319 research outputs found
Nonlinear Ionic Conductivity of Thin Solid Electrolyte Samples: Comparison between Theory and Experiment
Nonlinear conductivity effects are studied experimentally and theoretically
for thin samples of disordered ionic conductors. Following previous work in
this field the {\it experimental nonlinear conductivity} of sodium ion
conducting glasses is analyzed in terms of apparent hopping distances. Values
up to 43 \AA are obtained. Due to higher-order harmonic current density
detection, any undesired effects arising from Joule heating can be excluded.
Additionally, the influence of temperature and sample thickness on the
nonlinearity is explored. From the {\it theoretical side} the nonlinear
conductivity in a disordered hopping model is analyzed numerically. For the 1D
case the nonlinearity can be even handled analytically. Surprisingly, for this
model the apparent hopping distance scales with the system size. This result
shows that in general the nonlinear conductivity cannot be interpreted in terms
of apparent hopping distances. Possible extensions of the model are discussed.Comment: 7 pages, 6 figure
Channel diffusion of sodium in a silicate glass
We use classical molecular dynamics simulations to study the dynamics of
sodium atoms in amorphous NaO-4SiO. We find that the sodium
trajectories form a well connected network of pockets and channels. Inside
these channels the motion of the atoms is not cooperative but rather given by
independent thermally activated hops of individual atoms between the pockets.
By determining the probability that an atom returns to a given starting site,
we show that such events are not important for the dynamics of this system.Comment: 10 pages of Latex, 5 figures, one figure added, text expande
Factors Affecting European Farmers’Participation in Biodiversity Policies
This article reports the major findings from an interdisciplinary research project that synthesises key insights into farmers’ willingness and ability to co-operate with biodiversity policies. The results of the study are based on an assessment of about 160
publications and research reports from six EU member states and from international comparative research.We developed a conceptual framework to systematically review the
existent literature relevant for our purposes. This framework provides a common structure for analysing farmers’ perspectives regarding the introduction into farming practices of measures relevant to biodiversity. The analysis is coupled and contrasted with a survey of experts. The results presented above suggest that it is important to view support for practices oriented towards biodiversity protection not in a static sense – as a situation determined by one or several influencing factors – but rather as a process marked by interaction. Financial compensation and incentives function as a necessary, though
clearly not sufficient condition in this process
Matrix controlled channel diffusion of sodium in amorphous silica
To find the origin of the diffusion channels observed in sodium-silicate
glasses, we have performed classical molecular dynamics simulations of
NaO--4SiO during which the mass of the Si and O atoms has been
multiplied by a tuning coefficient. We observe that the channels disappear and
that the diffusive motion of the sodium atoms vanishes if this coefficient is
larger than a threshold value. Above this threshold the vibrational states of
the matrix are not compatible with those of the sodium ions. We interpret hence
the decrease of the diffusion by the absence of resonance conditions.Comment: 5 pages, 4 figure
The trade-off between taxi time and fuel consumption in airport ground movement
Environmental impact is a very important agenda item in many sectors nowadays, which the air transportation sector is also trying to reduce
as much as possible. One area which has remained relatively unexplored in this context is the ground movement problem for aircraft on the airport’s surface.
Aircraft have to be routed from a gate to a runway and vice versa and it is
still unknown whether fuel burn and environmental impact reductions will best result from purely minimising the taxi times or whether it is also important to avoid multiple acceleration phases. This paper presents a newly developed multi-objective approach for analysing the trade-off between taxi time and fuel consumption during taxiing. The approach consists of a combination of a graph-based routing algorithm and a population adaptive immune algorithm to discover different speed profiles of aircraft. Analysis with data from a European hub airport has highlighted the impressive performance of the new approach. Furthermore, it is shown that the trade-off between taxi time and fuel consumption is very sensitive to the fuel-related objective function which is used
Complex lithium ion dynamics in simulated LiPO3 glass studied by means of multi-time correlation functions
Molecular dynamics simulations are performed to study the lithium jumps in
LiPO3 glass. In particular, we calculate higher-order correlation functions
that probe the positions of single lithium ions at several times. Three-time
correlation functions show that the non-exponential relaxation of the lithium
ions results from both correlated back-and-forth jumps and the existence of
dynamical heterogeneities, i.e., the presence of a broad distribution of jump
rates. A quantitative analysis yields that the contribution of the dynamical
heterogeneities to the non-exponential depopulation of the lithium sites
increases upon cooling. Further, correlated back-and-forth jumps between
neighboring sites are observed for the fast ions of the distribution, but not
for the slow ions and, hence, the back-jump probability depends on the
dynamical state. Four-time correlation functions indicate that an exchange
between fast and slow ions takes place on the timescale of the jumps
themselves, i.e., the dynamical heterogeneities are short-lived. Hence, sites
featuring fast and slow lithium dynamics, respectively, are intimately mixed.
