The gas phase cyclization of deprotonated N-aryl-2-cyano-2-diazoacetamides

The document attached has been archived with permission from the publisher.1-Aryl-4-cyano-5-hydroxy-1,2,3-triazoles can be obtained in solution by base-catalysed cyclization of N-aryl-2-cyano-2-diazoacetamides. A similar reaction was shown to take place under conditions of negative ion chemical ionization in the ion source of a mass spectrometer. High resolution mass spectrometry, tandem mass spectrometry, charge reversal spectra, synthesis of the ions with known structures and quantum chemical calculations were used to prove the latter statement. The fact of the observed cyclization demonstrates once again the ability of mass spectrometry to study the gas phase chemical reactions that take place in solution.Vladislav V. Lobodin, Yuriy Yu. Morzherin, Tom Blumenthal, Daniel Bilusich, Vladimir V. Ovcharenko, John H. Bowie, and Albert T. Lebede

Parallel quantized charge pumping

Two quantized charge pumps are operated in parallel. The total current generated is shown to be far more accurate than the current produced with just one pump operating at a higher frequency. With the application of a perpendicular magnetic field the accuracy of quantization is shown to be $<$20 ppm for a current of $108.9$pA. The scheme for parallel pumping presented in this work has applications in quantum information processing, the generation of single photons in pairs and bunches, neural networking and the development of a quantum standard for electrical current. All these applications will benefit greatly from the increase in output current without the characteristic decrease in accuracy as a result of high-frequency operation

Single-parameter non-adiabatic quantized charge pumping

Controlled charge pumping in an AlGaAs/GaAs gated nanowire by single-parameter modulation is studied experimentally and theoretically. Transfer of integral multiples of the elementary charge per modulation cycle is clearly demonstrated. A simple theoretical model shows that such a quantized current can be generated via loading and unloading of a dynamic quasi-bound state. It demonstrates that non-adiabatic blockade of unwanted tunnel events can obliterate the requirement of having at least two phase-shifted periodic signals to realize quantized pumping. The simple configuration without multiple pumping signals might find wide application in metrological experiments and quantum electronics.Comment: 4 pages, 4 figure

Gamma-ray emission from massive young stellar objects

Massive stars form in dense and massive molecular cores. The exact formation mechanism is unclear, but it is possible that some massive stars are formed by processes similar to those that produce the low-mass stars, with accretion/ejection phenomena occurring at some point of the evolution of the protostar. This picture seems to be supported by the detection of a collimated stellar wind emanating from the massive protostar IRAS 16547-4247. A triple radio source is associated with the protostar: a compact core and two radio lobes. The emission of the southern lobe is clearly non-thermal. Such emission is interpreted as synchrotron radiation produced by relativistic electrons locally accelerated at the termination point of a thermal jet. Since the ambient medium is determined by the properties of the molecular cloud in which the whole system is embedded, we can expect high densities of particles and infrared photons. Because of the confirmed presence of relativistic electrons, inverse Compton and relativistic Bremsstrahlung interactions are unavoidable. Proton-proton collision should also occur, producing an injection of neutral pions. In this paper we aim at making quantitative predictions of the spectral energy distribution of the non-thermal spots generated by massive young stellar objects, with emphasis on the particular case of IRAS 16547-4247. We present spectral energy distributions for the southern lobe of this source, for a variety of conditions. We show that high-energy emission might be detectable from this object in the gamma-ray domain (MeV to TeV). The source may also be detectable at X-rays through long exposures with current X-ray instruments.Comment: 8 pages, 6 figures, accepted for publication in A&

A simple analytical model for dark matter halo structure and adiabatic contraction

