47 research outputs found
Quantifying Li-content for compositional tailoring of lithium ferrite ceramics
Owing to their multiple applications, lithium ferrites are relevant materials
for several emerging technologies. For instance, LiFeO2 has been spotted as an
alternative cathode material in Li-ion batteries, while LiFe5O8 is the lowest
damping ferrite, holding promise in the field of spintronics. The Li-content in
lithium ferrites has been shown to greatly affect the physical properties, and
in turn, the performance of functional devices based on these materials.
Despite this, lithium content is rarely accurately quantified, as a result of
the low number of electrons in Li hindering its identification by means of
routine materials characterization methods. In the present work, magnetic
lithium ferrite powders with Li:Fe ratios of 1:1, 1:3 and 1:5 have been
synthesized, successfully obtaining phase-pure materials (LiFeO2 and LiFe5O8),
as well as a controlled mixture of both phases. The powders have been compacted
and subsequently sintered by thermal treatment (Tmax = 1100 {\deg}C) to
fabricate dense pellets which preserve the original Li:Fe ratios. Li-content on
both powders and pellets has been determined by two independent methods: (i)
Rutherford backscattering spectroscopy combined with nuclear reaction analysis
and (ii) Rietveld analysis of powder X-ray diffraction data. With good
agreement between both techniques, it has been confirmed that the Li:Fe ratios
employed in the synthesis are maintained in the sintered ceramics. The same
conclusion is drawn from spatially-resolved confocal Raman microscopy
experiments on regions of a few microns. Field emission scanning electron
microscopy has evidenced the substantial grain growth taking place during the
sintering process - mean particle sizes rise from about 600 nm in the powders
up to 3.8(6) um for dense LiFeO2 and 10(2) um for LiFe5O8 ceramics
Seeds as potential sources of phenolic compounds and minerals for the Indian population
Seeds are major sources of nutrients and bioactive compounds for human beings. In this work, the chemical composition and physicochemical properties of 155 Indian seeds (belonging to 49 families) are reported. Moisture and ash were measured with reference protocols from AOAC; total polyphenols and flavonoids were measured with spectrophotometric methods after extraction with organic solvents, and mineral elements were determined by X-ray fluorescence spectrophotometry. Total phenolic compounds, flavonoids and mineral contents (Al, Ba, Ca, Cl, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, P, Rb, S, Sr, Ti, V and Zn) were found to vary in the ranges 182–5000, 110–4465 and 687–7904 mg/100 g (DW), respectively. Noticeably, polyphenol contents higher than 2750 mg/100 g were observed in 18 seeds. In addition, mineral contents >5000 mg/100 g were detected in the seeds from Cuminum cyminum, Foeniculum vulgare, Commiphora wightii, Parkia javanica, Putranjiva roxburghii, Santalum album and Strychnos potatorum. Botanical and taxonomical variations in the proximate characteristics of the examined seeds are also discussed
Tuning the Néel temperature in an antiferromagnet: the case of NixCo1−xO microstructures
We show that it is possible to tune the Néel temperature of nickel(II)-cobalt(II) oxide films by changing the Ni to Co ratio. We grow single crystalline micrometric triangular islands with tens of nanometers thickness on a Ru(0001) substrate using high temperature oxygen-assisted molecular beam epitaxy. Composition is controlled by adjusting the deposition rates of Co and Ni. The morphology, shape, crystal structure and composition are determined by low-energy electron microscopy and diffraction, and synchrotron-based x-ray absorption spectromicroscopy. The antiferromagnetic order is observed by x-ray magnetic linear dichroism. Antiferromagnetic domains up to micrometer width are observedThis work is supported by the Spanish Agencia Estatal de Investigación (MCIU/AEI/FEDER, EU)) through Projects Nos MAT2015-64110-C2-1-P, MAT2015-64110-C2-2-P, RTI2018-095303-B-C51, and RTI2018-095303-B-C53, by the European Commission through Project H2020 No. 720853 (Amphibian) and by the Comunidad de Madrid through Project. NANOMAGCOST-CM P2018/NMT-4321. These experiments were performed at the CIRCE beamline of the ALBA Synchrotron Light Facility. A.M. acknowledges funding via a CSIC-Alba agreemen
FeCo Nanowire-Strontium Ferrite Powder Composites for Permanent Magnets with High-Energy Products
Due to the issues associated with rare-earth elements, there arises a strong
need for magnets with properties between those of ferrites and rare-earth
magnets that could substitute the latter in selected applications. Here, we
produce a high remanent magnetization composite bonded magnet by mixing FeCo
nanowire powders with hexaferrite particles. In the first step, metallic
nanowires with diameters between 30 and 100 nm and length of at least 2 {\mu}m
are fabricated by electrodeposition. The oriented as-synthesized nanowires show
remanence ratios above 0.76 and coercivities above 199 kA/m and resist core
oxidation up to 300 {\deg}C due to the existence of a > 8 nm thin oxide
passivating shell. In the second step, a composite powder is fabricated by
mixing the nanowires with hexaferrite particles. After the optimal nanowire
diameter and composite composition are selected, a bonded magnet is produced.
