102 research outputs found
Ce-L3-XAS study of the temperature dependence of the 4f occupancy in the Kondo system Ce2Rh3Al9
We have used temperature dependent x-ray absorption at the Ce-L3 edge to
investigate the recently discovered Kondo compound Ce2Rh3Al9. The systematic
changes of the spectral lineshape with decreasing temperature are analyzed and
found to be related to a change in the occupation number, n_f, as the
system undergoes a transition into a Kondo state. The temperature dependence of
indicates a characteristic temperature of 150K, which is clearly related
with the high temperature anomaly observed in the magnetic susceptibility of
the same system. The further anomaly observed in the resistivity of this system
at low temperature (ca. 20K) has no effect on n_f and is thus not of Kondo
origin.Comment: 7 pages, three figures, submitted to PR
Photoemission and x-ray absorption study of MgC_(1-x)Ni_3
We investigated electronic structure of MgC_(1-x)Ni_3 with photoemission and
x-ray absorption spectroscopy. Both results show that overall band structure is
in reasonable agreement with band structure calculations including the
existence of von Hove singularity (vHs)near E_F. However, we find that the
sharp vHs peak theoretically predicted near the E_F is substantially
suppressed. As for the Ni core level and absorption spectrum, there exist the
satellites of Ni 2p which have a little larger energy separation and reduced
intensity compared to the case of Ni-metal. These facts indicate that
correlation effects among Ni 3d electrons may be important to understand
various physical properties.Comment: 12 pages, 4 figure
Superconducting gap in the presence of bilayer splitting in underdoped Bi(Pb)2212
The clearly resolved bilayer splitting in ARPES spectra of the underdoped
Pb-Bi2212 compound rises the question of how the bonding and antibonding sheets
of the Fermi surface are gapped in the superconducting state. Here we compare
the superconducting gaps for both split components and show that within the
experimental uncertainties they are identical. By tuning the relative intensity
of the bonding and antibonding bands using different excitation conditions we
determine the precise {\bf k}-dependence of the leading edge gap. Significant
deviations from the simple cos()-cos() gap function for the
studied doping level are detected.Comment: 5 pages, 4 figures (revtex4
Hole Doping Evolution of the Quasiparticle Band in Models of Strongly Correlated Electrons for the High-T_c Cuprates
Quantum Monte Carlo (QMC) and Maximum Entropy (ME) techniques are used to
study the spectral function of the one band Hubbard model
in strong coupling including a next-nearest-neighbor electronic hopping with
amplitude . These values of parameters are chosen to improve the
comparison of the Hubbard model with angle-resolved photoemission (ARPES) data
for . A narrow quasiparticle (q.p.) band is observed in the
QMC analysis at the temperature of the simulation , both at and away
from half-filling. Such a narrow band produces a large accumulation of weight
in the density of states at the top of the valence band. As the electronic
density decreases further away from half-filling, the chemical
potential travels through this energy window with a large number of states, and
by it has crossed it entirely. The region near momentum
and in the spectral function is more sensitive to doping
than momenta along the diagonal from to . The evolution with
hole density of the quasiparticle dispersion contains some of the features
observed in recent ARPES data in the underdoped regime. For sufficiently large
hole densities the ``flat'' bands at cross the Fermi energy, a
prediction that could be tested with ARPES techniques applied to overdoped
cuprates. The population of the q.p. band introduces a {\it hidden} density in
the system which produces interesting consequences when the quasiparticles are
assumed to interact through antiferromagnetic fluctuations and studied with the
BCS gap equation formalism. In particular, a region of extended s-wave is found
to compete with d-wave in the overdoped regime, i.e. when the chemical
potential has almost entirely crossed the q.p.Comment: 14 pages, Revtex, with 13 embedded ps figures, submitted to Phys.
Rev. B., minor modifications in the text and in figures 1b, 2b, 3b, 4b, and
6
Matrilineal diversity and population history of Norwegians
Background
While well known for its Viking past, Norway's population history and the influences that have shaped its genetic diversity are less well understood. This is particularly true with respect to its demography, migration patterns, and dialectal regions, despite there being curated historical records for the past several centuries. In this study, we undertook an analysis of mitochondrial DNA (mtDNA) diversity within the country to elaborate this history from a matrilineal genetic perspective.
Methods
We aggregated 1174 partial modern Norwegian mtDNA sequences from the published literature and subjected them to detailed statistical and phylogenetic analysis by dialectal regions and localities. We further contextualized the matrilineal ancestry of modern Norwegians with data from Mesolithic, Iron Age, and historic period populations.
