9,348 research outputs found
Magnetic Properties of the Novel Low-Dimensional Cuprate Na5RbCu4(AsO4)4Cl2
The magnetic properties of a new compound, Na5RbCu4(AsO4)4Cl2 are reported.
The material has a layered structure comprised of square Cu4O4 tetramers. The
Cu ions are divalent and the system behaves as a low-dimensional S=1/2
antiferromagnet. Spin exchange in Na5RbCu4(AsO4)4Cl2 appears to be
quasi-two-dimensional and non-frustrated. Measurements of the bulk magnetic
susceptibility and heat capacity are consistent with low-dimensional magnetism.
The compound has an interesting, low-entropy, magnetic transition at T = 17 K.Comment: 4 pages, 5 figure
Radius Dependent Luminosity Evolution of Blue Galaxies in GOODS-N
We examine the radius-luminosity (R-L) relation for blue galaxies in the Team
Keck Redshift Survey (TKRS) of GOODS-N. We compare with a volume-limited, Sloan
Digital Sky Survey sample and find that the R-L relation has evolved to lower
surface brightness since z=1. Based on the detection limits of GOODS this can
not be explained by incompleteness in low surface-brightness galaxies. Number
density arguments rule out a pure radius evolution. It can be explained by a
radius dependent decline in B-band luminosity with time. Assuming a linear
shift in M_B with z, we use a maximum likelihood method to quantify the
evolution. Under these assumptions, large (R_{1/2} > 5 kpc), and intermediate
sized (3 < R_{1/2} < 5 kpc) galaxies, have experienced Delta M_B =1.53
(-0.10,+0.13) and 1.65 (-0.18, +0.08) magnitudes of dimming since z=1. A simple
exponential decline in star formation with an e-folding time of 3 Gyr can
result in this amount of dimming. Meanwhile, small galaxies, or some subset
thereof, have experienced more evolution, 2.55 (+/- 0.38) magnitudes. This
factor of ten decline in luminosity can be explained by sub-samples of
starbursting dwarf systems that fade rapidly, coupled with a decline in burst
strength or frequency. Samples of bursting, luminous, blue, compact galaxies at
intermediate redshifts have been identified by various previous studies. If
there has been some growth in galaxy size with time, these measurements are
upper limits on luminosity fading.Comment: 34 Total pages, 15 Written pages, 19 pages of Data Table, 13 Figures,
accepted for publication in Ap
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Polyamide Nanocomposites for Selective Laser Sintering
Current polyamide 11 and 12 are lacking in fire retardancy and high strength/high
heat resistance characteristics for a plethora of finished parts that are desired and required
for performance driven applications. It is anticipated that nanomodification of polyamide
11 and 12 will result in enhanced polymer performance, i.e., fire retardancy, high strength
and high heat resistance for polyamide 11 and 12. It is expected that these findings will
expand the market opportunities for polyamide 11 and 12 resin manufacturers.
The objective of this research is to develop improved polyamide 11 and 12 polymers
with enhanced flame retardancy, thermal, and mechanical properties for selective laser
sintering (SLS) rapid manufacturing (RM). A nanophase was introduced into the
polyamide 11 and 12 via twin screw extrusion to provide improved material properties of
the polymer blends. Arkema RILSAN® polyamide 11 molding polymer pellets and
Degussa VESTAMID® L1670 polyamide 12 were examined with three types of
nanoparticles: chemically modified montmorillonite (MMT) organoclays, surface
modified nanosilica, and carbon nanofibers (CNFs) to create polyamide 11 and 12
nanocomposites.
Wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM)
were used to determine the degree of dispersion. Injection molded test specimens were
fabricated for physical, thermal, mechanical properties, and flammability tests. Thermal
stability of these polyamide 11 and 12 nanocomposites was examined by TGA.
Mechanical properties such as tensile, flexural, and elongation at break were measured.
Flammability properties were also obtained using the Cone Calorimeter at an external
heat flux of 50 kW/m2. TEM micrographs, physical, mechanical, and flammability
properties are included in the paper. Polyamide 11 and 12 nanocomposites properties are
compared with polyamide 11 and 12 baseline polymers. Based on flammability and
mechanical material performance, selective polymers including polyamide 11
nanocomposites and control polyamide 11 were cryogenically ground into fine powders
and fabricated into SLS parts.Mechanical Engineerin
OH (1720 MHz) Masers: A Multiwavelength Study of the Interaction between the W51C Supernova Remnant and the W51B Star Forming Region
We present a comprehensive view of the W51B HII region complex and the W51C
supernova remnant (SNR) using new radio observations from the VLA, VLBA,
MERLIN, JCMT, and CSO along with archival data from Spitzer, ROSAT, ASCA, and
Chandra. Our VLA data include the first 400 cm (74 MHz) continuum image of W51
at high resolution (88 arcsec). The 400 cm image shows non-thermal emission
surrounding the G49.2-0.3 HII region, and a compact source of non-thermal
emission (W51B_NT) coincident with the previously-identified OH (1720 MHz)
maser spots, non-thermal 21 and 90 cm emission, and a hard X-ray source.
