143 research outputs found
The Effect of 45{\deg} Grain Boundaries and associated Fe particles on Jc and resistivity in Ba(Fe0.9Co0.1)2As2 Thin Films
The anisotropy of the critical current density Jc depends in general on both
the properties of the flux lines (such as line tension, coherence length and
penetration depth) and the properties of the defects (such as density, shape,
orientation etc.). Whereas the Jc anisotropy in microstructurally clean films
can be scaled to an effective magnetic field containing the Ginzburg-Landau
anisotropy term, it is in general not possible (or only in a limited field
range) for samples containing extended defects. Here, the Jc anisotropy of a
Co-doped BaFe2As2 sample with 45{\deg} [001] tilt grain boundaries (GBs), i.e.
grain boundaries created by 45{\deg} in-plane rotated grains, as well as
extended Fe particles is investigated. This microstructure leads to c-axis
correlated pinning, both due to the GBs and the Fe particles and manifests in a
c-axis peak in the Jc anisotropy at low magnetic fields and a deviation from
the anisotropic Ginzburg-Landau scaling at higher fields. Strong pinning at
ellipsoidal extended defects, i.e. the Fe particles, is discussed, and the full
Jc anisotropy is fitted successfully with the vortex path model. The results
are compared to a sample without GBs and Fe particles. 45{\deg} GBs seem to be
good pinning centers rather than detrimental to current flow.Comment: 8 pages, 7 figures, CEC-ICMC 2013 proceeding, accepted for
publication in Advances in Cryogenic Engineering (Materials
Low-Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)2M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)
Herein, the synthesis of new low-valent Group 14 phosphinidenide complexes [({SIDipp}P)2M] exhibiting P–M pp–pp interactions (SIDipp=1,3-bis(2,6-diisopropylphenyl)-imidazolidin-2-ylidene, M=Ge, Sn, Pb), is presented. These compounds were investigated by means of structural, spectroscopic, and quantum-chemical methods. Furthermore, the monosubstituted compounds [(SIDippP)MX]₂ (M=Sn, X=Cl; M=Pb, X=Br) are presented, which show dimeric structures instead of multiple bonding interaction
Inter- to Intra-Layer Resistivity Anisotropy of NdFeAs(O,H) with Various Hydrogen Concentrations
With molecular beam epitaxy and topotactic chemical reaction, we prepared
NdFeAs(O,H) epitaxial thin films with various hydrogen concentrations on
5{\deg} vicinal cut MgO substrates. By measuring the resistivities along the
longitudinal and transversal directions, the ab plane and the c axis
resistivities (\{rho}_ab and \{rho}_c) were obtained. The resistivity
anisotropy {\gamma}_\{rho}=\{rho}_c \ \{rho}_ab of NdFeAs(O,H) with various
hydrogen concentrations was compared with that of NdFeAs(O,F). At the H
concentrations which led to superconducting transition temperatures Tc over 40
K, {\gamma}_\r{ho} recorded ~100-150 at 50 K. On the other hand, a low
{\gamma}_\{rho} value of 9 was observed with the mostly doped sample. The
exponent \{beta} of the ab plane resistivity obtained by fitting a power law
expression \{rho}_{ab}(T)=\{rho}_0+AT^\{beta} to the data was close to unity
down to low temperature in the vicinity where the second antiferromagnetic
phase locates, which may be related to the quantum critical point discussed at
the over-doped side of the phase diagram.Comment: Appeared in Physical. Rev. Material
Neurotransmitter transporter/receptor co-expression shares organizational traits with brain structure and function
The relationship between brain areas based on neurotransmitter receptor and transporter molecule expression patterns may provide a link between brain structure and its function. Here, we studied the organization of the receptome, a measure of regional neurotransmitter receptor/transporter molecule (NTRM) similarity, derived from in vivo PET imaging studies of 19 different receptors and transporters. Nonlinear dimensionality reduction revealed three main spatial gradients of receptor similarity in the cortex. The first gradient differentiated the somato-motor network from the remaining cortex. The second gradient spanned between temporo-occipital and frontal anchors, differentiating visual and limbic networks from attention and control networks, and the third receptome gradient was anchored between the occipital and temporal cortices. In subcortical structures, the receptome delineated a striato-thalamic axis, separating functional communities. Moreover, we observed similar organizational principles underlying receptome differentiation in cortex and subcortex, indicating a link between subcortical and cortical NTRM patterning. Overall, we found that the cortical receptome shared key organizational traits with brain structure and function. Node-level correspondence of receptor similarity to functional, microstructural, and diffusion MRI-based measures decreased along a primary-to-transmodal gradient. Compared to primary and paralimbic regions, we observed higher receptomic diversification in unimodal and heteromodal regions, possibly supporting functional flexibility. In sum, we show how receptor similarity may form an additional organizational layer of human brain architecture, bridging brain structure and function
Epitaxial LaFeAsOF thin films grown by pulsed laser deposition
Superconducting and epitaxially grown LaFeAsOF thin films were successfully
prepared on (001)-oriented LaAlO3 substrates using pulsed laser deposition. The
prepared thin films show exclusively a single in-plane orientation with
epitaxial relation (001)[100] parallel to (001)[100] and a FWHM value of 1deg.
Furthermore, resistive measurement of the superconducting transition
temperature revealed a Tc90 of 25K with a high residual resistive ratio of 6.8.
The applied preparation technique, standard thin film pulsed laser deposition
at room temperature in combination with a subsequent post annealing process, is
suitable for fabrication of high quality LaFeAsO1-xFx thin films. A high upper
critical field of 76.2 T was evaluated for magnetic fields applied
perpendicular to the c-axis and the anisotropy was calculated to be 3.3
assuming single band superconductivity.Comment: 6 pages, 4 Figure
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