6,463 research outputs found
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Polyamide Nanocomposites for Selective Laser Sintering
Current polyamide 11 and 12 are lacking in fire retardancy and high strength/high
heat resistance characteristics for a plethora of finished parts that are desired and required
for performance driven applications. It is anticipated that nanomodification of polyamide
11 and 12 will result in enhanced polymer performance, i.e., fire retardancy, high strength
and high heat resistance for polyamide 11 and 12. It is expected that these findings will
expand the market opportunities for polyamide 11 and 12 resin manufacturers.
The objective of this research is to develop improved polyamide 11 and 12 polymers
with enhanced flame retardancy, thermal, and mechanical properties for selective laser
sintering (SLS) rapid manufacturing (RM). A nanophase was introduced into the
polyamide 11 and 12 via twin screw extrusion to provide improved material properties of
the polymer blends. Arkema RILSAN® polyamide 11 molding polymer pellets and
Degussa VESTAMID® L1670 polyamide 12 were examined with three types of
nanoparticles: chemically modified montmorillonite (MMT) organoclays, surface
modified nanosilica, and carbon nanofibers (CNFs) to create polyamide 11 and 12
nanocomposites.
Wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM)
were used to determine the degree of dispersion. Injection molded test specimens were
fabricated for physical, thermal, mechanical properties, and flammability tests. Thermal
stability of these polyamide 11 and 12 nanocomposites was examined by TGA.
Mechanical properties such as tensile, flexural, and elongation at break were measured.
Flammability properties were also obtained using the Cone Calorimeter at an external
heat flux of 50 kW/m2. TEM micrographs, physical, mechanical, and flammability
properties are included in the paper. Polyamide 11 and 12 nanocomposites properties are
compared with polyamide 11 and 12 baseline polymers. Based on flammability and
mechanical material performance, selective polymers including polyamide 11
nanocomposites and control polyamide 11 were cryogenically ground into fine powders
and fabricated into SLS parts.Mechanical Engineerin
Radius Dependent Luminosity Evolution of Blue Galaxies in GOODS-N
We examine the radius-luminosity (R-L) relation for blue galaxies in the Team
Keck Redshift Survey (TKRS) of GOODS-N. We compare with a volume-limited, Sloan
Digital Sky Survey sample and find that the R-L relation has evolved to lower
surface brightness since z=1. Based on the detection limits of GOODS this can
not be explained by incompleteness in low surface-brightness galaxies. Number
density arguments rule out a pure radius evolution. It can be explained by a
radius dependent decline in B-band luminosity with time. Assuming a linear
shift in M_B with z, we use a maximum likelihood method to quantify the
evolution. Under these assumptions, large (R_{1/2} > 5 kpc), and intermediate
sized (3 < R_{1/2} < 5 kpc) galaxies, have experienced Delta M_B =1.53
(-0.10,+0.13) and 1.65 (-0.18, +0.08) magnitudes of dimming since z=1. A simple
exponential decline in star formation with an e-folding time of 3 Gyr can
result in this amount of dimming. Meanwhile, small galaxies, or some subset
thereof, have experienced more evolution, 2.55 (+/- 0.38) magnitudes. This
factor of ten decline in luminosity can be explained by sub-samples of
starbursting dwarf systems that fade rapidly, coupled with a decline in burst
strength or frequency. Samples of bursting, luminous, blue, compact galaxies at
intermediate redshifts have been identified by various previous studies. If
there has been some growth in galaxy size with time, these measurements are
upper limits on luminosity fading.Comment: 34 Total pages, 15 Written pages, 19 pages of Data Table, 13 Figures,
accepted for publication in Ap
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Innovative Selective Laser Sintering Rapid Manufacturing using Nanotechnology
The objective of this research is to develop an improved nylon 11 (polyamide 11) polymer
with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering
(SLS) rapid manufacturing (RM). A nanophase was introduced into nylon 11 via twin screw
extrusion to provide improved material properties of the polymer blends. Atofina (now known
as Arkema) RILSAN® nylon 11 injection molding polymer pellets was used with three types of
nanoparticles: chemically modified montmorillonite (MMT) organoclays, nanosilica, and carbon
nanofibers (CNF) to create nylon 11 nanocomposites. Wide angle X-ray diffraction (WAXD)
and transmission electron microscopy (TEM) were used to determine the degree of dispersion.
Fifteen nylon 11 nanocomposites and control nylon 11 were fabricated by injection molding.
Flammability properties (using a cone calorimeter with a radiant flux of 50 kW/m2
) and
mechanical properties such as tensile strength and modulus, flexural modulus, elongation at
break were determined for the nylon 11 nanocomposites and compared with the baseline nylon
11. Based on flammability and mechanical material performance, five polymers including four
nylon 11 nanocomposites and a control nylon 11 were cryogenically ground into fine powders
for SLS RM. SLS specimens were fabricated for flammability, mechanical, and thermal
properties characterization. Nylon 11-CNF nanocomposites exhibited the best overall properties
for this study.Mechanical Engineerin
Superclustering at Redshift Z=0.54
We present strong evidence for the existence of a supercluster at a redshift
of z=0.54 in the direction of Selected Area 68. From the distribution of
galaxies with spectroscopic redshifts we find that there is a large
over-density of galaxies (a factor of four over the number expected in an
unclustered universe) within the redshift range 0.530 < z < 0.555. By
considering the spatial distribution of galaxies within this redshift range
(using spectroscopic and photometric redshifts) we show that the galaxies in
SA68 form a linear structure passing from the South-West of the survey field
through to the North-East (with a position angle of approximately 35 deg East
of North). This position angle is coincident with the positions of the X-ray
clusters CL0016+16, RX J0018.3+1618 and a new X-ray cluster, RX J0018.8+1602,
centered near the radio source 54W084. All three of these sources are at a
redshift of approximately z=0.54 and have position angles, derived from their
X-ray photon distributions, consistent with that measured for the supercluster.
