725 research outputs found
Infrared spectra of molecules and materials of astrophysical interest
The Raman spectra of gaseous, liquid and solid, and infrared spectra of gaseous and solid isopropylamine-d sub 0 and -d sub 2 was investigated between 4000 and 50 cm superscript -1. Differences between the spectrum of the solid phase and that of the fluid phases were interpreted in terms of an equilibrium between low energy s-trans and high energy gauche conformers, and a complete vibrational assignment was proposed for the s-trans conformer. The far infrared spectra of the gaseous compounds contained bands due to the asymmetric amino and coupled methyl torsions; the assignment of these bands was aided by observation of a number of two quantum transitions for each vibrational mode. The asymmetric potential functions were calculated, which resulted in values for the enthalpy differences between conformers in the gaseous phase of 446 and 523 callmole for the sub 0 -d and -d sub 2 compounds, respectively. The methyl torsional potential function of isopropylamine-d sub 0 was calculated which led to a value for the barrier height to internal rotation of the methyl rotors of 4.23 + or - 0.06 kcal/mole. Values for the ideal gas thermodynamic functions were calculated over a range of temperatures
Infrared spectra of molecules and materials of astrophysical interest Quarterly progress report, 15 jun. - 15 sep. 1970
Infrared spectra of molecules and materials of astrophysical interest Quarterly progress report, 15 Jun. - 15 Sep. 197
Infrared spectra of molecules and materials of astrophysical interest Quarterly progress report, 15 Dec. 1970 - 15 Mar. 1971
Vibrational spectra of molecules expected in Jovian atmospher
Infrared spectra of molecules and materials of astrophysical interest
The vibrational spectra from 4,000 to 33/cm of several molecules which may be present in the atmosphere of the Jovian planets or exist in outer space were studied. These studies have been made to provide vibrational frequencies which can be used to: (1) determine the composition of the cloud covers of several of the planets, (2) provide structural information under favorable circumstances, (3) provide necessary data from which accurate thermodynamic data can be calculated, and (4) furnish information as to the nature of the potential energy function of the molecules and forces acting within them. Some of the molecules studied can be produced photochemically from methane, ammonia, and hydrogen sulfide which are thought to be constituents of the planets with reducing atmospheres. Some of the compounds will polymerize under ultraviolet radiation and drop out of the atmospheres. However, planets with a hot base, like that of Jupiter, may rebuild molecules destroyed photochemically. These criteria were used in selecting the compounds under study
Infrared spectra of molecules and materials of astrophysical interest
The vibrational spectra from 4000 to 33 cm-1 of several modecules which may be present in the atmosphere of the Jovian planets are studied to provide vibrational frequencies which can be used to: (1) determine the composition of the cloud covers of several of the planets; (2) provide structural information under favorable circumstances; (3) provide necessary data from which accurate thermodynamic data can be calculated; and (4) furnish information as to the nature of the potential energy function of the molecules and forces acting within them. Some of the molecules are produced photochemically from methane, ammonia, and hydrogen sulfide which are thought to be constituents of the planets with reducing atmospheres. Some of the compounds polymerize under ultraviolet radiation and drop out of the atmospheres. However, planets with a hot base, like that of Jupiter, may rebuild molecules destroyed photochemically
Infrared spectra of molecules and materials of astrophysical interest Quarterly progress report, 15 Sep. - 15 Dec. 1970
Vibrational spectra of molecules and solid materials from 4000 to 33 cm in Jovian atmospher
Bond Properties and Molecular Conformation from Vibrational Intensity Analysis
Experimental vibrational intensities in infrared spectra can be
transformed into quantities characterizing bond properties fol-
lowing the formalism of the bond polar parameters model. The
theory is briefly presented. An optimized set of bond polar parameters for hydrocarbons is obtained following constraints derived
from experimental spectral data and ab initio MO calculations.
The set of intensity parameters together with transferable force
constants is used in predicting the infrared spectra of individual
conformers and equilibrium conformer mixtures of n-butane-do,
n-pentane-d, n-pentane-djj and n-hexane-d, The influence of
rotational isomerism on infrared intensities in these systems is discussed
Far Infrared and Raman Spectroscopic Investigations of the Lattice:Modes of Crystalline Thiophene
Vibrational spectroscopic measurements combined with the
lattice statics and lattice mod es calculations have been applied in
order to derive the most probable structure of the low temperature
(stable) phase V of thiophene (below 112 K). The far infrared
spectrum has been recorded from 135 to 30 cm? of this phase of
thiophene at 20 K. The low frequency Raman spectrum from
150 to 10 cm" has also been record ed for the phase V at 35 K.
