Scanning tunneling spectroscopy of layers of superconducting 2H-TaSe2_\textbf{2}: Evidence for a zero bias anomaly in single layers

We report a characterization of surfaces of the dichalcogenide TaSe$_2$ using scanning tunneling microscopy and spectroscopy (STM/S) at 150 mK. When the top layer has the 2H structure and the layer immediately below the 1T structure, we find a singular spatial dependence of the tunneling conductance below 1 K, changing from a zero bias peak on top of Se atoms to a gap in between Se atoms. The zero bias peak is additionally modulated by the commensurate $3a_0 \times 3a_0$ charge density wave of 2H-TaSe$_2$. Multilayers of 2H-TaSe$_2$ show a spatially homogeneous superconducting gap with a critical temperature also of 1 K. We discuss possible origins for the peculiar tunneling conductance in single layers.Comment: 10 pages, 10 figure

Possible Magnetic Chirality in Optically Chiral Magnet [Cr(CN)6_6][Mn(SS)-pnH(H2_2O)](H2_2O) Probed by Muon Spin Rotation and Relaxation

Local magnetic fields in a molecule-based optically chiral magnet [Cr(CN)$_6$][Mn($S$)-pnH(H$_2$O)](H$_2$O) (GN-S) and its enantiomer (GN-R) are studied by means of muon spin rotation and relaxation (muSR). Detailed analysis of muon precession signals under zero field observed below T_c supports the average magnetic structure suggested by neutron powder diffraction. Moreover, comparison of muSR spectra between GN-S and GN-R suggests that they are a pair of complete optical isomers in terms of both crystallographic and magnetic structure. Possibility of magnetic chirality in such a pair is discussed.Comment: 5 pages, 5 figures, submitted to J. Phys. Soc. Jp

REVIEW OF CFD SIMULATION OF OXY-COAL COMBUSTION FOR ELETRICAL POWER GENERATION: OPPORTUNITIES AND CHALLENGES

The oxy-combustion has generated significant interested for reduction of CO2 emission when the fossil fuel is coal, due to simplification on the separation process of CO2 from the flue gas, it can be more easily stored in reservoir. The CFD numerical simulation techniques in oxy-coal combustion has the potential to contribute to designers in cost savings and reduced computational time; Furthermore, such techniques also provide a robust tool for better understanding and description of the aerothermodynamics processes involved, as well as, aiding the design of most efficient furnaces. However, to obtain representative results of the physical phenomena, the numerical models employed by CFD needs to be suitable for oxy-coal combustion. So, the aim of the paper is to carry out a review of the recent models that are being used for turbulence, combustion and pollutant emissions. Moreover, it is shown a comparison of different results obtained in the numerical simulation of oxy-coal combustion among new models, existing models and experiments. The analysis of the models and experiments shows that the challenges that are still being faced to obtain better accuracy of numerical simulation results. Improvements in the models for oxy-coal combustion can be seen like potential opportunities to investigate and optimize the process that occur in the combustion

Physicochemical and biological interactions between cerium oxide nanoparticles and a 1,8-naphthalimide derivative

This Accepted Manuscript is available for reuse under a CC BY-NC-ND licence after the 24 month embargo period provided that all the terms of the licence are adhered toCerium (Ce) oxide nanoparticles (CNPs) have attracted attention due to their high bioactivity and unique redox-chemistry. The oxygen vacancies at the surface of the nanoparticle explain the autocatalytic properties of CNPs in which the Ce3+ atoms occupy the center of the oxygen vacancies surrounded by Ce4+ atoms. Until now, CNPs have been associated with organic molecules at the synthesis stage to extend their applications or improve their stability. However, there is a lack of information regarding the post-synthesis interaction of CNPs and organic molecules that could enhance or induce new properties. Due to their unique optical properties and their many uses in different areas such as supramolecular chemistry or biomedicine, we have chosen a derivative from the family of naphthalimides (the 4-amino-1,8-naphthalimide-N-substituted; ANN) to study the interaction with different CNPs (CNP1-4) and their joint bioactivity compared to that of the same compounds alone. ANN-CNP complexes were formed as revealed by spectroscopic studies, but, the interaction was markedly different depending on the physicochemical properties of CNPs and their surface content of Ce3+ sites. The ANN adsorption on all CNPs involved the amino group in the naphthalene moiety as shown by NMR spectroscopy, while the pyrrolidine ring was mainly involved in the specific interaction between ANN and CNP1. The biological effect of each CNP and ANN individually and forming complexes was assessed using a bioluminescent model bacterium. The results showed that ANN and CNP with the higher content of surface Ce3+ (CNP1) when combined acted additively towards the used model organism. In the opposite, ANN-CNP2, ANN-CNP3 and ANN-CNP4 complexes were antagonistic when the nanoparticles dominated the mixture. The results of this study contribute to expand the knowledge of the interaction between nanoparticles and organic molecules which may be useful for understanding the behavior of nanoparticles in complex matricesThis research was supported by CTM2013-45775-C2-1-R and CTM2013-45775-C2-2-R grants from MINECO. Cerium oxide nanoparticles were kindly provided by S. Seal and S. Das (University of Central Florida, U.S.A). Gerardo Pulido-Reyes thanks the Spanish Ministry of Education for the award of an FPU grant (FPU12/01796