W51B_NT falls within the region of high likelihood for the position of TeV
gamma-ray emission. Using the VLBA three OH (1720 MHz) maser spots are detected
in the vicinity of W51B_NT with sizes of 60 to 300 AU and Zeeman effect
magnetic field strengths of 1.5 to 2.2 mG. The multiwavelength data demonstrate
that the northern end of the W51B HII region complex has been partly enveloped
by the advancing W51C SNR and this interaction explains the presence of W51B_NT
and the OH masers. This interaction also appears in the thermal molecular gas
which partially encircles W51B_NT and exhibits narrow pre-shock (DeltaV 5 km/s)
and broad post-shock (DeltaV 20 km/s) velocity components. RADEX radiative
transfer modeling of these two components yield physical conditions consistent
with the passage of a non-dissociative C-type shock. Confirmation of the
W51B/W51C interaction provides additional evidence in favor of this region
being one of the best candidates for hadronic particle acceleration known thus
far.Comment: Accepted to Ap
The Asymptotic Giant Branch and the Tip of the Red Giant Branch as Probes of Star Formation History: The Nearby Dwarf Irregular Galaxy KKH 98
We investigate the utility of the asymptotic giant branch (AGB) and the red
giant branch (RGB) as probes of the star formation history (SFH) of the nearby
(D=2.5 Mpc) dwarf irregular galaxy, KKH 98. Near-infrared (IR) Keck Laser Guide
Star Adaptive Optics (AO) images resolve 592 IR bright stars reaching over 1
magnitude below the Tip of the Red Giant Branch. Significantly deeper optical
(F475W and F814W) Hubble Space Telescope images of the same field contain over
2500 stars, reaching to the Red Clump and the Main Sequence turn-off for 0.5
Gyr old populations. Compared to the optical color magnitude diagram (CMD), the
near-IR CMD shows significantly tighter AGB sequences, providing a good probe
of the intermediate age (0.5 - 5 Gyr) populations. We match observed CMDs with
stellar evolution models to recover the SFH of KKH 98. On average, the galaxy
has experienced relatively constant low-level star formation (5 x 10^-4 Mo
yr^-1) for much of cosmic time. Except for the youngest main sequence
populations (age < 0.1 Gyr), which are typically fainter than the AO data flux
limit, the SFH estimated from the the 592 IR bright stars is a reasonable match
to that derived from the much larger optical data set. Differences between the
optical and IR derived SFHs for 0.1 - 1 Gyr populations suggest that current
stellar evolution models may be over-producing the AGB by as much as a factor
of three in this galaxy. At the depth of the AO data, the IR luminous stars are
not crowded. Therefore these techniques can potentially be used to determine
the stellar populations of galaxies at significantly further distances.Comment: 15 pages, 14 figs, accepted for publication in Ap
Singlet ground state in the alternating spin- chain compound NaVOAsO
We present the synthesis and a detailed investigation of structural and
magnetic properties of polycrystalline NaVOAsO by means of x-ray
diffraction, magnetization, electron spin resonance (ESR), and As
nuclear magnetic resonance (NMR) measurements as well as density-functional
band structure calculations. Temperature-dependent magnetic susceptibility, ESR
intensity, and NMR line shift could be described well using an alternating
spin- chain model with the exchange coupling K and
an alternation parameter . From the high-field magnetic
isotherm measured at K, the critical field of the gap closing is found
to be T, which corresponds to the zero-field spin gap of
K. Both NMR shift and spin-lattice relaxation
rate show an activated behavior at low temperatures, further confirming the
singlet ground state. The spin chains do not coincide with the structural
chains, whereas the couplings between the spin chains are frustrated. Because
of a relatively small spin gap, NaVOAsO is a promising compound for further
experimental studies under high magnetic fields.Comment: 14 pages, 10 figures, 2 table
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Innovative Selective Laser Sintering Rapid Manufacturing using Nanotechnology
The objective of this research is to develop an improved nylon 11 (polyamide 11) polymer
with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering
(SLS) rapid manufacturing (RM). A nanophase was introduced into nylon 11 via twin screw
extrusion to provide improved material properties of the polymer blends. Atofina (now known
as Arkema) RILSAN® nylon 11 injection molding polymer pellets was used with three types of
nanoparticles: chemically modified montmorillonite (MMT) organoclays, nanosilica, and carbon
nanofibers (CNF) to create nylon 11 nanocomposites. Wide angle X-ray diffraction (WAXD)
and transmission electron microscopy (TEM) were used to determine the degree of dispersion.
Fifteen nylon 11 nanocomposites and control nylon 11 were fabricated by injection molding.
Flammability properties (using a cone calorimeter with a radiant flux of 50 kW/m2
) and
mechanical properties such as tensile strength and modulus, flexural modulus, elongation at
break were determined for the nylon 11 nanocomposites and compared with the baseline nylon
11. Based on flammability and mechanical material performance, five polymers including four
nylon 11 nanocomposites and a control nylon 11 were cryogenically ground into fine powders
for SLS RM. SLS specimens were fabricated for flammability, mechanical, and thermal
properties characterization. Nylon 11-CNF nanocomposites exhibited the best overall properties
for this study.Mechanical Engineerin
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