From the fact that there is coincidence between lattice mode
frequencies observed in the infrared and Raman spectra, one can
exclude centrosymmetric space groups. The observations of 20
lattice modes in the Raman spectrum and 14 modes in the FIR
spectrum eliminate the possibility of tetragonal symmetry, but
the data are consistent with orthorhombic symmetry with the
unit cell containing 4 molecules on Cl sites. In spite of the
glassy-like transition observed for this phase at 42 K, both spectra
bear striking resemblance to the typical low frequency spectra
of molecular crystals. Therefore, it is assumed, for the purposes
of the static and dynamic studies, that the thiophene in phase
V can be considered as an ideally ordered crystal. Calculations
of the lattice energy and lattice mode frequencies, based on
the atom-atom potential, appear to be most consistent with
space group Pca2l (C2v5) which is in agreement with most of
the earlier predictions made for the structure of the thiophene
phase V. The Raman spectrum of the metastable phase II2 is also given
Far Infrared and Raman Spectroscopic Investigations of the Lattice:Modes of Crystalline Thiophene
Vibrational spectroscopic measurements combined with the
lattice statics and lattice mod es calculations have been applied in
order to derive the most probable structure of the low temperature
(stable) phase V of thiophene (below 112 K). The far infrared
spectrum has been recorded from 135 to 30 cm? of this phase of
thiophene at 20 K. The low frequency Raman spectrum from
150 to 10 cm" has also been record ed for the phase V at 35 K.
From the fact that there is coincidence between lattice mode
frequencies observed in the infrared and Raman spectra, one can
exclude centrosymmetric space groups. The observations of 20
lattice modes in the Raman spectrum and 14 modes in the FIR
spectrum eliminate the possibility of tetragonal symmetry, but
the data are consistent with orthorhombic symmetry with the
unit cell containing 4 molecules on Cl sites. In spite of the
glassy-like transition observed for this phase at 42 K, both spectra
bear striking resemblance to the typical low frequency spectra
of molecular crystals. Therefore, it is assumed, for the purposes
of the static and dynamic studies, that the thiophene in phase
V can be considered as an ideally ordered crystal. Calculations
of the lattice energy and lattice mode frequencies, based on
the atom-atom potential, appear to be most consistent with
space group Pca2l (C2v5) which is in agreement with most of
the earlier predictions made for the structure of the thiophene
phase V. The Raman spectrum of the metastable phase II2 is also given
Vibrational spectra and normal coordinate analysis of CF 3 OF and CF 3 OCl
The IR spectra (1400 cm −1 to 160 cm −1 ) of the gases at ambient temperature and the Raman spectra (below 1400 cm −1 ) of the liquids near −196°C are reported for CF 3 OF and CF 3 OCl. All fundamentals are assigned under C s symmetry and the results of a normal coordinate analysis are presented. The assignments of Smardzewski and Fox are adopted with one exception for both CF 3 OF and CF 3 OCl: the CF 3 rock of A ″ symmetry is assigned near 430 cm −1 and the two bands between 200 cm −1 and 300 cm −1 are assigned to an A ′ fundamental, involving CF 3 rocking and COX bending and a Δ ν =2 transition in the CF 3 torsion. An extra band at 548 cm −1 in the Raman spectrum of liquid CF 3 COl near −196°C is assigned to a CF 3 OCl ⃛Cl 2 complex. The values of the force constants d (OX) for CF 3 OX molecules are suggested to be near those for X 2 O molecules. More than half the normal modes of A ′ symmetry show extensive mixing of symmetry coordinates. In some of these cases the symmetry coordinate for which the normal mode is named is the largest but not the dominant contributor to the potential energy distribution, while in others this symmetry coordinate is not even the largest contributor to the potential energy distribution. No normal modes of A ′ symmetry are present in which ν(CO), δ s (CF 3 ), δ(COX), or δ(CF 3 ) symmetry coordinates are dominant, and the mode conventionally labeled as v (CO) should be labeled as ν s (CF 3 ). For the remaining A ′ normal modes and all the A ″ normal modes, the symmetry coordinate for which the normal mode is named is dominant in the potential energy distribution.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/91176/1/1250090406_ftp.pd
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