The nature of the potassium compound acting as a promoter in iron-alumina catalysts for ammonia synthesis

The chemical form of the potassium promoter on an iron-alumina catalyst during ammonia synthesis has been studied by two methods, viz, (i) the measurement of the equilibrium constant of the process KNH2 + H2 KH + NH3, and (ii) chemical analysis of the used catalyst. The equilibrium constant measurements gave K723 = (12.9 ± 0.5) × 10−3, ΔHf2980(KNH2) = −119 ± 3 kJ mol−1 and S2980(KNH2) = 109 ± 4 J mol−1 K−1. The chemical analysis showed that no KNH2 is present on the catalyst during synthesis. From these results and with the aid of thermodynamic considerations it is concluded that KNH2, K and K2O are not stable compounds under conditions of ammonia synthesis. X-Ray diffraction showed that part of the potassium reacts with Al2O3, probably leaving part of the potassium in the form of KOH which is quite stable under ammonia synthesis conditions

Thaan Vuzha Nilam Tharisu: the land without a farmer becomes barren

This report forms a part of the international research project on policy and sustainable agriculture, Policies that Work for Sustainable Agriculture and Regenerated Rural Economies. The report details the findings of one of the constituent studies, undertaken by an Indian NGO, the Society for People's Education and Economic Change (SPEECH). The Importance of this project is that it concentrated on rainfed rather than irrigated agriculture - i.e. the sharp end of rural development in India, and that the focus was very much on the micro-level, looking at policy as seen from the ground. One of the recurring themes throughout the research was the importance of appreciating people as individuals, and in this spirit some of the personal qualities of the research team are shared. The research covers events in sites in the Virudhunagar district of Tamilnadu: Tiruchuli Panchayat Union and the Villur chain of tanks. This is an essentially rural area, where the need for sustainable forms of agriculture and rural livelihoods is clear. The political landscape is fractured and complex (§2.3), and the officials with the responsibility of implementing policy face significant obstacles and disincentives in doing so in response to the needs of local communities

New forms of BRST symmetry in rigid rotor

We derive the different forms of BRST symmetry by using the Batalin-Fradkin-Vilkovisky formalism in a rigid rotor. The so called "dual-BRST" symmetry is obtained from usual BRST symmetry by making a canonical transformation in the ghost sector. On the other hand, a canonical transformation in the sector involving Lagrange multiplier and its corresponding momentum leads to a new form of BRST as well as dual-BRST symmetry.Comment: 10 Pages, revtex, No Fig

Methodology development for evaluation of selective-fidelity rotorcraft simulation

This paper addressed the initial step toward the goal of establishing performance and handling qualities acceptance criteria for realtime rotorcraft simulators through a planned research effort to quantify the system capabilities of 'selective fidelity' simulators. Within this framework the simulator is then classified based on the required task. The simulator is evaluated by separating the various subsystems (visual, motion, etc.) and applying corresponding fidelity constants based on the specific task. This methodology not only provides an assessment technique, but also provides a technique to determine the required levels of subsystem fidelity for a specific task

Aviation technology research plan rotary wing program development and evaluation of performance

Issued as Progress reports [nos. 1-2], and Final report, Project no. E-16-M08Final report has title: Aviation technology research plan rotary wing program development and evaluation of performanceFinal report has co-author: J.V.R. Prasa

Geomagnetic storm effects on GPS based navigation

The energetic events on the sun, solar wind and subsequent effects on the Earth's geomagnetic field and upper atmosphere (ionosphere) comprise space weather. Modern navigation systems that use radio-wave signals, reflecting from or propagating through the ionosphere as a means of determining range or distance, are vulnerable to a variety of effects that can degrade the performance of the navigational systems. In particular, the Global Positioning System (GPS) that uses a constellation of earth orbiting satellites are affected due to the space weather phenomena. <br><br> Studies made during two successive geomagnetic storms that occurred during the period from 8 to 12 November 2004, have clearly revealed the adverse affects on the GPS range delay as inferred from the Total Electron Content (TEC) measurements made from a chain of seven dual frequency GPS receivers installed in the Indian sector. Significant increases in TEC at the Equatorial Ionization anomaly crest region are observed, resulting in increased range delay during the periods of the storm activity. Further, the storm time rapid changes occurring in TEC resulted in a number of phase slips in the GPS signal compared to those on quiet days. These phase slips often result in the loss of lock of the GPS receivers, similar to those that occur during strong(>10 dB) L-band scintillation events, adversely affecting the GPS based navigation

The mini trawl fishery of Kerala

Mini trawl operation started in Kerala during 1987, is another post motorisation innovation like the ring seine by the artisanal fishers. During 1987-2002, annual mini trawl landings ranged between 1,500 and 18,600 tonnes. The minimum landing was in 1987, when this gear was introduced for the first time in Kerala and the peak landings of 18,600 tonnes was during 1997. The low investment of the mini trawls at the initial stage has attracted more fishermen. A trend in component group landings and seasonal trends have been cited in this information. They could earn more for their livelihood with less investment. Prawns which come to the nearby shore for breeding, are caught by this gear. Appropriate management measures need to be taken to regulate this fishery for ensuring sustrainbility and better livelihood for the artisanal sector