In addition, a backward correlation beyond the first neighbor shell for highly
mobile ions and the presence of long-range dynamical heterogeneities suggest
that fast ion migration occurs along preferential pathways in the glassy
matrix. In the melt, we find no evidence for correlated back-and-forth motions
and dynamical heterogeneities on the length scale of the next-neighbor
distance.Comment: 12 pages, 13 figure
Time-resolved XUV Opacity Measurements of Warm-Dense Aluminium
The free-free opacity in plasmas is fundamental to our understanding of
energy transport in stellar interiors and for inertial confinement fusion
research. However, theoretical predictions in the challenging dense plasma
regime are conflicting and there is a dearth of accurate experimental data to
allow for direct model validation. Here we present time-resolved transmission
measurements in solid-density Al heated by an XUV free-electron laser. We use a
novel functional optimization approach to extract the temperature-dependent
absorption coefficient directly from an oversampled pool of single-shot
measurements, and find a pronounced enhancement of the opacity as the plasma is
heated to temperatures of order the Fermi energy. Plasma heating and
opacity-enhancement is observed on ultrafast time scales, within the duration
of the femtosecond XUV pulse. We attribute further rises in the opacity on ps
timescales to melt and the formation of warm-dense matter
The electric double layer has a life of its own
Using molecular dynamics simulations with recently developed importance
sampling methods, we show that the differential capacitance of a model ionic
liquid based double-layer capacitor exhibits an anomalous dependence on the
applied electrical potential. Such behavior is qualitatively incompatible with
standard mean-field theories of the electrical double layer, but is consistent
with observations made in experiment. The anomalous response results from
structural changes induced in the interfacial region of the ionic liquid as it
develops a charge density to screen the charge induced on the electrode
surface. These structural changes are strongly influenced by the out-of-plane
layering of the electrolyte and are multifaceted, including an abrupt local
ordering of the ions adsorbed in the plane of the electrode surface,
reorientation of molecular ions, and the spontaneous exchange of ions between
different layers of the electrolyte close to the electrode surface. The local
ordering exhibits signatures of a first-order phase transition, which would
indicate a singular charge-density transition in a macroscopic limit
The uptake of different tillage practices in England
Reduced tillage systems have been argued to provide several potential benefits to soil, environment and to farm incomes. In England, while many farms have partially adopted such practices, a large proportion of arable farmers do not undertake reduced tillage in any form. This paper analyses the rationale for and uptake of different cultivation techniques, including analysis of the barriers to adoption of reduced tillage, aiming to benefit policy makers and researchers and increase the spread of smart agricultural practices. Based on a postal questionnaire, we estimated that 47.6% of English arable land is cultivated using minimum‐tillage and 7% under no‐tillage. As farm size increased, so did the probability of reduced tillage uptake. Furthermore, farms growing combinable crops were more likely to utilise reduced tillage approaches than other farm types. Soil type, weed control and weather conditions were noted as the main drivers for ‘strategic' and ‘rotational' ploughing, constraining continuous reduced tillage use. To effect greater reduced tillage uptake, greater communication between researchers and farmers is needed to facilitate the implementation of sustainable soil management solutions, supported by current legislation permitting responsible herbicide use in arable production. Financial support to access reduced tillage machinery may also be required for farmers operating smaller holdings. Adopting reduced tillage is a continuous learning process requiring ongoing training and information‐gathering; supporting a network of reduced tillage ‘farmer champions' would facilitate practical knowledge exchange, allow farmers to observe soil improvements, understand transition phase barriers, and ultimately encourage increased reduced tillage uptake
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