10,755 research outputs found
Polyimides prepared from 3,5-diamino benzo trifluoride
High performance, thermooxidatively stable polyimides are prepared by reacting aromatic diamines with pendant trifluoromethyl groups and dianhydrides in an amide solvent to form a poly(amic acid), followed by cyclizing the poly(amic acid) to form the corresponding polyimide
Isomeric oxydiphthalic anhydride polyimides
Much of the polyimide research at Langley Research Center has focused on isomeric modification of the diamine component; polyimides having considerably improved processability and adhesion have resulted. The present structure-property study was designed to investigate how isomeric attachment of the three oxydiphthalic anhydride (ODPA) polyimides affects their properties. Each dianhydride, 3,4,3',4'-oxydiphthalic anhydride (4,4'-OPDA,I), 2,3,2',3'-oxydiphthalic anhydride (3,3'-ODPA,II), and 2,3,3',4'-oxydiphthalic anhydride (3,4'-OPDA,III), was reacted with p-phenylenediamine, 4,4'-oxydianiline, 3,3'-diaminodiphenylsulfone, 3,3'-diaminobenzophenone, and 4,4'-bis(3-aminophenoxy)benzophenone in DMAc. The inherent viscosities of the resulting poly(amic acids) were determined. Thermally imidized films were studied for their creasability and solubility, as well as by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and wide angle X-ray scattering (WAXS). A comparison of these properties will be made
Transverse "resistance overshoot" in a Si/SiGe two-dimensional electron gas in the quantum Hall effect regime
We investigate the peculiarities of the "overshoot" phenomena in the
transverse Hall resistance R_{xy} in Si/SiGe. Near the low magnetic field end
of the quantum Hall effect plateaus, when the filling factor \nu approaches an
integer i, R_{xy} overshoots the normal plateau value h/ie^2. However, if
magnetic field B increases further, R_{xy} decreases to its normal value. It is
shown that in the investigated sample n-Si/Si_{0.7}Ge_{0.3}, overshoots exist
for almost all \nu. Existence of overshoot in R_{xy} observed in different
materials and for different \nu, where splitting of the adjacent Landau bands
has different character, hints at the common origin of this effect. Comparison
of the experimental curves R_{xy}(\nu) for \nu = 3 and \nu = 5 with and without
overshoot showed that this effect exist in the whole interval between plateaus,
not only in the region where R_{xy} exceeds the normal plateau value.Comment: 3 pages, 5 EPS figure
Segmented printed circuit board electrode for locally-resolved current density measurements in all-vanadium redox flow batteries
One of the most important parameters for the design of redox flow batteries is a uniform distribution of the electrolyte solution over the complete electrode area. The performance of redox flow batteries is usually investigated by general measurements of the cell in systematic experimental studies such as galvanostatic charge-discharge cycling. Local inhomogeneity within the electrode cannot be locally-resolved. In this study a printed circuit board (PCB) with a segmented current collector was integrated into a 40 cm2 all-vanadium redox flow battery to analyze the locally-resolved current density distribution of the graphite felt electrode. Current density distribution during charging and discharging of the redox flow battery indicated different limiting influences. The local current density in redox flow batteries mainly depends on the transport of the electrolyte solution. Due to this correlation, the electrolyte flow in the porous electrode can be visualized. A PCB electrode can easily be integrated into the flow battery and can be scaled to nearly any size of the electrode area. The carbon coating of the PCB enables direct contact to the corrosive electrolyte, whereby the sensitivity of the measurement method is increased compared to state-of-the-art methods
Orientational phase transitions in anisotropic rare-earth magnets at low temperatures
Orientational phase transitions are investigated within the Heisenberg model
with single-site anisotropy. The temperature dependence of the cone angle is
calculated within the spin-wave theory. The role of the quantum
renormalizations of anisotropy constants is discussed. A comparison with the
experimental data on the cone-plane orientational transition in holmium is
performed.Comment: 9 pages, LaTeX, 3 figure
Dominant g(9/2)^2 neutron configuration in the 4+1 state of 68Zn based on new g factor measurements
The factor of the state in Zn has been remeasured with
improved energy resolution of the detectors used. The value obtained is
consistent with the previous result of a negative factor thus confirming
the dominant neutron nature of the state. In addition, the
accuracy of the factors of the , and states has been
improved an d their lifetimes were well reproduced. New large-scale shell model
calculations based on a Ni core and an model space
yield a theoretical value, . Although the calculated value
is small, it cannot fully explain the experimental value, . The magnitude of the deduced B(E2) of the and
transition is, however, rather well described. These results demonstrate again
the importance of factor measurements for nuclear structure determination s
due to their specific sensitivity to detailed proton and neutron components in
the nuclear wave functions.Comment: 7 pages, 3 figs, submitted to PL
A diode laser stabilization scheme for 40Ca+ single ion spectroscopy
We present a scheme for stabilizing multiple lasers at wavelengths between
795 and 866 nm to the same atomic reference line. A reference laser at 852 nm
is stabilized to the Cs D2 line using a Doppler-free frequency modulation
technique. Through transfer cavities, four lasers are stabilized to the
relevant atomic transitions in 40Ca+. The rms linewidth of a transfer-locked
laser is measured to be 123 kHz with respect to an independent atomic
reference, the Rb D1 line. This stability is confirmed by the comparison of an
excitation spectrum of a single 40Ca+ ion to an eight-level Bloch equation
model. The measured Allan variance of 10^(-22) at 10 s demonstrates a high
degree of stability for time scales up to 100 s.Comment: 8 pages, 11 figure
Cost recommendation under uncertainty in IQWiG’s efficiency frontier framework
Background: The National Institute for Quality and Efficiency in Health Care (IQWiG) employs an efficiency frontier (EF) framework to facilitate setting maximum reimbursable prices for new interventions. Probabilistic sensitivity analysis (PSA) is used when yes/no reimbursement decisions are sought based on a fixed threshold. In the IQWiG framework, an additional layer of complexity arises as the EF itself may vary its shape in each PSA iteration, and thus the willingness-to-pay, indicated by the EF segments, may vary.
Objectives: To explore the practical problems arising when, within the EF approach, maximum reimbursable prices for new interventions are sought through PSA.
Methods: When the EF is varied in a PSA, cost recommendations for new interventions may be determined by the mean or the median of the distances between each intervention’s point estimate and each EF. Implications of using these metrics were explored in a simulation study based on the model used by IQWiG to assess the cost-effectiveness of 4 antidepressants. Results. Depending on the metric used, cost recommendations can be contradictory. Recommendations based on the mean can also be inconsistent. Results (median) suggested that costs of duloxetine, venlafaxine, mirtazapine, and bupropion should be decreased by €131, €29, €12, and €99, respectively. These recommendations were implemented and the analysis repeated. New results suggested keeping the costs as they were. The percentage of acceptable PSA outcomes increased 41% on average, and the uncertainty associated to the net health benefit was significantly reduced.
Conclusions: The median of the distances between every intervention outcome and every EF is a good proxy for the cost recommendation that would be given should the EF be fixed. Adjusting costs according to the median increased the probability of acceptance and reduced the uncertainty around the net health benefit distribution, resulting in a reduced uncertainty for decision makers
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