, the energy of the non-Abelian solutions is lower than that of the corresponding Abelian one (except in certain regions of the parameter space). Regarding the angular momentum, the Abelian solutions possess the maximal value, although there exist non-Abelian solutions which reach that maximal value too. In order to classify the solutions it is useful to consider the non-Abelian solutions with asymptotically vanishing AtA_t component of the gauge potential, which may be labelled by an integer number mm. For vortex number n=3n=3 and above, we have found uniqueness violation: two different non-Abelian solutions with all the global charges equal. Finally, we have investigated the limit of infinity Higgs self-coupling parameter and found a piecewise Regge-like relation between the energy and the angular momentum.Comment: 9 pages, 13 figure

    Wear and friction of TiAlN/VN coatings against Al2O3 in air at room and elevated temperatures

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    TiAlN/VN multilayer coatings exhibit excellent dry sliding wear resistance and low friction coefficient, reported to be associated with the formation of self-lubricating V2O5. To investigate this hypothesis, dry sliding ball-on-disc wear tests of TiAlN/VN coatings on flat stainless steel substrates were undertaken against Al2O3 at 25 C, 300 C and 635 C in air. The coating exhibited increased wear rate with temperature. The friction coefficient was 0.53 at 25 C, which increased to 1.03 at 300 C and decreased to 0.46 at 635 C. Detailed investigation of the worn surfaces was undertaken using site-specific transmission electron microscopy (TEM) via focused ion beam (FIB) microscopy, along with Fourier transform infrared (FTIR) and Raman spectroscopy. Microstructure and tribo-induced chemical reactions at these temperatures were correlated with the coating’s wear and friction behaviour. The friction behaviour at room temperature is attributed to the presence of a thin hydrated tribofilm and the presence of V2O5 at high temperature

    The role of extracellular DNA in uranium precipitation and biomineralisation.

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    Bacterial extra polymeric substances (EPS) have been associated with the extracellular precipitation of uranium. Here we report findings on the biomineralisation of uranium, with extracellular DNA (eDNA) used as a model biomolecule representative of EPS. The complexation and precipitation of eDNA with uranium were investigated as a function of pH, ionic strength and varying concentrations of reactants. The role of phosphate moieties in the biomineralisation mechanism was studied by enzymatically releasing phosphate (ePO4) from eDNA compared to abiotic phosphate (aPO4). The eDNA-uranium precipitates and uranium minerals obtained were characterised by Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FT-IR) spectroscopy, Scanning Electron Microscopy-Energy Dispersive X-Ray analysis (SEM-EDX), X-Ray Powder Diffraction (XRD) and X-Ray Photoelectron Spectroscopy (XPS). ATR-FT-IR showed that at pH 5, the eDNA-uranium precipitation mechanism was predominantly mediated by interactions with phosphate moieties from eDNA. At pH 2, the uranium interactions with eDNA occur mainly through phosphate. The solubility equilibrium was dependent on pH with the formation of precipitate reduced as the pH increased. The XRD data confirmed the formation of a uranium phosphate precipitate when synthesised using ePO4. XPS and SEM-EDX studies showed the incorporation of carbon and nitrogen groups from the enzymatic orthophosphate hydrolysis on the obtained precipitated. These results suggested that the removal of uranium from solution occurs via two mechanisms: complexation by eDNA molecules and precipitation of a uranium phosphate mineral of the type (UO2HPO4)·xH2O by enzymatic orthophosphate hydrolysis. This demonstrated that eDNA from bacterial EPS is a key contributor to uranium biomineralisation

    Microsolvation of Mg2+, Ca2+: Strong influence of formal charges in hydrogen bond networks

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    A stochastic exploration of the quantum conformational spaces in the microsolvation of divalent cations with explicit consideration of up to six solvent molecules [Mg (H 2 O) n )]2+, (n = 3, 4, 5, 6) at the B3LYP, MP2, CCSD(T) levels is presented. We find several cases in which the formal charge in Mg2+ causes dissociation of water molecules in the first solvation shell, leaving a hydroxide ion available to interact with the central cation, the released proton being transferred to outer solvation shells in a Grotthus type mechanism; this particular finding sheds light on the capacity of Mg2+ to promote formation of hydroxide anions, a process necessary to regulate proton transfer in enzymes with exonuclease activity. Two distinct types of hydrogen bonds, scattered over a wide range of distances (1.35–2.15 Å) were identified. We find that in inner solvation shells, where hydrogen bond networks are severely disturbed, most of the interaction energies come from electrostatic and polarization+charge transfer, while in outer solvation shells the situation approximates that of pure water clusters

    Low X-ray Luminosity Galaxy Clusters. III: Weak Lensing Mass Determination at 0.18 << z << 0.70

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    This is the third of a series of papers of low X-ray luminosity galaxy clusters. In this work we present the weak lensing analysis of eight clusters, based on observations obtained with the Gemini Multi-Object Spectrograph in the gg', rr' and ii' passbands. For this purpose, we have developed a pipeline for the lensing analysis of ground-based images and we have performed tests applied to simulated data. We have determined the masses of seven galaxy clusters, six of them measured for the first time. For the four clusters with availably spectroscopic data, we find a general agreement between the velocity dispersions obtained via weak lensing assuming a Singular Isothermal Sphere profile, and those obtained from the redshift distribution of member galaxies. The correlation between our weak lensing mass determinations and the X-ray luminosities are suitably fitted by other observations of the MLXM-L_{X} relation and models
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