Assuming a redshift of 0.54 for the distribution of galaxies and a FWHM
dispersion in redshift of 0.020 this represents a coherent structure with a
radial extent of 31 Mpc, transverse dimension of 12 Mpc, and a thickness of
approximately 4 Mpc. The detection of this possible supercluster demonstrates
the power of using X-ray observations, combined with multicolor observations,
to map the large scale distribution of galaxies at intermediate redshifts.Comment: 12 pages, 3 figures, Latex, aaspp4.sty, accepted for publication in
Ap J Letters. Figure 3 and followup observations can be found at
http://tarkus.pha.jhu.edu/~ajc/papers/supercluster
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Flame Retardant Intumescent Polyamide 11 Nanocomposites – Further Study
The objective of this research is to develop improved polyamide 11 and 12 polymers with
enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering
(SLS) rapid manufacturing (RM). In the present study, a nanophase was introduced into the
polyamide 11 and combine with a conventional intumescent flame retardant (FR) additive via
twin screw extrusion. Arkema Rilsan® polyamide 11 molding polymer pellets were used with
two types of nanoparticles such as: chemically modified montmorillonite (MMT) organoclays
and carbon nanofibers (CNFs). Two types of Clariant’s Exolit® OP 1311 and 1312 intumescent
FR additives were used to generate a family of FR intumescent polyamide 11 nanocomposites
with anticipated synergism.Mechanical Engineerin
Evidences of a consolute critical point in the Phase Separation regime of La(5/8-y)Pr(y)Ca(3/8)MnO(3) (y = 0.4) single crystals
We report on DC and pulsed electric field sensitivity of the resistance of
mixed valent Mn oxide based La(5/8-y)Pr(y)Ca(3/8)MnO(3) (y = 0.4) single
crystals as a function of temperature. The low temperature regime of the
resistivity is highly current and voltage dependent. An irreversible transition
from high (HR) to a low resistivity (LR) is obtained upon the increase of the
electric field up to a temperature dependent critical value (V_c). The
current-voltage characteristics in the LR regime as well as the lack of a
variation in the magnetization response when V_c is reached indicate the
formation of a non-single connected filamentary conducting path. The
temperature dependence of V_c indicates the existence of a consolute point
where the conducting and insulating phases produce a critical behavior as a
consequence of their separation.Comment: 5 pages, 6 figures, corresponding author: C. Acha ([email protected]
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Polyamide 11-Carbon Nanotubes Nanocomposites: Preliminary Investigation
The objective of this research is to develop an improved polyamide 11 (PA11) polymer with
enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering
(SLS) rapid manufacturing. In the present study, a nanophase was introduced into polyamide 11
via twin screw extrusion. Arkema Rilsan® polyamide 11 molding polymer pellets were used
with 1, 3, 5, and 7 wt% loadings of Arkema’s GraphistrengthTM multi-wall carbon nanotubes
(MWNTs) to create a family of PA11-MWNT nanocomposites.
Transmission electron microscopy and scanning electron microscopy were used to determine
the degree and uniformity of dispersion. Injection molded test specimens were fabricated for
physical, thermal, mechanical properties, and flammability measurements. Thermal stability of
these polyamide 11-MWNT nanocomposites was examined by TGA. Mechanical properties such
as ultimate tensile strength, rupture tensile strength, and elongation at rupture were measured.
Flammability properties were also obtained using the UL 94 test method. All these different
methods and subsequent polymer characteristics are discussed in this paper.Mechanical Engineerin
The Luminosity Function of Field Galaxies in the CNOC1 Redshift Survey
We have computed the luminosity function for 389 field galaxies from the
Canadian Network for Observational Cosmology cluster redshift survey (CNOC1),
over redshifts z = 0.2-0.6. We find Schechter parameters M^* - 5 log h = -19.6
\pm 0.3 and \alpha = -0.9 \pm 0.2 in rest-frame B_{AB}. We have also split our
sample at the color of a redshifted but nonevolving Sbc galaxy, and find
distinctly different luminosity functions for red and blue galaxies. Red
galaxies have a shallow slope \alpha \approx -0.4 and dominate the bright end
of the luminosity function, while blue galaxies have a steep \alpha \approx
-1.4 and prevail at the faint end. Comparisons of the CNOC1 results to those
from the Canada-France (CFRS) and Autofib redshift surveys show broad agreement
among these independent samples, but there are also significant differences
which will require larger samples to resolve. Also, in CNOC1 the red galaxy
luminosity density stays about the same over the range z = 0.2-0.6, while the
blue galaxy luminosity density increases steadily with redshift. These results
are consistent with the trend of the luminosity density vs. redshift relations
seen in the CFRS, though the normalizations of the luminosity densities appear
to differ for blue galaxies. Comparison to the local luminosity function from
the Las Campanas redshift survey (LCRS) shows that the luminosity density at z
\approx 0.1 is only about half that seen at z \approx 0.4. A change in the
luminosity function shape, particularly at the faint end, appears to be
required to match the CNOC1 and LCRS luminosity functions, if galaxy evolution
is the sole cause of the differences seen. However, it should be noted that the
specific details of the construction of different surveys may complicate the
comparison of results and so may need to be considered carefully.Comment: 22 pages, including 6 postscript figures, uses AASTEX v4.0 style
files. Corrected minor typos and updated references. Results and conclusions
unchanged. Final version to appear in the Astrophysical Journa
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