A Comparison of the Fish Populations and Habitat in Open and Closed Salt Marsh Impoundments in East-Central Florida

Historical and recent biological surveys including aerial and ground level photographs reveal gross changes in vegetation and fish habitat associated with impoundment and flooding of salt marshes bordering the Indian River lagoon in east-central Florida. These studies show a depauperate ichthyofauna and floral association in impoundments excluded from estuarine tidal influence. Monthly collections of fishes made during 1979 and 1980 are used to compare two marsh impoundments: one closed to tidal influence from the Indian River lagoon and the other reopened to tidal influence through a single 80 em diameter culvert. The closed impoundment was found to contain a depauperate ichthyofauna consisting of 12 species collected under stressed environmental conditions. Water temperatures ranged from 14 to 34° C, salinities fluctuated widely from 2.0 to 200 ppt and dissolved oxygen was measured as low as 1.2 and as high as 14.2 ppm. The open impoundment contained a far richer ichthyofauna with 41 fish species captured at temperatures of 13.5 to 30° C, salinities of 25 to 38 ppt and dissolved oxygen levels of 2.2 to 7.5 ppm. The open impoundment also demonstrated extensive regrowth of marsh vegetation

The measurement of lubricant-film thickness using ultrasound

Ultrasound is reflected from a liquid layer between two solid bodies. This reflection depends on the ultrasonic frequency, the acoustic properties of the liquid and solid, and the layer thickness. If the wavelength is much greater than the liquid-layer thickness, then the response is governed by the stiffness of the layer. If the wavelength and layer thickness are similar, then the interaction of ultrasound with the layer is controlled by its resonant behaviour. This stiffness governed response and resonant response can be used to determine the thickness of the liquid layer, if the other parameters are known. In this paper, ultrasound has been developed as a method to determine the thickness of lubricating films in bearing systems. An ultrasonic transducer is positioned on the outside of a bearing shell such that the wave is focused on the lubricant-film layer. The transducer is used to both emit and receive wide-band ultrasonic pulses. For a particular lubricant film, the reflected pulse is processed to give a reflection-coefficient spectrum. The lubricant-film thickness is then obtained from either the layer stiffness or the resonant frequency. The method has been validated using fluid wedges at ambient pressure between flat and curved surfaces. Experiments on the elastohydrodynamic film formed between a sliding ball and a flat surface were performed. Film-thickness values in the range 50-500 nm were recorded, which agreed well with theoretical film-formation predictions. Similar measurements have been made on the oil film between the balls and outer raceway of a deep-groove ball bearing

Interaction of Gold Nanoparticles in Barium Titanate Thin Films

A novel approach to control the grain size of oxide thin film materials has been investigated. Perovskite BaTiO3 shows interesting grain structures when deposited on gold predeposited, (111)-oriented, singlecrystal SrTiO3 substrates. Solid oxide films grow epitaxially on patterned seed layers and show variations in grain size relative to the films deposited on SrTiO3 directly.Comment: 14 pages, 4 figure

Can energy fluxes be used to interpret glacial/interglacial precipitation changes in the Tropics?

Recent theoretical advances in the relationship between heat transport and the position of the inter tropical convergence zone (ITCZ) present an elegant framework through which to interpret past changes in tropical precipitation patterns. Using a very large ensemble of climate model simulations we investigate whether it is possible to use this framework to interpret changes in the position of the ITCZ in response to glacial and interglacial boundary conditions. We find that the centroid of tropical precipitation, which represents the evolution of precipitation in the whole tropics, is best correlated with heat transport changes. We find that the response of the annual mean ITCZ to glacial and interglacial boundary conditions is quite different to the response of the climatological annual cycle of the ITCZ to the seasonal cycle of insolation. We show that the reason for this is that while the Hadley Circulation plays a dominant role in transporting heat over the seasonal cycle, in the annual mean response to forcing, the Hadley Circulation is not dominant. When we look regionally, rather than at the zonal mean, we find that local precipitation is poorly related to either the zonal mean ITCZ or to meridional heat transport. We demonstrate that precipitation is spatially highly variable even when the zonal mean ITCZ is in the same location. This suggests only limited use for heat transport in explaining local precipitation records, thus there is limited scope for using heat transport changes to explain individual paleo-precipitation records

