Properties of Mg-doped Nd-Ba-Cu-O generic seed crystals for the top seeded melt growth of (RE)-Ba-Cu-O bulk superconductors

We have recently developed a new generic seed crystal that has been used successfully to fabricate any oriented, single grain (RE)-Ba-Cu-O bulk superconductor by a cold seeding technique. In this paper we report the chemical, structural and microstructural properties of these seed crystals, including the variation of melting point, crystallographic parameters and volume fraction of Mg-rich inclusions in the Nd1 + xBa 2-x(Cu1-yMgy)3Oz matrix as a function of externally added MgO content. The influence of Mg-doping on the superconducting transition temperatures of YBCO grains fabricated using these seeds is investigated. Finally, an optimum MgO content of the generic seed that effectively controls the orientation of the seeded grain without compromising its superconducting properties is suggested from the many seed crystals fabricated with a wide range of Mg-rich addition

Spin-polarized tunneling spectroscopic studies of the intrinsic heterogeneity and pseudogap phenomena in colossal magnetoresistive manganite La_{0.7}Ca_{0.3}MnO_{3}

Spatially resolved tunneling spectroscopic studies of colossal magnetoresistive (CMR) manganite $\rm La_{0.7}Ca_{0.3}MnO_3$ (LCMO) epitaxial films on $\rm (LaAlO_3)_{0.3}(Sr_2AlTaO_6)_{0.7}$ substrate are investigated as functions of temperature, magnetic field and spin polarization by means of scanning tunneling spectroscopy. Systematic surveys of the tunneling spectra taken with Pt/Ir tips reveal spatial variations on the length scale of a few hundred nanometers in the ferromagnetic state, which may be attributed to the intrinsic heterogeneity of the manganites due to their tendency towards phase separation. The electronic heterogeneity is found to decrease either with increasing field at low temperatures or at temperatures above all magnetic ordering temperatures. On the other hand, spectra taken with Cr-coated tips are consistent with convoluted electronic properties of both LCMO and Cr. In particular, for temperatures below the magnetic ordering temperatures of both Cr and LCMO, the magnetic-field dependent tunneling spectra may be quantitatively explained by the scenario of spin-polarized tunneling in a spin-valve configuration. Moreover, a low-energy insulating energy gap $\sim 0.6$ eV commonly found in the tunneling conductance spectra of bulk metallic LCMO at $T \to 0$ may be attributed to a surface ferromagnetic insulating (FI) phase, as evidenced by its spin filtering effect at low temperatures and vanishing gap value above the Curie temperature. Additionally, temperature independent pseudogap (PG) phenomena existing primarily along the boundaries of magnetic domains are observed in the zero-field tunneling spectra. The PG becomes strongly suppressed by applied magnetic fields at low temperatures when the tunneling spectra of LCMO become highly homogeneous. These findings suggest that the occurrence PG is associated with the electronic heterogeneity of the manganites.Comment: 15 pages, 15 figures. Published in Physical Review B. Corresponding author: Nai-Chang Yeh (E-mail: [email protected]

Self-consistent tilted-axis-cranking study of triaxial strongly deformed bands in 158^{158}Er at ultrahigh spin

Stimulated by recent experimental discoveries, triaxial strongly deformed (TSD) states in $^{158}$Er at ultrahigh spins have been studied by means of the Skyrme-Hartree-Fock model and the tilted-axis-cranking method. Restricting the rotational axis to one of the principal axes -- as done in previous cranking calculations -- two well-defined TSD minima in the total Routhian surface are found for a given configuration: one with positive and another with negative triaxial deformation $\gamma$. By allowing the rotational axis to change direction, the higher-energy minimum is shown to be a saddle point. This resolves the long-standing question of the physical interpretation of the two triaxial minima at a very similar quadrupole shape obtained in the principal axis cranking approach. Several TSD configurations have been predicted, including a highly deformed band expected to cross lesser elongated TSD bands at the highest spins. Its transitional quadrupole moment $Q_t \approx 10.5$\,eb is close to the measured value of $\sim$11\,eb; hence, it is a candidate for the structure observed in experiment.Comment: 5 pages, 5 figure

Exploring the biochemistry at the extracellular redox frontier of bacterial mineral Fe(III) respiration

Many species of the bacterial Shewanella genus are notable for their ability to respire in anoxic environments utilizing insoluble minerals of Fe(III) and Mn(IV) as extracellular electron acceptors. In Shewanella oneidensis, the process is dependent on the decahaem electron-transport proteins that lie at the extracellular face of the outer membrane where they can contact the insoluble mineral substrates. These extracellular proteins are charged with electrons provided by an inter-membrane electron-transfer pathway that links the extracellular face of the outer membrane with the inner cytoplasmic membrane and thereby intracellular electron sources. In the present paper, we consider the common structural features of two of these outer-membrane decahaem cytochromes, MtrC and MtrF, and bring this together with biochemical, spectroscopic and voltammetric data to identify common and distinct properties of these prototypical members of different clades of the outer-membrane decahaem cytochrome superfamily

Exotic Kondo crossover in a wide temperature region in the topological Kondo insulator SmB6 revealed by high-resolution ARPES

Temperature dependence of the electronic structure of SmB6 is studied by high-resolution ARPES down to 1 K. We demonstrate that there is no essential difference for the dispersions of the surface states below and above the resistivity saturating anomaly (~ 3.5 K). Quantitative analyses of the surface states indicate that the quasi-particle scattering rate increases linearly as a function of temperature and binding energy, which differs from Fermi-Liquid behavior. Most intriguingly, we observe that the hybridization between the d and f states builds gradually over a wide temperature region (30 K < T < 110 K). The surface states appear when the hybridization starts to develop. Our detailed temperature-dependence results give a complete interpretation of the exotic resistivity result of SmB6, as well as the discrepancies among experimental results concerning the temperature regions in which the topological surface states emerge and the Kondo gap opens, and give new insights into the exotic Kondo crossover and its relationship with the topological surface states in the topological Kondo insulator SmB6.Comment: 8 pages, 5 figure

Clustering in Geo-Social Networks

The rapid growth of Geo-Social Networks (GeoSNs) provides a new and rich form of data. Users of GeoSNs can capture their geographic locations and share them with other users via an operation named checkin. Thus, GeoSNs can track the connections (and the time of these connections) of geographic data to their users. In addition, the users are organized in a social network, which can be extended to a heterogeneous network if the connections to places via checkins are also considered. The goal of this paper is to analyze the opportunities in clustering this rich form of data. We first present a model for clustering geographic locations, based on GeoSN data. Then, we discuss how this model can be extended to consider temporal information from checkins. Finally, we study how the accuracy of community detection approaches can be improved by taking into account the checkins of users in a GeoSN.published_or_final_versio