The resulting magnet presents a 20% increase in remanence and an enhancement of
the energy product of 48% with respect to a pure hexaferrite (strontium
ferrite) magnet. These results put nanowire-ferrite composites at the forefront
as candidate materials for alternative magnets for substitution of rare earths
in applications that operate with moderate magnet performance
Real space observation of the magnetic coupling between a Co film and a barium hexaferrite film
RIVA ONLINE 2021 – IBERIAN VACUUM ONLINE MEETING.
The Iberian Vacuum Conference, (Reunión Ibérica de Vacío, RIVA) is a joint meeting of the Portuguese Vacuum Society (SOPORVAC) and the Spanish Vacuum Society (ASEVA),
2021 RIVA will take place ON-LINE from 4-6th October 2021. .-https://aseva.es/conferences/riva-online/Barium ferrite (BaFe12O19, BFO) is a hexagonal ferrite with applications as permanent magnet in many different devices due to its high magnetocrystalline anisotropy, high coercive field and low cost. However, the moderate saturation magnetization of BFO
means that the energy product is orders of magnitude smaller than the one that rare-earth-based magnetic materials offer. To overcome this limitation, a commonly proposed strategy to enhance the energy product is exchange-coupling the magnetically hard
component (BFO) with a soft phase in order to improve the combined remanent magnetization without a high loss in coercivity. Nonetheless, the results obtained in other hard/soft systems (SFO/Co bilayers) have pointed out the difficulty to take advantage of
this rigid coupling magnetic regime1. In this research, we focus on two steps to investigate the Co/BFO coupling in a bilayer system: first, we sought to obtain BFO films with an in-
plane magnetic easy axis to avoid shape anisotropy competition, and second, we deposit Co on top of such a BFO film while monitoring both the BFO and Co magnetic domains
Insights onto the magnetic coupling at hexaferrite-based hard/soft bilayer systems
IBERTRIVA 2019 X Iberian Conference on Tribology – IBERTRIB, XI Iberian Vacuum Conference - RIVA, Seville, Spain,June 26-28Magnets are used in a variety of applications, such as generators, magnetic recording media,
components in RF and microwave devices. However, many of these magnets contain s rare
earths, critical elements whose extraction is environmentally harmful and that present price
volatility risks. Their replacement by cheaper and more environmentally friendly materials is
therefore sought.
In our case, we have focused on magnetically hard strontium hexaferrite (SrFe 12O19, SFO) as
the base for alternative permanent magnets (Figure 1a). The atomic arrangement of this ferrite
results in a high magnetocrystalline anisotropy and a coercive field, however, its magnetization
is moderate (1). It is well known that the coupling between a magnetically hard and soft material
improved magnetization while avoiding a high cost in coercitivity loss (2). However, results have
been disappointing so far as structural and geometrical limitations make it extremely challenging
to fabricate. In this work, we aim at further understanding the magnetic coupling at hard -soft
interfaces involving ferrites, for which we have deposited soft iron and cobalt metals on top of
SrFe12O19 thin films with controlled easy-axis of magnetization.
SFO thin films have been obtained by RF magnetron sputtering at 260W followed by a
subsequent annealing in air of 850ºC. Their structure and composition was characterized by
Raman spectroscospy (Figure 1b), Mössbauer spectroscopy, X-ray photoemission
spectroscopy and low-energy electron microscopy (LEEM). We have grown the magnetically
soft layer by molecular-beam epitaxy and we have analyzed the resulting bilayer system
through photoemission electron microscopy, LEEM and vibrating-sample magnetometry.
References
[1] R.C. Pullar, Hexagonal ferrites: a review of the synthesis, properties and applications of hexaferrite ceramics, Progress in Materials Science 57 (2012), pp 1191¿1334.