Genetically predicted complement component 4A expression: effects on memory function and middle temporal lobe activation

Background The longstanding association between the major histocompatibility complex (MHC) locus and schizophrenia (SZ) risk has recently been accounted for, partially, by structural variation at the complement component 4 (C4) gene. This structural variation generates varying levels of C4 RNA expression, and genetic information from the MHC region can now be used to predict C4 RNA expression in the brain. Increased predicted C4A RNA expression is associated with the risk of SZ, and C4 is reported to influence synaptic pruning in animal models. Methods Based on our previous studies associating MHC SZ risk variants with poorer memory performance, we tested whether increased predicted C4A RNA expression was associated with reduced memory function in a large (n = 1238) dataset of psychosis cases and healthy participants, and with altered task-dependent cortical activation in a subset of these samples. Results We observed that increased predicted C4A RNA expression predicted poorer performance on measures of memory recall (p = 0.016, corrected). Furthermore, in healthy participants, we found that increased predicted C4A RNA expression was associated with a pattern of reduced cortical activity in middle temporal cortex during a measure of visual processing (p < 0.05, corrected). Conclusions These data suggest that the effects of C4 on cognition were observable at both a cortical and behavioural level, and may represent one mechanism by which illness risk is mediated. As such, deficits in learning and memory may represent a therapeutic target for new molecular developments aimed at altering C4’s developmental role

Soliton excitations in halogen-bridged mixed-valence binuclear metal complexes

Motivated by recent stimulative observations in halogen (X)-bridged binuclear transition-metal (M) complexes, which are referred to as MMX chains, we study solitons in a one-dimensional three-quarter-filled charge-density-wave system with both intrasite and intersite electron-lattice couplings. Two distinct ground states of MMX chains are reproduced and the soliton excitations on them are compared. In the weak-coupling region, all the solitons are degenerate to each other and are uniquely scaled by the band gap, whereas in the strong-coupling region, they behave differently deviating from the scenario in the continuum limit. The soliton masses are calculated and compared with those for conventional mononuclear MX chains.Comment: 9 pages, 10 figures embedded, to be published in J. Phys. Soc. Jpn. 71, No. 1 (2002

Autosomal dominant hereditary spastic paraplegia: Novel mutations in the REEP1 gene (SPG31)

<p>Abstract</p> <p>Background</p> <p>Mutations in the <it>SPG4 </it>gene (spastin) and in the <it>SPG3A </it>gene (atlastin) account for the majority of 'pure' autosomal dominant form of hereditary spastic paraplegia (HSP). Recently, mutations in the <it>REEP1 </it>gene were identified to cause autosomal dominant HSP type SPG31. The purpose of this study was to determine the prevalence of <it>REEP1 </it>mutations in a cohort of 162 unrelated Caucasian index patients with 'pure' HSP and a positive family history (at least two persons per family presented symptoms).</p> <p>Methods</p> <p>162 patients were screened for mutations by, both, DHPLC and direct sequencing.</p> <p>Results</p> <p>Ten mutations were identified in the <it>REEP1 </it>gene, these included eight novel mutations comprising small insertions/deletions causing frame shifts and subsequently premature stop codons, one nonsense mutation and one splice site mutation as well as two missense mutations. Both missense mutations and the splice site mutation were not identified in 170 control subjects.</p> <p>Conclusion</p> <p>In our HSP cohort we found pathogenic mutations in 4.3% of cases with autosomal dominant inheritance. Our results confirm the previously observed mutation range of 3% to 6.5%, respectively, and they widen the spectrum of <it>REEP1 </it>mutations.</p

