3,813 research outputs found
H2 molecule in strong magnetic fields
The Pauli-Hamiltonian of a molecule with fixed nuclei in a strong constant
magnetic field is asymptotic, in norm-resolvent sense, to an effective
Hamiltonian which has the form of a multi-particle Schr\"odinger operator with
interactions given by one-dimensional \delta-potentials. We study this
effective Hamiltonian in the case of the H2 -molecule and establish existence
of the ground state. We also show that the inter-nuclear equilibrium distance
tends to 0 as the field-strength tends to infinity
The Value of Comparative Animal Research : Kroghâs Principle Facilitates Scientific Discoveries
There are no conflicts of interest to declare. This paper developed from the 2016 Early Career Impact Award from the Federation of Associations in Behavioral & Brain Sciences to TJS. TJS has received funding from The Leverhulme Trust. FJPE is in receipt of funding from the BBSRC (BB/M001555/1). The National Institutes of Health has funded RDF (NS 034950, NS093277, NIMH 087930), AGO (HD079573, IOS-1354760) and AMK (HD081959). BAA is an Arnold O. Beckman postdoctoral fellow.Peer reviewedPostprin
The Total Synthesis of (â)-Scabrolide A
The first total synthesis of the norcembranoid diterpenoid scabrolide A is disclosed. The route begins with the synthesis of two chiral pool-derived fragments, which undergo a convergent coupling to expediently introduce all 19 carbon atoms of the natural product. An intramolecular DielsâAlder reaction and an enoneâolefin cycloaddition/fragmentation sequence are then employed to construct the fused [5â6â7] linear carbocyclic core of the molecule and complete the total synthesis
Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A
Enantioselective Pd-catalyzed allylic alkylations of dihydropyrido[1,2-a]indolone (DHPI) substrates were used to construct the C20-quaternary stereocenters of multiple monoterpene indole alkaloids. Stereodivergent PictetâSpengler and BischlerâNapieralski cyclization/reduction cascades furnish the cis- and trans-fused azadecalin subunits present in Aspidosperma and Kopsia alkaloids, respectively, enâ
route to highly efficient syntheses of (+)-limaspermidine and (+)-kopsihainanineâ
A
Angular Power Spectrum Estimation of Cosmic Ray Anisotropies with Full or Partial Sky Coverage
We study the angular power spectrum estimate in order to search for large
scale anisotropies in the arrival directions distribution of the highest-energy
cosmic rays. We show that this estimate can be performed even in the case of
partial sky coverage and validated over the full sky under the assumption that
the observed fluctuations are statistically spatial stationary. If this
hypothesis - which can be tested directly on the data - is not satisfied, it
would prove, of course, that the cosmic ray sky is non isotropic but also that
the power spectrum is not an appropriate tool to represent its anisotropies,
whatever the sky coverage available. We apply the method to simulations of the
Pierre Auger Observatory, reconstructing an input power spectrum with the
Southern site only and with both Northern and Southern ones. Finally, we show
the improvement that a full-sky observatory brings to test an isotropic
distribution, and we discuss the sensitivity of the Pierre Auger Observatory to
large scale anisotropies.Comment: 16 pages, 6 figures, version accepted for publication by JCA
The Total Synthesis of (â)-Scabrolide A
The first total synthesis of the norcembranoid diterpenoid scabrolide A is disclosed. The route begins with the synthesis of two chiral pool-derived fragments, which undergo a convergent coupling to expediently introduce all 19 carbon atoms of the natural product. An intramolecular DielsâAlder reaction and an enoneâolefin cycloaddition/fragmentation sequence are then employed to construct the fused [5â6â7] linear carbocyclic core of the molecule and complete the total synthesis
Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A
Enantioselective Pd-catalyzed allylic alkylations of dihydropyrido[1,2-a]indolone (DHPI) substrates were used to construct the C20-quaternary stereocenters of multiple monoterpene indole alkaloids. Stereodivergent PictetâSpengler and BischlerâNapieralski cyclization/reduction cascades furnish the cis- and trans-fused azadecalin subunits present in Aspidosperma and Kopsia alkaloids, respectively, enâ
route to highly efficient syntheses of (+)-limaspermidine and (+)-kopsihainanineâ
A
Rigorous investigation of the reduced density matrix for the ideal Bose gas in harmonic traps by a loop-gas-like approach
In this paper, we rigorously investigate the reduced density matrix (RDM)
associated to the ideal Bose gas in harmonic traps. We present a method based
on a sum-decomposition of the RDM allowing to treat not only the isotropic
trap, but also general anisotropic traps. When focusing on the isotropic trap,
the method is analogous to the loop-gas approach developed by W.J. Mullin in
[38]. Turning to the case of anisotropic traps, we examine the RDM for some
anisotropic trap models corresponding to some quasi-1D and quasi-2D regimes.
For such models, we bring out an additional contribution in the local density
of particles which arises from the mesoscopic loops. The close connection with
the occurrence of generalized-BEC is discussed. Our loop-gas-like approach
provides relevant information which can help guide numerical investigations on
highly anisotropic systems based on the Path Integral Monte Carlo (PIMC)
method.Comment: v3: Minor modifications of v2. v2: Major modifications: the former
version (v1) has been completely rewritten. New results concerning the
anisotropic traps and generalized Bose-Einstein condensation have been added.
The connection with the loop-gas approach is further discussed. 40 page
Recommended from our members
A GCSS model intercomparison for a tropical squall line observed during toga-coare. II: Intercomparison of single-column models and a cloud-resolving model
This paper presents single-column model (SCM) simulations of a tropical squall-line case observed during the Coupled Ocean-Atmosphere Response Experiment of the Tropical Ocean/Global Atmosphere Programme. This case-study was part of an international model intercomparison project organized by Working Group 4 âPrecipitating Convective Cloud Systemsâ of the GEWEX (Global Energy and Water-cycle Experiment) Cloud System Study.
Eight SCM groups using different deep-convection parametrizations participated in this project. The SCMs were forced by temperature and moisture tendencies that had been computed from a reference cloud-resolving model (CRM) simulation using open boundary conditions. The comparison of the SCM results with the reference CRM simulation provided insight into the ability of current convection and cloud schemes to represent organized convection. The CRM results enabled a detailed evaluation of the SCMs in terms of the thermodynamic structure and the convective mass flux of the system, the latter being closely related to the surface convective precipitation. It is shown that the SCMs could reproduce reasonably well the time evolution of the surface convective and stratiform precipitation, the convective mass flux, and the thermodynamic structure of the squall-line system. The thermodynamic structure simulated by the SCMs depended on how the models partitioned the precipitation between convective and stratiform. However, structural differences persisted in the thermodynamic profiles simulated by the SCMs and the CRM. These differences could be attributed to the fact that the total mass flux used to compute the SCM forcing differed from the convective mass flux. The SCMs could not adequately represent these organized mesoscale circulations and the microphysicallradiative forcing associated with the stratiform region. This issue is generally known as the âscale-interactionâ problem that can only be properly addressed in fully three-dimensional simulations.
Sensitivity simulations run by several groups showed that the time evolution of the surface convective precipitation was considerably smoothed when the convective closure was based on convective available potential energy instead of moisture convergence. Finally, additional SCM simulations without using a convection parametrization indicated that the impact of a convection parametrization in forced SCM runs was more visible in the moisture profiles than in the temperature profiles because convective transport was particularly important in the moisture budget
- âŠ