Thermal decomposition of some boracites

The thermal decompn. under Ar of the boracites M3B7O13X (M = divalent metal ion, X = halogen ion or OH-) was studied by thermogravimetry (TG) and DTA for the compns. MgCl, MgOH, CrCl, CrBr, CrI, MnCl, MnBr, MnI, FeCl, FeBr, FeI, CoCl, CoBr, CoI, NiCl, NiBr, NiI, CuCl, CuBr, ZnCl, ZnBr, ZnI, CdCl, CdBr and DI. The lithium boracites Li4B7O12X (X = Cl and Br) were also studied. The stability of the boracites systematically decreases in the order MCl > MBr > MI. The most stable boracite is CrCl (1% wt. loss at 1242°) and the least stable one studied here is MgoH (1% wt. loss at 717°)

Confirmatory factor analysis of the Beck Depression inventory in obese individuals seeking surgery

Background : The Beck Depression Inventory (BDI) is frequently employed as measure of depression in studies of obesity. The aim of the study was to assess the factorial structure of the BDI in obese patients prior to bariatric surgery. Methods : Confirmatory factor analysis was conducted on the current published factor analyses of the BDI. Three published models were initially analysed with two additional modified models subsequently included. A sample of 285 patients presenting for Lap-Band® surgery was used. Results : The published bariatric model by Munoz et al. was not an adequate fit to the data. The general model by Shafer et al. was a good fit to the data but had substantial limitations. The weight loss item did not significantly load on any factor in either model. A modified Shafer model and a proposed model were tested, and both were found to be a good fit to the data with minimal differences between the two. A proposed model, in which two items, weight loss and appetite, were omitted, was suggested to be the better model with good reliability. Conclusions : The previously published factor analysis in bariatric candidates by Munoz et al. was a poor fit to the data, and use of this factor structure should be seriously reconsidered within the obese population. The hypothesised model was the best fit to the data. The findings of the study suggest that the existing published models are not adequate for investigating depression in obese patients seeking surgery