Using Radium isotopes to evaluate the mixing timeline and relative age of waters in a leaky coastal lagoon

The Ria Formosa wetland system is classified as a leaky coastal lagoon and covers approximately 100 km2 of the South of Portugal, with roughly 50% being intertidal. Its hinterland is set in an arid region and on a coastal plain subject to intensive agriculture since the 50’s. In spite of high exchange coefficients with the coastal ocean (50 and 75% at neap and spring tides, respectively) and the annual total potential freshwater discharge from the hinterland a fraction of the daily tidal prism, worrying signs of eutrophication have been detected during the past couple of decades. These include fish- and clam-kill episodes, increased occurrence of nuisance algal blooms and substitution of native sea grass communities by macroalgae. Notwithstanding its critical importance for the evaluation of pollutant exposure period, the literature includes a wide range of estimates for the ‘residence time’ of waters within the lagoon (16 hours to 11 days, with an the apparent consensus falling within the 1-2 day interval) and this point is a clear obstacle for a correct environmental risk assessment, including management of the system. This lack of clarity is due in our view to two main factors: i) the lack of proper physical definition of the term ‘residence time’, with its consequent misuse and misapplication in context, a misconception that is unfortunately too common within the environmental community, and different concepts in the application of transport time scales ii) the geomorphological and hydraulic complexity of the system.. As part of ongoing research evaluating the role of Submarine Groundwater Discharge (SGD) as a loading vector for nutrients (especially Nitrate) into the lagoon, we use the radium quartet in combination with remote sensing and isotope mixing models to develop and discuss a mixing timeline for the system, We conclude that the average, whole-system residence time of waters within the lagoon is at least 4 days

Molecular diversity of arbuscular mycorrhizal fungi in onion roots from organic and conventional farming systems in the Netherlands

Diversity and colonization levels of naturally occurring arbuscular mycorrhizal fungi (AMF) in onion roots were studied to compare organic and conventional farming systems in the Netherlands. In 2004, 20 onion fields were sampled in a balanced survey between farming systems and between two regions, namely, Zeeland and Flevoland. In 2005, nine conventional and ten organic fields were additionally surveyed in Flevoland. AMF phylotypes were identified by rDNA sequencing. All plants were colonized, with 60% for arbuscular colonization and 84% for hyphal colonization as grand means. In Zeeland, onion roots from organic fields had higher fractional colonization levels than those from conventional fields. Onion yields in conventional farming were positively correlated with colonization level. Overall, 14 AMF phylotypes were identified. The number of phylotypes per field ranged from one to six. Two phylotypes associated with the Glomus mosseae-coronatum and the G. caledonium-geosporum species complexes were the most abundant, whereas other phylotypes were infrequently found. Organic and conventional farming systems had similar number of phylotypes per field and Shannon diversity indices. A few organic and conventional fields had larger number of phylotypes, including phylotypes associated with the genera Glomus-B, Archaeospora, and Paraglomus. This suggests that farming systems as such did not influence AMF diversity, but rather specific environmental conditions or agricultural practice

Estimating submarine groundwater discharge into the Ria Formosa lagoon, Portugal: Uncertainties in the lagoon-open ocean radium exchange

The Ria Formosa lagoon is the most important resource for the fishing, aquaculture and tourism industries of southern Portugal. The lagoon expands across an area of approximately 100 km²and about half of its area is intertidal, covered with muddy sand and saltmarshes. The lagoon is shallow (2 m average depth) with semidiurnal tides at amplitudes between 1.3 m and 3 m (during neap and spring tides respectively) causing a relatively rapid renewal of water through three inlets at time scales shorter than 5 days. The hinterland is characterized by intensive agriculture leading to elevated nitrate concentrations in coastal groundwaters. To quantify the amount of submarine groundwater discharge (SGD) and possible associated nutrient fluxes to the lagoon radium concentrations (223Ra, 224Ra, 228Ra, 226Ra) were measured during low and high spring tides in December 2009 and May 2010 using standard techniques (delayed coincidence counting, gamma spectrometry). A radium mass balance model accounting for all major sources and sinks of radium was employed to derive quantitative estimates of SGD. In order to avoid biases due to non-representative sampling, areal average radium concentrations were generated using the ArcGIS spatial analyst interpolation scheme. Radium exchange with the open ocean was the most significant parameter in the mass balance calculations. Three independent models were used to calculate this exchange flux: i) a tidal prism model using radium to calculate the return flow factor, ii) a hydrographic model providing outflow and inflow water fluxes for the Ria Formosa lagoon; and by combining these fluxes with the average concentrations measured at the inlet; iii) a model which estimates the exchange with the ocean based on the radium residence time calculated from the water exposure time in the lagoon. For each of these models we calculated SGD based on 223Ra, 224Ra and 226Ra mass balances the differences being at a maximum no greater than 35 %. However, the results from the models differed up to a factor of 2 with the tidal prism model producing the highest estimate and the residence time model the lowest estimates. We will discuss possible causes for the differences in the model results

Comparing phenomenological recipes with a microscopic model for the electric amplitude in strangeness photoproduction

Corrections to the Born approximation in photo-induced strangeness production off a proton are calculated in a semi-realistic microscopic model. The vertex corrections and internal contributions to the amplitude of the $\gamma p \to K^+ \Lambda$ reaction are included on the one-loop level. Different gauge-invariant phenomenological prescriptions for the modification of the Born contribution via the introduction of form factors and contact terms are discussed. In particular, it is shown that the popular minimal-substitution method of Ohta corresponds to a special limit of the more realistic approach.Comment: 10 pages, 6 figures in the tex