A simple analytical model for describing inner parts of dark matter halo is considered. It is assumed that dark matter density is power-law. The model deals with dark matter distribution function in phase space of adiabatic invariants (radial action and angular momentum). Two variants are considered for the angular part of the distribution function: narrow and broad distribution. The model allows to describe explicitly the process of adiabatic contraction of halo due to change of gravitational potential caused by condensation of baryonic matter in the centre. The modification of dark matter density in the centre is calculated, and is it shown that the standard algorithm of adiabatic contraction calculation overestimates the compressed halo density, especially in the case of strong radial anisotropy.Comment: 5 pages, 3 figures. v3 - major improvements, another halo model introduced, discussion extende

Cosmic Voids: structure, dynamics and galaxies

In this review we discuss several aspects of Cosmic Voids. Voids are a major component of the large scale distribution of matter and galaxies in the Universe. They are of instrumental importance for understanding the emergence of the Cosmic Web. Their relatively simple shape and structure makes them into useful tools for extracting the value of a variety cosmic parameters, possibly including even that of the influence of dark energy. Perhaps most promising and challenging is the issue of the galaxies found within their realm. Not only does the pristine environment of voids provide a promising testing ground for assessing the role of environment on the formation and evolution of galaxies, the dearth of dwarf galaxies may even represent a serious challenge to the standard view of cosmic structure formation.Comment: 29 pages, 12 figures, invited review COSPA2008, Pohang, Korea. Modern Physics Letters A, accepted. For high-res version see http://www.astro.rug.nl/~weygaert/voids.cospa2008.weygaert.pd

Representation of Markov chains by random maps: existence and regularity conditions

We systematically investigate the problem of representing Markov chains by families of random maps, and which regularity of these maps can be achieved depending on the properties of the probability measures. Our key idea is to use techniques from optimal transport to select optimal such maps. Optimal transport theory also tells us how convexity properties of the supports of the measures translate into regularity properties of the maps via Legendre transforms. Thus, from this scheme, we cannot only deduce the representation by measurable random maps, but we can also obtain conditions for the representation by continuous random maps. Finally, we present conditions for the representation of Markov chain by random diffeomorphisms.Comment: 22 pages, several changes from the previous version including extended discussion of many detail

The Role of a Hot Gas Environment on the Evolution of Galaxies

Most spiral galaxies are found in galaxy groups with low velocity dispersions; most E/S0 galaxies are found in galaxy groups with relatively high velocity dispersions. The mass of the hot gas we can observe in the E/S0 groups via their thermal X-ray emission is, on average, as much as the baryonic mass of the galaxies in these groups. By comparison, galaxy clusters have as much or more hot gas than stellar mass. Hot gas in S-rich groups, however, is of low enough temperature for its X-ray emission to suffer heavy absorption due to Galactic HI and related observational effects, and hence is hard to detect. We postulate that such lower temperature hot gas does exist in low velocity dispersion, S-rich groups, and explore the consequences of this assumption. For a wide range of metallicity and density, hot gas in S-rich groups can cool in far less than a Hubble time. If such gas exists and can cool, especially when interacting with HI in existing galaxies, then it can help link together a number of disparate observations, both Galactic and extragalactic, that are otherwise difficult to understand.Comment: 16 pages with one figure. ApJ Letters, in pres

Electromagnetic Cascades and Cascade Nucleosynthesis in the Early Universe

We describe a calculation of electromagnetic cascading in radiation and matter in the early universe initiated by the decay of massive particles or by some other process. We have used a combination of Monte Carlo and numerical techniques which enables us to use exact cross sections, where known, for all the relevant processes. In cascades initiated after the epoch of big bang nucleosynthesis $\gamma$-rays in the cascades will photodisintegrate $^4$He, producing $^3$He and deuterium. Using the observed $^3$He and deuterium abundances we are able to place constraints on the cascade energy deposition as a function of cosmic time. In the case of the decay of massive primordial particles, we place limits on the density of massive primordial particles as a function of their mean decay time, and on the expected intensity of decay neutrinos.Comment: compressed and uuencoded postscript. We now include a comparison with previous work of the photon spectrum in the cascade and the limits we calculate for the density of massive particles. The method of calculation of photon spectra at low energies has been improved. Most figures are revised. Our conclusions are substantially unchange