Electrostatic deflection of the water molecule: A fundamental asymmetric rotor.

An inhomogeneous electric field is used to study the deflection of a supersonic beam of water molecules. The deflection profiles show strong broadening accompanied by a small net displacement towards higher electric fields. The profiles are in excellent agreement with a calculation of rotational Stark shifts. The molecular rotational temperature being the only adjustable parameter, beam deflection is found to offer an accurate and practical means of determining this quantity. A pair of especially strongly responding rotational sublevels, adding up to ≈25% of the total beam intensity, are readily separated by deflection, making them potentially useful for further electrostatic manipulation. © 2007 The American Physical Society

Exploring the Spectrum of Heavy Quarkonium Hybrids with QCD Sum Rules

QCD Laplace sum rules are used to calculate heavy quarkonium (charmonium and bottomonium) hybrid masses in several distinct $J^{PC}$ channels. Previous studies of heavy quarkonium hybrids did not include the effects of dimension-six condensates, leading to unstable sum rules and unreliable mass predictions in some channels. We have updated these sum rules to include dimension-six condensates, providing new mass predictions for the spectra of heavy quarkonium hybrids. We confirm the finding of other approaches that the negative-parity $J^{PC}=(0,1,2)^{-+},\,1^{--}$ states form the lightest hybrid supermultiplet and the positive-parity $J^{PC}=(0,1)^{+-},\,(0,1,2)^{++}$ states are members of a heavier supermultiplet. Our results disfavor a pure charmonium hybrid interpretation of the $X(3872)$, in agreement with previous work.Comment: Presented by RTK at the Theory Canada 9 Conference, held at Wilfrid Laurier University in June 2014. Submitted for the conference proceedings to be published in the Canadian Journal of Physics. 5 pages, 1 figure. Version 2: reference added, typo correcte

QCD Sum Rule Analysis of Heavy Quarkonium Hybrids

We have studied the charmonium and bottomonium hybrid states with various $J^{PC}$ quantum numbers in QCD sum rules. At leading order in $\alpha_s$, the two-point correlation functions have been calculated up to dimension six including the tri-gluon condensate and four-quark condensate. After performing the QCD sum rule analysis, we have confirmed that the dimension six condensates can stabilize the hybrid sum rules and allow the reliable mass predictions. We have updated the mass spectra of the charmonium and bottomonium hybrid states and identified that the negative-parity states with $J^{PC}=(0, 1, 2)^{-+}, 1^{--}$ form the lightest hybrid supermultiplet while the positive-parity states with $J^{PC}=(0, 1)^{+-}, (0, 1, 2)^{++}$ belong to a heavier hybrid supermultiplet.Comment: 7 pages, 1 figures. Some minor edits have been made. Presentation at the DPF 2013 Meeting of the American Physical Society Division of Particles and Fields, Santa Cruz, California, August 13-17, 201

High-resolution Laser Spectroscopy of NO2 just above the X2 A1-A2B conical intersection: Transitions of K_=1 stacks

The complexity of the absorption spectrum of NO2NO2 can be attributed to a conical intersection of the potential energy surfaces of the two lowest electronic states, the electronic ground state of 2A12A1 symmetry and the first electronically excited state of 2B22B2 symmetry. In a previous paper we reported on the feasibility of using the hyperfine splittings, specifically the Fermi-contact interaction, to determine the electronic ground state character of the excited vibronic states in the region just above the conical intersection; 10 000 to 14 000 cm−114 000 cm−1 above the electronic ground state. High-resolution spectra of a number of vibronic bands in this region were measured by exciting a supersonically cooled beam of NO2NO2 molecules with a narrow-band Ti:Sapphire ring laser. The energy absorbed by the molecules was detected by the use of a bolometer. In the region of interest, rovibronic interactions play no significant role, with the possible exception of the vibronic band at 12 658 cm−1,12 658 cm−1, so that the fine- and hyperfine structure of each rotational transition could be analyzed by using an effective Hamiltonian. In the previous paper we restricted ourselves to an analysis of transitions of the K⎯=0K−=0 stack. In the present paper we extend the analysis to transitions of the K⎯=1K−=1 stack, from which, in addition to hyperfine coupling constants, values of the AA rotational constants of the excited NO2NO2 molecules can be determined. Those rotational constants also contain information about the electronic composition of the vibronic states, and, moreover, about the geometry of the NO2NO2 molecule in the excited state of interest. The results of our analyses are compared with those obtained by other authors. The conclusion arrived at in our previous paper that determining Fermi-constants is useful to help characterize the vibronic bands, is corroborated. In addition, the AA rotational constants correspond to geometries that are consistent with the electronic composition of the relevant excited states as expected from the Fermi-constants