Challenging pacemaker implantation:persistent left superior vena cava with absent right superior vena cava

A persistent left superior vena cava (PLSVC) in combination with an absent right superior vena cava (RSVC) is a rare congenital cardiovascular abnormality which is usually found by chance during pacemaker (PM) implantation. In this case we describe a PM implantation using right cephalic approach through PLSVC and coronary sinus (CS), with lead fixation in right atrium and a posterolateral branch of the CS

Infarct tissue characterization in implantable cardioverter-defibrillator recipients for primary versus secondary prevention following myocardial infarction: a study with contrast-enhancement cardiovascular magnetic resonance imaging

Knowledge about potential differences in infarct tissue characteristics between patients with prior life-threatening ventricular arrhythmia versus patients receiving prophylactic implantable cardioverter-defibrillator (ICD) might help to improve the current risk stratification in myocardial infarction (MI) patients who are considered for ICD implantation. In a consecutive series of (ICD) recipients for primary and secondary prevention following MI, we used contrast-enhanced (CE) cardiovascular magnetic resonance (CMR) imaging to evaluate differences in infarct tissue characteristics. Cine-CMR measurements included left ventricular end-diastolic and end-systolic volumes (EDV, ESV), left ventricular ejection fraction (LVEF), wall motion score index (WMSI), and mass. CE-CMR images were analyzed for core, peri, and total infarct size, infarct localization (according to coronary artery territory), and transmural extent. In this study, 95 ICD recipients were included. In the primary prevention group (n = 66), LVEF was lower (23 ± 9 % vs. 31 ± 14 %; P < 0.01), ESV and WMSI were higher (223 ± 75 ml vs. 184 ± 97 ml, P = 0.04, and 1.89 ± 0.52 vs. 1.47 ± 0.68; P < 0.01), and anterior infarct localization was more frequent (P = 0.02) than in the secondary prevention group (n = 29). There were no differences in infarct tissue characteristics between patients treated for primary versus secondary prevention (P > 0.6 for all). During 21 ± 9 months of follow-up, 3 (5 %) patients in the primary prevention group and 9 (31 %) in the secondary prevention group experienced appropriate ICD therapy for treatment of ventricular arrhythmia (P < 0.01). There was no difference in infarct tissue characteristics between recipients of ICD for primary versus secondary prevention, while the secondary prevention group showed a higher frequency of applied ICD therapy for ventricular arrhythmia.\u

Development and screening of selective catalysts for the synthesis of clean liquid fuels

This article is a compilation of the research carried out under EEC contract EN3V-0400-D at the Institut für Energieverfahrenstechnik in Jülich and at the Faculty of Chemical Technology and Materials Science, Delft, concerning the development and screening of copper/cobalt-based catalysts for the synthesis of alcohol mixtures from syngas. Analogous work, based on copper/zinc oxide/alumina catalysts, has been performed at the Faculty of Chemical Technology in Twente University at Enschede. This work is described in a companion paper. Comparative tests of several catalysts in a pressure micropulse reactor and in a plug flow tubular reactor, carried out at the Institut für Technische Chemie, TU Braunschweig, are presented in a second companion paper. \ud In the discussion section of the present article the results obtained by the joint groups are compared with the initial objectives of the programme

Assessing land-ocean connectivity via Submarine Groundwater Discharge (SGD) in the Ria Formosa Lagoon (Portugal): combining radon measurements and stable isotope hydrology

Natural radioactive tracer-based assessments of basin-scale Submarine Groundwater Discharge (SGD) are well developed, but because of the different modes in which SGD takes place and the wide range of spatial and temporal scales under which the flow and discharge mechanisms involved occur, quantifying SGD while discriminating its source functions remains a major challenge. Yet, correctly identifying both the fluid source and composition is critical: when multiple sources of the tracer of interest are present, failure to adequately discriminate between them will lead to inaccurate attribution and the resulting uncertainties will affect the reliability of SGD solute loading estimates. This lack of reliability then extends to the closure of local biogeochemical budgets, confusing measures aiming to mitigate pollution. Here, we report a multi-tracer study to identify the sources of SGD, distinguish its component parts and elucidate the mechanisms of their dispersion throughout the Ria Formosa – a seasonally hypersaline lagoon in Portugal. We combine radon budgets that determine the total SGD (meteoric + recirculated seawater) in the system with stable isotopes in water (2H, 18O), to specifically identify SGD source functions and characterize active hydrological pathways in the catchment. Using this approach, SGD in the Ria Formosa could be separated into a net water input and another involving no net water transfer, i.e. originating in seawater recirculation through permeable sediments. The former SGD mode is present occasionally on a multiannual timescale, while the latter is a permanent feature of the system. In the absence of meteoric SGD inputs, seawater recirculation through beach sediments occurs at a rate of ~ 1.4 × 106 m3 day−1, implying the entire tidal-averaged volume of the lagoon is filtered through local sandy sediments within 100 days, or about 3.5 times a year, driving an estimated nitrogen (N) load of ~ 350 t N yr−1 into the system as NO3−. Land-borne SGD could add a further ~ 61 t N yr−1 to the lagoon. The former source is autochthonous, continuous and responsible for a large fraction (59 %) of the estimated total N inputs into the system via non-point sources, while the latter is an occasional allochthonous source, so more difficult to predict, but capable of driving new production in the system