4,519 research outputs found
Discrete breathers for understanding reconstructive mineral processes at low temperatures
Reconstructive transformations in layered silicates need a high tem- perature
in order to be observed. However, very recently, some systems have been found
where transformation can be studied at temperatures 600 C below the lowest
experimental results previously reported, including sol-gel methods. We explore
the possible relation with the existence of intrinsic localized modes, known as
discrete breathers. We construct a model for nonlinear vibrations within the
cation layer, obtain their parameters and calculate them numerically, obtaining
their energies. Their statistics shows that although there are far less
breathers than phonons, there are much more above the activation energy, being
therefore a good candidate to explain the reconstructive transformations at low
temperature.Comment: 27 pages, 11 figure
Application of the superposition technique in conduction heat transfer for analysing arrays of shallow boreholes in ground source heat pump systems
A phase of liposomes with entangled tubular vesicles
An equilibrium phase belonging to the family of bilayer liposomes in ternary mixtures of dimyristoylphosphatidylcholine (DMPC), water, and geraniol (a biological alcohol derived from oil-soluble vitamins that acts as a cosurfactant) has been identified. Electron and optical microscopy reveal the phase, labeled Ltv, to be composed of highly entangled tubular vesicles. In situ x-ray diffraction confirms that the tubule walls are multilamellar with the lipids in the chain-melted state. Macroscopic observations show that the Ltv phase coexists with the well-known L4 phase of spherical vesicles and a bulk L alpha phase. However, the defining characteristic of the Ltv phase is the Weissenberg rod climbing effect under shear, which results from its polymer-like entangled microstructure
Caracterización quÃmica, perfil de ácidos grasos y actividad antioxidante del mesocarpio de la fruta Gustavia macarenensis y su aceite de la región amazónica de Ecuador como fuente no convencional de aceite vegetal
To our knowledge, this study is the first to report on the nutritional characterization, bioactive compounds and antioxidant activity of Amazonian G. macarenensis fruit. The fatty acid profile was determined using a high performance liquid chromatography analysis. The total phenolic content and antioxidant activity were determined using Folin Ciocalteu’s method and by radical scavenging activity, respectively. Moreover, a cluster analysis was carried out in order to classify the G. macarenensis fruit oil according to its fatty acid profile. Seven Fisher linear discriminant functions were obtained from the discriminant analysis. These models allow one to classify new fruits on the basis of their fatty acid profile. A high value for total lipids was obtained (53.57%). Its main components were palmitic and oleic acid. The TPC value (156.49 ± 2.62 mg GAE/Kg of oil) obtained from the G. macarenensis fruit pulp oil is higher than what was reported for some olive oil and Brazilian mango oil varieties.Hasta donde sabemos, este estudio serÃa el primero sobre la caracterización nutricional, los compuestos bioactivos y la actividad antioxidante de la fruta amazónica G. macarenensis. El perfil de ácidos grasos se determinó mediante análisis de cromatografÃa lÃquida de alta resolución. El contenido fenólico total y la actividad antioxidante se determinaron utilizando el método de Folin Ciocalteu y la medida de la actividad de eliminación de radicales, respectivamente. Además, se realizó un análisis de conglomerados para clasificar el aceite de fruta G. macarenensis según su perfil de ácidos grasos. Se obtuvieron siete funciones discriminantes lineales de Fisher a partir del análisis discriminante. Estos modelos permiten clasificar frutas nuevas en función de su perfil de ácidos grasos. Se obtuvo un alto valor para el total de lÃpidos (53.57%). Sus componentes principales son los ácidos palmÃtico y oleico. El valor TPC (156.49 ± 2.62 mg GAE/Kg de aceite) obtenido del aceite de pulpa de fruta de G. macarenensis es más alto que el que se reporta para algunas variedades de aceite de oliva y aceite de mango brasileño
Permissive effect of dexamethasone on the increase of proenkephalin mRNA induced by depolarization of chromaffin cells.
Immediate effects of diamond burr debridement in patients with spontaneous chronic corneal epithelial defects, light and electron microscopic evaluation
PANIC: the new panoramic NIR camera for Calar Alto
PANIC is a wide-field NIR camera, which is currently under development for
the Calar Alto observatory (CAHA) in Spain. It uses a mosaic of four Hawaii-2RG
detectors and covers the spectral range from 0.8-2.5 micron(z to K-band). The
field-of-view is 30x30 arcmin. This instrument can be used at the 2.2m
telescope (0.45arcsec/pixel, 0.5x0.5 degree FOV) and at the 3.5m telescope
(0.23arcsec/pixel, 0.25x0.25 degree FOV). The operating temperature is about
77K, achieved by liquid Nitrogen cooling. The cryogenic optics has three flat
folding mirrors with diameters up to 282 mm and nine lenses with diameters
between 130 mm and 255 mm. A compact filter unit can carry up to 19 filters
distributed over four filter wheels. Narrow band (1%) filters can be used. The
instrument has a diameter of 1.1 m and it is about 1 m long. The weight limit
of 400 kg at the 2.2m telescope requires a light-weight cryostat design. The
aluminium vacuum vessel and radiation shield have wall thicknesses of only 6 mm
and 3 mm respectively.Comment: This paper has been presented in the SPIE of Astronomical Telescopes
and Instrumentation 2008 in Marseille (France
A comparison of analytical and numerical model predictions of shallow soil temperature variation with experimental measurements
The file attached to this record is the author's final peer reviewed version. The Publisher's final version can be found by following the DOI link.In several fields of enquiry such as geothermal energy, geology and agriculture, it is of interest to study the thermal behaviour of shallow soils. For this, several analytical and numerical methodologies have been proposed to analyse the temperature variation of the soil in the short and long term. In this paper, a comparative study of different models (sinusoidal, semi-infinite and finite difference method) is conducted to estimate the shallow soil temperature variation in the short and long term. The models were compared with hourly experimental measured data of soil temperature in Leicester, UK, at depths between 0.75 and 2.75 m. The results show that the sinusoidal model is not appropriate to evaluate the short-term temperature variations, such as hourly or daily fluctuations. Likewise, this model is highly affected by the undisturbed ground temperature and can lead to very high errors. Regarding the semi-infinite model, it is accurate enough to predict the short-term temperature variation. However, it is useless to predict the long-term variation at depths greater than 1 m. The finite difference method (FDM) considering the air temperature as a boundary condition for the soil surface is the most accurate approach for estimating both short and long-term temperature variations while the FDM with heat flux as boundary condition is the least accurate approach due to the uncertainty of the assumed parameters. The ranges of errors for the sinusoidal, semi-infinite and FDM are found to be from 76.09 to 142.13%, 12.11 to 104.88% and 1.82 to 28.14% respectively
COMPLEMENTARITY AMONG INNOVATION STRATEGIES: EVIDENCE FROM COLOMBIA
Using Innovation Survey Data from Colombia, we apply a new methodology to assess complementarityrelationships among different innovative inputs. This approach allows scholars to preventserious data drawbacks, such as the lack of proper performance measures and is also fairly general,allowing cross equations restrictions. Empirically, we found evidence for the absorptive capacityhypothesis and the key role played by ICT
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