[2] Eric E. Fullerton, J. S. Jiang, M. Grimsditch, C. H. Sowers, and S. D. Bader, Exchange-spring behavior in epitaxial hard/soft magnetic bilayers, Phys. Rev. B 58 (1998) 1219
Dense strontium hexaferrite-based permanent magnet composites assisted by cold sintering process
[EN] The use of rare-earth-based permanent magnets is one of the critical points for the development of the current technology. On the one hand, industry of the rare-earths is highly polluting due to the negative environmental impact of their extraction and, on the other hand, the sector is potentially dependent on China. Therefore, investigation is required both in the development of rare-earth-free permanent magnets and in sintering processes that enable their greener fabrication with attractive magnetic properties at a more competitive price. This work presents the use of a cold sintering process (CSP) followed by a post-annealing at 1100 °C as a new way to sinter composite permanent magnets based on strontium ferrite (SFO). Composites that incorporate a percentage ≤ 10% of an additional magnetic phase have been prepared and the morphological, structural and magnetic properties have been evaluated after each stage of the process. CSP induces a phase transformation of SFO in the composites, which is partially recovered by the post-thermal treatment improving the relative density to 92% and the magnetic response of the final magnets with a coercivity of up to 3.0 kOe. Control of the magnetic properties is possible through the composition and the grain size in the sintered magnets. These attractive results show the potential of the sintering approach as an alternative to develop modern rare-earth-free composite permanent magnets.This work has been supported by the Ministerio Español de Ciencia e Innovación (MICINN), Spain, through the projects MAT2017-86540-C4-1-R and RTI2018-095303-A-C52, and by the European Commission through Project H2020 No. 720853 (Amphibian). C.G.-M. and A.Q. acknowledge financial support from MICINN through the “Juan de la Cierva” program (FJC2018-035532-I) and the “Ramón y Cajal” contract (RYC-2017-23320). S. R.-G. gratefully acknowledges the financial support of the Alexander von Humboldt foundation, Germany. A.S. acknowledges the financialsupport from the Comunidad de Madrid, Spain, for an “Atracción de Talento Investigador” contract (No. 2017-t2/IND5395)
Higher socioeconomic status is related to healthier levels of fatness and fitness already at 3 to 5 years of age: The PREFIT project: Relation between socioeconomic status, fatness and fitness in preschoolers
This study aimed to analyse the association between socioeconomic status (SES) and fatness and fitness in preschoolers. 2, 638 preschoolers (3–5 years old; 47.2% girls) participated. SES was estimated from the parental educational and occupational levels, and the marital status. Fatness was assessed by body mass index (BMI), waist circumference (WC), and waist-to-height ratio (WHtR). Physical fitness components were assessed using the PREFIT battery. Preschoolers whose parents had higher educational levels had lower fatness (P < 0.05). BMI significantly differed across occupational levels of each parent (P < 0.05) and WHtR across paternal levels (P = 0.004). Musculoskeletal fitness was different across any SES factor (P < 0.05), except handgrip across paternal occupational levels (P = 0.05). Preschoolers with high paternal occupation had higher speed/agility (P = 0.005), and those with high or low maternal education had higher VO2max (P = 0.046). Odds of being obese and having low musculoskeletal fitness was lower as SES was higher (P < 0.05). Those with married parents had higher cardiorespiratory fitness than single-parent ones (P = 0.010). School-based interventions should be aware of that children with low SES are at a higher risk of obesity and low fitness already in the first years of life
HPLC Method and Antioxidant Activity for Bioactive Component Determination of Lycopersicon esculentum Mill. Varieties from a Coastal Area of Southern Spain
The tomato (Lycopersicon esculentum Mill.) is one of the most widely consumed vegetables and is a component of the so-called "Mediterranean diet." It represents a significant source of antioxidants in the human diet, with an important biological function (lycopene and β-carotene), as well as other components with antioxidant properties. Antioxidant contents differ according to the variety of tomato, and environmental and agronomic conditions of growth. The aim is to optimize an high-performance liquid chromatography method for the determination of bioactive compounds and to use different antioxidant tests to determine free-radical scavenging activity.The analytical parameters, recovery assays higher than 97 %, satisfactory precision with Relative standard deviation values below 8 %, good linearity (r > 0.999), good sensitivity, and appropriate limits of detection and quantification show that the technique used is satisfactory for measuring these compounds. The tomato samples examined contain highly bioactive components and have high antioxidant capacity with high correlation between phenolic compound contents and antioxidant activity. © 2013 Springer Science+Business Media New York