Diffusive transport in spin-1 chains at high temperatures

We present a numerical study on the spin and thermal conductivities of the spin-1 Heisenberg chain in the high temperature limit, in particular of the Drude weight contribution and frequency dependence. We use the Exact Diagonalization and the recently developed microcanonical Lanczos method; it allows us a finite size scaling analysis by the study of significantly larger lattices. This work, pointing to a diffusive rather than ballistic behavior is discussed with respect to other recent theoretical and experimental studies

When spring ephemerals fail to meet pollinators: Mechanism of phenological mismatch and its impact on plant reproduction

The flowering phenology of early-blooming plants is largely determined by snowmelt timing in high-latitude and high-altitude ecosystems. When the synchrony of flowering and pollinator emergence is disturbed by climate change, seed production may be restricted due to insufficient pollination success. We revealed the mechanism of phenological mismatch between a spring ephemeral (Corydalis ambigua) and its pollinator (overwintered bumblebees), and its impact on plant reproduction, based on 19 years of monitoring and a snow removal experiment in a cool-temperate forest in northern Japan. Early snowmelt increased the risk of phenological mismatch under natural conditions. Seed production was limited by pollination success over the 3 years of the pollination experiment and decreased when flowering occurred prior to bee emergence. Similar trends were detected on modification of flowering phenology through snow removal. Following snowmelt, the length of the pre-flowering period strongly depended on the ambient surface temperature, ranging from 4 days (at greater than 7°C) to 26 days (at 2.5°C). Flowering onset was explained with an accumulated surface degree-day model. Bumblebees emerged when soil temperature reached 6°C, which was predictable by an accumulated soil degree-day model, although foraging activity after emergence might depend on air temperature. These results indicate that phenological mismatch tends to occur when snow melts early but subsequent soil warming progresses slowly. Thus, modification of the snowmelt regime could be a major driver disturbing spring phenology in northern ecosystems

High temperature thermal conductivity of 2-leg spin-1/2 ladders

Based on numerical simulations, a study of the high temperature, finite frequency, thermal conductivity $\kappa(\omega)$ of spin-1/2 ladders is presented. The exact diagonalization and a novel Lanczos technique are employed.The conductivity spectra, analyzed as a function of rung coupling, point to a non-diverging $dc-$limit but to an unconventional low frequency behavior. The results are discussed with perspective recent experiments indicating a significant magnetic contribution to the energy transport in quasi-one dimensional compounds.Comment: 4 pages, 4 figure

Synthesis and Characterization of Ruthenium Complexes Containing Chlorophenanthroline and Bipyridine

The divalent ruthenium polypyridine complexes hold promise as efficient photocatalysts for solar energy conversion schemes. This paper deals with the synthesis and spectroscopic investigation of ruthenium polypyridine complexes, which may be useful as photosensitizers. The homoleptic ruthenium(II) complex Ru(Cl-phen)3(PF6)2 (where Cl-phen = 5- chloro-1,10-phenanthroline), and heteroleptic ruthenium(II) complexes Ru(Cl-phen)2(bpy)(PF6)2, and Ru(Cl-phen)(bpy)2(PF6)2 (where bpy = 2,2′-bipyridine) have been prepared by following the standard synthetic procedure. Silica and alumina column chromatographies were used to purify the compounds. Mass spectroscopy, nuclear magnetic resonance (nmr) spectroscopy, and elemental analysis were used to confirm the identity and the integrity of the complexes. Absorption and emission spectroscopies in addition to cyclic voltammetry were used to investigate the properties of these complexes. The absorption spectra of all complexes consist of a series of absorption bands in the ultraviolet and visible regions. All three complexes show a strong emission band in the visible region. Cyclic-voltammetric investigations indicate that the chloro substitution either has little impact on the redox properties of the complexes or alters the redox properties in an advantageous manner

Synthesis and Characterization of Ruthenium Complexes Containing Chlorophenanthroline and Bipyridine

