628 research outputs found
Theory of the Eigler-swith
We suggest a simple model to describe the reversible field-induced transfer
of a single Xe-atom in a scanning tunneling microscope, --- the Eigler-switch.
The inelasticly tunneling electrons give rise to fluctuating forces on and
damping of the Xe-atom resulting in an effective current dependent temperature.
The rate of transfer is controlled by the well-known Arrhenius law with this
effective temperature. The directionality of atom transfer is discussed, and
the importance of use of non-equlibrium-formalism for the electronic
environment is emphasized. The theory constitutes a formal derivation and
generalization of the so-called Desorption Induced by Multiple Electron
Transitions (DIMET) point of view.Comment: 13 pages (including 2 figures in separate LaTeX-files with
ps-\specials), REVTEX 3.
EffectiveSan: Type and Memory Error Detection using Dynamically Typed C/C++
Low-level programming languages with weak/static type systems, such as C and
C++, are vulnerable to errors relating to the misuse of memory at runtime, such
as (sub-)object bounds overflows, (re)use-after-free, and type confusion. Such
errors account for many security and other undefined behavior bugs for programs
written in these languages. In this paper, we introduce the notion of
dynamically typed C/C++, which aims to detect such errors by dynamically
checking the "effective type" of each object before use at runtime. We also
present an implementation of dynamically typed C/C++ in the form of the
Effective Type Sanitizer (EffectiveSan). EffectiveSan enforces type and memory
safety using a combination of low-fat pointers, type meta data and type/bounds
check instrumentation. We evaluate EffectiveSan against the SPEC2006 benchmark
suite and the Firefox web browser, and detect several new type and memory
errors. We also show that EffectiveSan achieves high compatibility and
reasonable overheads for the given error coverage. Finally, we highlight that
EffectiveSan is one of only a few tools that can detect sub-object bounds
errors, and uses a novel approach (dynamic type checking) to do so.Comment: To appear in the Proceedings of 39th ACM SIGPLAN Conference on
Programming Language Design and Implementation (PLDI2018
Surface Screening Charge and Effective Charge
The charge on an atom at a metallic surface in an electric field is defined
as the field-derivative of the force on the atom, and this is consistent with
definitions of effective charge and screening charge. This charge can be found
from the shift in the potential outside the surface when the atoms are moved.
This is used to study forces and screening on surface atoms of Ag(001)
c -- Xe as a function of external field. It is found that at low
positive (outward) fields, the Xe with a negative effective charge of -0.093
is pushed into the surface. At a field of 2.3 V \AA the charge
changes sign, and for fields greater than 4.1 V \AA the Xe experiences
an outward force. Field desorption and the Eigler switch are discussed in terms
of these results.Comment: 4 pages, 1 figure, RevTex (accepted by PRL
Polymerization in carbone : a novel method for the synthesis of more sustainable electrodes and their application as cathodes for lithium–organic energy storage materials based on vanillin
Sustainable energy storage materials are needed to implement necessary transitions to a more sustainable society. Therefore, we present novel vanillin (and thus ultimately possibly lignin)-derived electrode materials for lithium-ion-based energy storage systems. In the present approach, vanillin is first modified in two sustainable steps to afford bisvanillonitrile (BVN). The precursor materials for the electrodes are made from BVN and carbon black and are subsequently treated in the atmosphere of triflic acid in order to polymerize BVN. Used as a cathode material in a lithium-ion-based energy storage device, the resulting material shows capacities up to 90 mAh g–1 (respective to the whole electrode mass). This extraordinary performance can be attributed to a combination of non-Faradaic and Faradaic charge storage involving quinone units, which are abundantly found in the polymer backbone. In contrast to conventional organic electrode materials, excellent contact to carbon as a conductive additive is established by performing the polymerization in a mixture with carbon (in carbone), allowing the omission of additional unsustainable binder materials. Due to the sustainable synthesis and good performance, such sustainable electrodes may be applied in future energy storage devices
Atomic Scale Memory at a Silicon Surface
The limits of pushing storage density to the atomic scale are explored with a
memory that stores a bit by the presence or absence of one silicon atom. These
atoms are positioned at lattice sites along self-assembled tracks with a pitch
