1,256 research outputs found
AC electrokinetic phenomena over semiconductive surfaces: effective electric boundary conditions and their applications
Electrokinetic boundary conditions are derived for AC electrokinetic (ACEK)
phenomena over leaky dielectric (i.e., semiconducting) surfaces. Such boundary
conditions correlate the electric potentials across the
semiconductor-electrolyte interface (consisting of the electric double layer
(EDL) inside the electrolyte solutions and the space charge layer (SCL) inside
the semiconductors) under AC electric fields with arbitrary wave forms. The
present electrokinetic boundary conditions allow for evaluation of induced zeta
potential contributed by both bond charges (due to electric polarization) and
free charges (due to electric conduction) from the leaky dielectric materials.
Subsequently, we demonstrate the applications of these boundary conditions in
analyzing the ACEK phenomena around a semiconducting cylinder. It is concluded
that the flow circulations exist around the semiconducting cylinder and are
shown to be stronger under an AC field with lower frequency and around a
cylinder with higher conductivity.Comment: 29 pages, 4 figure
Spatio-temporal patterns in a mechanical model for mesenchymal morphogenesis
We present an in-depth study of spatio-temporal patterns in a simplified version of a mechanical model for pattern formation in mesenchymal morphogenesis. We briefly motivate the derivation of the model and show how to choose realistic boundary conditions to make the system well-posed. We firstly consider one-dimensional patterns and carry out a nonlinear perturbation analysis for the case where the uniform steady state is linearly unstable to a single mode. In two-dimensions, we show that if the displacement field in the model is represented as a sum of orthogonal parts, then the model can be decomposed into two sub-models, only one of which is capable of generating pattern. We thus focus on this particular sub-model. We present a nonlinear analysis of spatio-temporal patterns exhibited by the sub-model on a square domain and discuss mode interaction. Our analysis shows that when a two-dimensional mode number admits two or more degenerate mode pairs, the solution of the full nonlinear system of partial differential equations is a mixed mode solution in which all the degenerate mode pairs are represented in a frequency locked oscillation
Friedel Oscillations and Charge-density Waves Pinning in Quasi-one-dimensional Conductors: An X-ray Access
We present an x-ray diffraction study of the Vanadium-doped blue bronze
K0.3(Mo0.972V0.028)O3. At low temperature, we have observed both an intensity
asymmetry of the +-2kF satellite reflections relative to the pure compound, and
a profile asymmetry of each satellite reflections. We show that the profile
asymmetry is due to Friedel oscillation around the V substituant and that the
intensity asymmetry is related to the charge density wave (CDW) pinning. These
two effects, intensity and profile asymmetries, gives for the first time access
to the local properties of CDW in disordered systems, including the pinning and
even the phase shift of FOs.Comment: 4 pages REVTEX, 5 figure
Random division of an interval
The well-known relation between random division of an interval and the Poisson process is interpreted as a Laplace transformation. With the use of this interpretation a number of (in part known) results is derived very easily
Sandwich mixer–reactor: influence of the diffusion coefficient and flow rate ratios
A sandwich mixer consists of mixing two solutions in a channel, one central laminar flow being sandwiched between two outer flow solutions. The present numerical study considers the convection– diffusion of two reacting species A and B, provided respectively by the two incoming solutions. The simulations show how the diffusion coefficient, flow rate and species concentration ratios influence, via the transversal diffusion length and reaction kinetics, the reaction extent at the end of the sandwich mixer. First, this extent can be enhanced up to 60% if the species with the lowest diffusion coefficient is located in the outer solutions where the flow velocity is small compared to that of the central part (higher residence time). Secondly, decreasing the outer flow rates (to confine the reaction close to the walls) and increasing the local concentration to keep the same flux ratio improve the extent by 300%. Comparison with a bi-lamination passive mixer, with an ideal mixer and an electro-osmotic driven flow mixer is presented. These conclusions are also demonstrated for consecutive reactions, showing an amplification of the effects described above. The results are also presented versus the residence time in the mixer–reactor to show the time window for which the gain is appreciable
Ginzburg-Landau theory of phase transitions in quasi-one-dimensional systems
A wide range of quasi-one-dimensional materials, consisting of weakly coupled
chains, undergo three-dimensional phase transitions that can be described by a
complex order parameter. A Ginzburg-Landau theory is derived for such a
transition. It is shown that intrachain fluctuations in the order parameter
play a crucial role and must be treated exactly. The effect of these
fluctuations is determined by a single dimensionless parameter. The
three-dimensional transition temperature, the associated specific heat jump,
coherence lengths, and width of the critical region, are computed assuming that
the single chain Ginzburg-Landau coefficients are independent of temperature.
The width of the critical region, estimated from the Ginzburg criterion, is
virtually parameter independent, being about 5-8 per cent of the transition
temperature. To appear in {\it Physical Review B,} March 1, 1995.Comment: 15 pages, RevTeX, 5 figures in uuencoded compressed tar file
Electrokinetic supercharging for highly efficient peptide preconcentration in capillary zone electrophoresis
Electrokinetic supercharging has been integrated in CZE for the development of a highly sensitive methodology for protein tryptic digest analysis. A careful choice of the experimental conditions led to sensitivity enhancement factors between 1000 and 10 000 whilst maintaining a satisfactory resolution. Peptides in the low nanomolar concentration range have been detected despite the use of the poorly sensitive UV absorbance detection mode. The buffer system used in this study is fully suitable for coupling CE to MS
Noninvasive mechanical ventilation in high-risk pulmonary infections: a clinical review
The aim of this article was to review the role of noninvasive ventilation (NIV) in acute pulmonary infectious diseases, such as severe acute respiratory syndrome (SARS), H1N1 and tuberculosis, and to assess the risk of disease transmission with the use of NIV from patients to healthcare workers. We performed a clinical review by searching Medline and EMBASE. These databases were searched for articles on "clinical trials" and "randomised controlled trials". The keywords selected were non-invasive ventilation pulmonary infections, influenza-A (H1N1), SARS and tuberculosis. These terms were cross-referenced with the following keywords: health care workers, airborne infections, complications, intensive care unit and pandemic. The members of the International NIV Network examined the major results regarding NIV applications and SARS, H1N1 and tuberculosis. Cross-referencing mechanical ventilation with SARS yielded 76 studies, of which 10 studies involved the use of NIV and five were ultimately selected for inclusion in this review. Cross-referencing with H1N1 yielded 275 studies, of which 27 involved NIV. Of these, 22 were selected for review. Cross-referencing with tuberculosis yielded 285 studies, of which 15 involved NIV and from these seven were selected. In total 34 studies were selected for this review. NIV, when applied early in selected patients with SARS, H1N1 and acute pulmonary tuberculosis infections, can reverse respiratory failure. There are only a few reports of infectious disease transmission among healthcare workers
Capillary Electrophoresis as a Second Dimension to Isoelectric Focusing for Peptide Separation
Capillary zone electrophoresis and carrier ampholytes based capillary electrophoresis have been used as a second separation step to Off-Gel isoelectric focusing for the analysis of complex peptide mixtures. A tryptic digest of four proteins (bovine serum albumin, β-lactoglobulin, horse myoglobin, cytochrome c) has been chosen as a peptide test mixture. After assessment of different modes of capillary electrophoresis as a second dimension to Off-Gel isoelectric focusing, the optimized two-dimensional platforms provide a degree of orthogonality comparable to state-of-the-art multidimensional liquid chromatography systems as well as a practical peak capacity above 700
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