Optical and Quasi-Optical Analysis of System Components for a Far-Infrared Space Interferometer

Many important astrophysical processes occur at wavelengths that fall within the far-infrared band of the EM spectrum, and over distance scales that require sub-arc second spatial resolution. It is clear that in order to achieve sub-arc second resolution at these relatively long wavelengths (compared to optical/near-IR), which are strongly absorbed by the atmosphere, a space-based far-IR interferometer will be required. We present analysis of the optical system for a proposed spatial-spectral interferometer, discussing the challenges that arise when designing such a system and the simulation techniques employed that aim to resolve these issues. Many of these specific challenges relate to combining the beams from multiple telescopes where the wavelengths involved are relatively short (compared to radio interferometry), meaning that care must be taken with mirror surface quality, where surface form errors not only present potential degradation of the single system beams, but also serve to reduce fringe visibility when multiple telescope beams are combined. Also, the long baselines required for sub-arc second resolution present challenges when considering propagation of the relatively long wavelengths of the signal beam, where beam divergence becomes significant if the beam demagnification of the telescopes is not carefully considered. Furthermore, detection of the extremely weak far-IR signals demands ultra-sensitive detectors and instruments capable of operating at maximum efficiency. Thus, as will be shown, care must be taken when designing each component of such a complex quasioptical system

Scope and Mechanistic Study of the Coupling Reaction of α,β-Unsaturated Carbonyl Compounds with Alkenes: Uncovering Electronic Effects on Alkene Insertion vs Oxidative Coupling Pathways

The cationic ruthenium-hydride complex [(C6H6)(PCy3)(CO)RuH]+BF4– (1) was found to be a highly effective catalyst for the intermolecular conjugate addition of simple alkenes to α,β-unsaturated carbonyl compounds to give (Z)-selective tetrasubstituted olefin products. The analogous coupling reaction of cinnamides with electron-deficient olefins led to the oxidative coupling of two olefinic C–H bonds in forming (E)-selective diene products. The intramolecular version of the coupling reaction efficiently produced indene and bicyclic fulvene derivatives. The empirical rate law for the coupling reaction of ethyl cinnamate with propene was determined as follows: rate = k[1]1[propene]0[cinnamate]−1. A negligible deuterium kinetic isotope effect (kH/kD = 1.1 ± 0.1) was measured from both (E)-C6H5CH═C(CH3)CONHCH3 and (E)-C6H5CD═C(CH3)CONHCH3 with styrene. In contrast, a significant normal isotope effect (kH/kD = 1.7 ± 0.1) was observed from the reaction of (E)-C6H5CH═C(CH3)CONHCH3 with styrene and styrene-d8. A pronounced carbon isotope effect was measured from the coupling reaction of (E)-C6H5CH═CHCO2Et with propene (13C(recovered)/13C(virgin) at Cβ = 1.019(6)), while a negligible carbon isotope effect (13C(recovered)/13C(virgin) at Cβ = 0.999(4)) was obtained from the reaction of (E)-C6H5CH═C(CH3)CONHCH3 with styrene. Hammett plots from the correlation of para-substituted p-X-C6H4CH═CHCO2Et (X = OCH3, CH3, H, F, Cl, CO2Me, CF3) with propene and from the treatment of (E)-C6H5CH═CHCO2Et with a series of para-substituted styrenes p-Y-C6H4CH═CH2 (Y = OCH3, CH3, H, F, Cl, CF3) gave the positive slopes for both cases (ρ = +1.1 ± 0.1 and +1.5 ± 0.1, respectively). Eyring analysis of the coupling reaction led to the thermodynamic parameters, ΔH⧧ = 20 ± 2 kcal mol–1 and ΔS⧧ = −42 ± 5 eu. Two separate mechanistic pathways for the coupling reaction have been proposed on the basis of these kinetic and spectroscopic studies