Results
Modern Norwegian mtDNAs fell into eight West Eurasian (N, HV, JT, I, U, K, X, W), five East Eurasian (A, F, G, N11, Z), and one African (L2) haplogroups. Pairwise analysis of molecular variance (AMOVA) estimates for all Norwegians indicated they were differentiated from each other at 1.68% (p < 0.001). Norwegians within the same dialectal region also showed genetic similarities to each other, although differences between subpopulations within dialectal regions were also observed. In addition, certain mtDNA lineages in modern Norwegians were also found among prehistoric and historic period populations, suggesting some level of genetic continuity over hundreds to many thousands of years.
Conclusions
This analysis of mtDNA diversity provides a detailed picture of the genetic variation within Norway in light of its topography, settlement history, and historical migrations over the past several centuries.publishedVersio
Variation in Soil Respiration across Soil and Vegetation Types in an Alpine Valley.
BACKGROUND AND AIMS: Soils of mountain regions and their associated plant communities are highly diverse over short spatial scales due to the heterogeneity of geological substrates and highly dynamic geomorphic processes. The consequences of this heterogeneity for biogeochemical transfers, however, remain poorly documented. The objective of this study was to quantify the variability of soil-surface carbon dioxide efflux, known as soil respiration (Rs), across soil and vegetation types in an Alpine valley. To this aim, we measured Rs rates during the peak and late growing season (July-October) in 48 plots located in pastoral areas of a small valley of the Swiss Alps.
FINDINGS: Four herbaceous vegetation types were identified, three corresponding to different stages of primary succession (Petasition paradoxi in pioneer conditions, Seslerion in more advanced stages and Poion alpinae replacing the climactic forests), as well as one (Rumicion alpinae) corresponding to eutrophic grasslands in intensively grazed areas. Soils were developed on calcareous alluvial and colluvial fan deposits and were classified into six types including three Fluvisols grades and three Cambisols grades. Plant and soil types had a high level of co-occurrence. The strongest predictor of Rs was soil temperature, yet we detected additional explanatory power of sampling month, showing that temporal variation was not entirely reducible to variations in temperature. Vegetation and soil types were also major determinants of Rs. During the warmest month (August), Rs rates varied by over a factor three between soil and vegetation types, ranging from 2.5 μmol m-2 s-1 in pioneer environments (Petasition on Very Young Fluvisols) to 8.5 μmol m-2 s-1 in differentiated soils supporting nitrophilous species (Rumicion on Calcaric Cambisols).
CONCLUSIONS: Overall, this study provides quantitative estimates of spatial and temporal variability in Rs in the mountain environment, and demonstrates that estimations of soil carbon efflux at the watershed scale in complex geomorphic terrain have to account for soil and vegetation heterogeneity
Evaluating model outputs using integrated global speleothem records of climate change since the last glacial
Although quantitative isotope data from speleothems has been used to evaluate isotope-enabled model simulations, currently no consensus exists regarding the most appropriate methodology through which to achieve this. A number of modelling groups will be running isotope-enabled palaeoclimate simulations in the framework of the Coupled Model Intercomparison Project Phase 6, so it is timely to evaluate different approaches to using the speleothem data for data–model comparisons. Here, we illustrate this using 456 globally distributed speleothem δ18O records from an updated version of the Speleothem Isotopes Synthesis and Analysis (SISAL) database and palaeoclimate simulations generated using the ECHAM5-wiso isotope-enabled atmospheric circulation model. We show that the SISAL records reproduce the first-order spatial patterns of isotopic variability in the modern day, strongly supporting the application of this dataset for evaluating model-derived isotope variability into the past. However, the discontinuous nature of many speleothem records complicates the process of procuring large numbers of records if data–model comparisons are made using the traditional approach of comparing anomalies between a control period and a given palaeoclimate experiment. To circumvent this issue, we illustrate techniques through which the absolute isotope values during any time period could be used for model evaluation. Specifically, we show that speleothem isotope records allow an assessment of a model's ability to simulate spatial isotopic trends. Our analyses provide a protocol for using speleothem isotope data for model evaluation, including screening the observations to take into account the impact of speleothem mineralogy on δ18O values, the optimum period for the modern observational baseline and the selection of an appropriate time window for creating means of the isotope data for palaeo-time-slices
Review of MXenes as new nanomaterials for energy storage/delivery and selected environmental applications
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