of 5 atom rows. The writing process involves removal of Si atoms with the tip
of a scanning tunneling microscope. The memory can be reformatted by controlled
deposition of silicon. The constraints on speed and reliability are compared
with data storage in magnetic hard disks and DNA.Comment: 13 pages, 5 figures, accepted by Nanotechnolog
First principles theory of inelastic currents in a scanning tunneling microscope
A first principles theory of inelastic tunneling between a model probe tip
and an atom adsorbed on a surface is presented, extending the elastic tunneling
theory of Tersoff and Hamann. The inelastic current is proportional to the
change in the local density of states at the center of the tip due to the
addition of the adsorbate. We use the theory to investigate the vibrational
heating of an adsorbate below an STM tip. We calculate the desorption rate of H
from Si(100)-H(21) as function of the sample bias and tunnel current,
and find excellent agreement with recent experimental data.Comment: 5 pages, RevTeX, epsf file
Atomic Tunneling from a STM/AFM tip: Dissipative Quantum Effects from Phonons
We study the effects of phonons on the tunneling of an atom between two
surfaces. In contrast to an atom tunneling in the bulk, the phonons couple very
strongly, and qualitatively change the tunneling behavior. This is the first
example of {\it ohmic} coupling from phonons for a two-state system. We propose
an experiment in which an atom tunnels from the tip of an STM, and show how its
behavior would be similar to the Macroscopic Quantum Coherence behavior
predicted for SQUIDS. The ability to tune and calculate many parameters would
lead to detailed tests of the standard theories. (For a general intro to this
work on the on the World-Wide-Web: http://www.lassp.cornell.edu. Click on
``Entertaining Science Done Here'' and ``Quantum Tunneling of Atoms'')Comment: 12 pages, ReVTex3.0, two figures (postscript). This is a
(substantially) revised version of cond-mat/9406043. More info (+ postscript
text) at : http://www.lassp.cornell.edu/ardlouis/publications.htm
Scattering Theory of Kondo Mirages and Observation of Single Kondo Atom Phase Shift
We explain the origin of the Kondo mirage seen in recent quantum corral
Scanning Tunneling Microscope (STM) experiments with a scattering theory of
electrons on the surfaces of metals. Our theory combined with experimental data
provides the first direct observation of a single Kondo atom phase shift. The
Kondo mirage at the empty focus of an elliptical quantum corral is shown to
arise from multiple electron bounces off the walls of the corral in a manner
analagous to the formation of a real image in optics. We demonstrate our theory
with direct quantitive comparision to experimental data.Comment: 13 pages; significant clarifications of metho
Resolution of intramolecular dipoles and push-back effect of individual molecules on a metal surface
Molecules consisting of a donor and an acceptor moiety can exhibit large
intrinsic dipole moments. Upon deposition on a metal surface, the dipole may be
effectively screened and the charge distribution altered due to hybridization
with substrate electronic states. Here, we deposit Ethyl-Diaminodicyanoquinone
molecules, which exhibit a large dipole moment in gas phase, on a Au(111)
surface. Employing a combination of scanning tunneling microscopy and
non-contact atomic force microscopy, we find that a significant dipole moment
persists in the flat-lying molecules. Density-functional theory calculations
reveal that the dipole moment is even increased on the metal substrate as
compared to the gas phase. We also show that the local contact potential across
the molecular islands is decreased by several tens of meV with respect to the
bare metal. We explain this by the induced charge-density redistribution due to
the adsorbed molecules, which confine the substrate's wavefunction at the
interface. Our local measurements provide direct evidence of this so-called
push-back or cushion effect at the scale of individual molecules.Comment: This document is the unedited Author's version of a Submitted Work
that was subsequently accepted for publication in Journal of Physical
Chemistry
Microscopic theory for quantum mirages in quantum corrals
Scanning tunneling microscopy permits to image the Kondo resonance of a
single magnetic atom adsorbed on a metallic surface. When the magnetic impurity
is placed at the focus of an elliptical quantum corral, a Kondo resonance has
been recently observed both on top of the impurity and on top of the focus
where no magnetic impurity is present. This projection of the Kondo resonance
to a remote point on the surface is referred to as quantum mirage. We present a
quantum mechanical theory for the quantum mirage inside an ideal quantum corral
and predict that the mirage will occur in corrals with shapes other than
elliptical
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