Water vapor at a translational temperature of one kelvin

We report the creation of a confined slow beam of heavy-water (D2O) molecules with a translational temperature around 1 kelvin. This is achieved by filtering slow D2O from a thermal ensemble with inhomogeneous static electric fields exploiting the quadratic Stark shift of D2O. All previous demonstrations of electric field manipulation of cold dipolar molecules rely on a predominantly linear Stark shift. Further, on the basis of elementary molecular properties and our filtering technique we argue that our D2O beam contains molecules in only a few ro-vibrational states.Comment: 4 pages, 4 figures, 1 tabl

Adiabatic orientation of rotating dipole molecules in an external field

The induced polarization of a beam of polar clusters or molecules passing through an electric or magnetic field region differs from the textbook Langevin-Debye susceptibility. This distinction, which is important for the interpretation of deflection and focusing experiments, arises because instead of acquiring thermal equilibrium in the field region, the beam ensemble typically enters the field adiabatically, i.e., with a previously fixed distribution of rotational states. We discuss the orientation of rigid symmetric-top systems with a body-fixed electric or magnetic dipole moment. The analytical expression for their "adiabatic-entry" orientation is elucidated and compared with exact numerical results for a range of parameters. The differences between the polarization of thermodynamic and "adiabatic-entry" ensembles, of prolate and oblate tops, and of symmetric-top and linear rotators are illustrated and identified.Comment: 18 pages, 4 figure

Mass Spectrum of Heavy Quarkonium Hybrids

We have extended the calculation of the correlation functions of heavy quarkonium hybrid operators with various $J^{PC}$ quantum numbers to include QCD condensates up to dimension six. In contrast to previous analyses which were unable to optimize the QCD sum-rules for certain $J^{PC}$, recent work has shown that inclusion of dimension six condensates stabilizes the hybrid sum-rules and permits reliable mass predictions. In this work we have investigated the effects of the dimension six condensates on the remaining channels. After performing the QCD sum-rule analysis, we update the mass spectra of charmonium and bottomonium hybrids with exotic and non-exotic quantum numbers. We identify that the negative-parity states with $J^{PC}=(0, 1, 2)^{-+}, 1^{--}$ form the lightest hybrid supermultiplet while the positive-parity states with $J^{PC}=(0, 1)^{+-}, (0, 1, 2)^{++}$ belong to a heavier hybrid supermultiplet, confirming the supermultiplet structure found in other approaches. The hybrid with $J^{PC}=0^{--}$ has a much higher mass which may suggest a different excitation of the gluonic field compared to other channels. In agreement with previous results, we find that the $J^{PC}=1^{++}$ charmonium hybrid is substantially heavier than the X(3872), which seems to preclude a pure charmonium hybrid interpretation for this state.Comment: 17 pages, 7 figures, 4 table

Theoretical description of adiabatic laser alignment and mixed-field orientation: the need for a non-adiabatic model

We present a theoretical study of recent laser-alignment and mixed-field-orientation experiments of asymmetric top molecules. In these experiments, pendular states were created using linearly polarized strong ac electric fields from pulsed lasers in combination with weak electrostatic fields. We compare the outcome of our calculations with experimental results obtained for the prototypical large molecule benzonitrile (C$_7$H$_5$N) [J.L. Hansen et al, Phys. Rev. A, 83, 023406 (2011)] and explore the directional properties of the molecular ensemble for several field configurations, i.e., for various field strengths and angles between ac and dc fields. For perpendicular fields one obtains pure alignment, which is well reproduced by the simulations. For tilted fields, we show that a fully adiabatic description of the process does not reproduce the experimentally observed orientation, and it is mandatory to use a diabatic model for population transfer between rotational states. We develop such a model and compare its outcome to the experimental data confirming the importance of non-adiabatic processes in the field-dressed molecular dynamics.Comment: 11 pages, 9 figure