The divalent ruthenium polypyridine complexes hold promise as efficient photocatalysts for solar energy conversion schemes. This paper deals with the synthesis and spectroscopic investigation of ruthenium polypyridine complexes, which may be useful as photosensitizers. The homoleptic ruthenium(II) complex Ru(Cl-phen)3(PF6)2 (where Cl-phen = 5- chloro-1,10-phenanthroline), and heteroleptic ruthenium(II) complexes Ru(Cl-phen)2(bpy)(PF6)2, and Ru(Cl-phen)(bpy)2(PF6)2 (where bpy = 2,2′-bipyridine) have been prepared by following the standard synthetic procedure. Silica and alumina column chromatographies were used to purify the compounds. Mass spectroscopy, nuclear magnetic resonance (nmr) spectroscopy, and elemental analysis were used to confirm the identity and the integrity of the complexes. Absorption and emission spectroscopies in addition to cyclic voltammetry were used to investigate the properties of these complexes. The absorption spectra of all complexes consist of a series of absorption bands in the ultraviolet and visible regions. All three complexes show a strong emission band in the visible region. Cyclic-voltammetric investigations indicate that the chloro substitution either has little impact on the redox properties of the complexes or alters the redox properties in an advantageous manner

Thermal Conductivity in the Bose-Einstein Condensed State of Triplons in the Bond-Alternating Spin-Chain System Pb2V3O9

In order to clarify the origin of the enhancement of the thermal conductivity in the Bose-Einstein Condensed (BEC) state of field-induced triplons, we have measured the thermal conductivity along the [101] direction parallel to spin-chains, $kappa_{\|[101]}$, and perpendicular to spin-chains, $kappa_{\perp[101]}$, of the S=1/2 bond-alternating spin-chain system Pb2V3O9 in magnetic fields up to 14 T. With increasing field at 3 K, it has been found that both $kappa_{\|[101]}$ and $kappa_{\perp[101]}$ are suppressed in the gapped normal state in low fields. In the BEC state of field-induced triplons in high fields, on the other hand, $kappa_{\|[101]}$ is enhanced with increasing field, while $kappa_{\perp[101]}$ is suppressed. That is, the thermal conductivity along the direction, where the magnetic interaction is strong, is markedly enhanced in the BEC state. Accordingly, our results suggest that the enhancement of $kappa_{\|[101]}$ in the BEC state is caused by the enhancement of the thermal conductivity due to triplons on the basis of the two-fluid model, as in the case of the superfluid state of liquid 4He.Comment: 5 pages, 3 figure

Candidate local parent Hamiltonian for 3/7 fractional quantum Hall effect

While a parent Hamiltonian for Laughlin $1/3$ wave function has been long known in terms of the Haldane pseudopotentials, no parent Hamiltonians are known for the lowest-Landau-level projected wave functions of the composite fermion theory at $n/(2n+1)$ with $n\geq2$. If one takes the two lowest Landau levels to be degenerate, the Trugman-Kivelson interaction produces the unprojected 2/5 wave function as the unique zero energy solution. If the lowest three Landau levels are assumed to be degenerate, the Trugman-Kivelson interaction produces a large number of zero energy states at $\nu=3/7$. We propose that adding an appropriately constructed three-body interaction yields the unprojected $3/7$ wave function as the unique zero energy solution, and report extensive exact diagonalization studies that provide strong support to this proposal.Comment: 11 pages, 2 figure

Exactly Solvable Hamiltonian for Non-Abelian Quasiparticles

Particles obeying non-Abelian braid statistics have been predicted to emerge in the fractional quantum Hall effect. In particular, a model Hamiltonian with short-range three-body interaction ($\hat{V}^\text{Pf}_3$) between electrons confined to the lowest Landau level provides exact solutions for quasiholes, and thereby allows a proof of principle for the existence of quasiholes obeying non-Abelian braid statistics. We construct, in terms of two- and three- body Haldane pseudopotentials, a model Hamiltonian that can be solved exactly for both quasiholes and quasiparticles, and provide evidence of non-Abelian statistics for the latter as well. The structure of the quasiparticle states of this model is in agreement with that predicted by the bipartite composite-fermion model of quasiparticles with exact lowest Landau level projection. We further demonstrate adiabatic continuity for the ground state, the ordinary neutral excitation, and the topological exciton as we deform our model Hamiltonian continuously into the lowest Landau-level $\hat{V}^\text{Pf}_3$ Hamiltonian.Comment: 15 pages, 10 figure