515 research outputs found

    Sub-Glass-Transition Temperature Interface Formation Between an Immiscible Glass Rubber Pair

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    ABSTRACT: We used neutron reflectivity to measure the interfacial width in the immiscible system polystyrene/poly(n-butyl methacrylate) (PS/PnBMA). Measurements were made on the same samples at temperatures ranging from below the glasstransition temperature (T g ) of PS to slightly above. We observed significant broadening of the interface at temperatures below the T g of PS, indicating chain mobility below the bulk T g value. The interfacial width exhibited a plateau at a value of 20 Å in the temperature range of 365 K Ͻ T Ͻ 377 K. A control experiment involving hydrogenated and deuterated PS films (hPS/dPS) showed no such broadening over the same temperature region. The results are consistent with a reduction of the T g of PS in the interfacial region of ϳ20 K

    Dewetting of thin polymer films near the glass transition

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    Dewetting of ultra-thin polymer films near the glass transition exhibits unexpected front morphologies [G. Reiter, Phys. Rev. Lett., 87, 186101 (2001)]. We present here the first theoretical attempt to understand these features, focusing on the shear-thinning behaviour of these films. We analyse the profile of the dewetting film, and characterize the time evolution of the dry region radius, Rd(t)R_{d}(t), and of the rim height, hm(t)h_{m}(t). After a transient time depending on the initial thickness, hm(t)h_{m}(t) grows like t\sqrt{t} while Rd(t)R_{d}(t) increases like exp(t)\exp{(\sqrt{t})}. Different regimes of growth are expected, depending on the initial film thickness and experimental time range.Comment: 4 pages, 5 figures Revised version, published in Physical Review Letters: F. Saulnier, E. Raphael and P.-G. de Gennes, Phys. Rev. Lett. 88, 196101 (2002

    Slow dynamics near glass transitions in thin polymer films

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    The α\alpha-process (segmental motion) of thin polystyrene films supported on glass substrate has been investigated in a wider frequency range from 103^{-3} Hz to 104^4 Hz using dielectric relaxation spectroscopy and thermal expansion spectroscopy. The relaxation rate of the α\alpha-process increases with decreasing film thickness at a given temperature above the glass transition. This increase in the relaxation rate with decreasing film thickness is much more enhanced near the glass transition temperature. The glass transition temperature determined as the temperature at which the relaxation time of the α\alpha-process becomes a macroscopic time scale shows a distinct molecular weight dependence. It is also found that the Vogel temperature has the thickness dependence, i.e., the Vogel temperature decreases with decreasing film thickness. The expansion coefficient of the free volume αf\alpha_f is extracted from the temperature dependence of the relaxation time within the free volume theory. The fragility index mm is also evaluated as a function of thickness. Both αf\alpha_f and mm are found to decrease with decreasing film thickness.Comment: 9 pages, 7 figures, and 2 table

    Secondary Prevention Through Cardiac Rehabilitation: Position Paper of the Working Group on Cardiac Rehabilitation and Exercise Physiology of the European Society of Cardiology

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    The purpose of this statement is to provide specific recommendations in regard to evaluation and intervention in each of the core components of cardiac rehabilitation (CR) to assist CR staff in the design and development of their programmes; the statement should also assist health care providers, insurers, policy makers and consumers in the recognition of the comprehensive nature of such programmes. Those charged with responsibility for secondary prevention of cardiovascular disease, whether at European, at national or at individual centre level, need to consider where and how structured programmes of CR can be delivered to the large constituency of patients now considered eligible for C

    Measurement of 222Rn dissolved in water at the Sudbury Neutrino Observatory

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    The technique used at the Sudbury Neutrino Observatory (SNO) to measure the concentration of 222Rn in water is described. Water from the SNO detector is passed through a vacuum degasser (in the light water system) or a membrane contact degasser (in the heavy water system) where dissolved gases, including radon, are liberated. The degasser is connected to a vacuum system which collects the radon on a cold trap and removes most other gases, such as water vapor and nitrogen. After roughly 0.5 tonnes of H2O or 6 tonnes of D2O have been sampled, the accumulated radon is transferred to a Lucas cell. The cell is mounted on a photomultiplier tube which detects the alpha particles from the decay of 222Rn and its daughters. The overall degassing and concentration efficiency is about 38% and the single-alpha counting efficiency is approximately 75%. The sensitivity of the radon assay system for D2O is equivalent to ~3 E(-15) g U/g water. The radon concentration in both the H2O and D2O is sufficiently low that the rate of background events from U-chain elements is a small fraction of the interaction rate of solar neutrinos by the neutral current reaction.Comment: 14 pages, 6 figures; v2 has very minor change

    A radium assay technique using hydrous titanium oxide adsorbent for the Sudbury Neutrino Observatory

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    As photodisintegration of deuterons mimics the disintegration of deuterons by neutrinos, the accurate measurement of the radioactivity from thorium and uranium decay chains in the heavy water in the Sudbury Neutrino Observatory (SNO) is essential for the determination of the total solar neutrino flux. A radium assay technique of the required sensitivity is described that uses hydrous titanium oxide adsorbent on a filtration membrane together with a beta-alpha delayed coincidence counting system. For a 200 tonne assay the detection limit for 232Th is a concentration of 3 x 10^(-16) g Th/g water and for 238U of 3 x 10^(-16) g U/g water. Results of assays of both the heavy and light water carried out during the first two years of data collection of SNO are presented.Comment: 12 pages, 4 figure

    A Search for Neutrinos from the Solar hep Reaction and the Diffuse Supernova Neutrino Background with the Sudbury Neutrino Observatory

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    A search has been made for neutrinos from the hep reaction in the Sun and from the diffus
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