On the unsteady behavior of turbulence models

Periodically forced turbulence is used as a test case to evaluate the predictions of two-equation and multiple-scale turbulence models in unsteady flows. The limitations of the two-equation model are shown to originate in the basic assumption of spectral equilibrium. A multiple-scale model based on a picture of stepwise energy cascade overcomes some of these limitations, but the absence of nonlocal interactions proves to lead to poor predictions of the time variation of the dissipation rate. A new multiple-scale model that includes nonlocal interactions is proposed and shown to reproduce the main features of the frequency response correctly

Off-Shell Electromagnetic Form Fators of the Nucleon in Chiral Perturbation Theory

We study the electromagnetic form factors of a nucleon in next-to-leading order chiral perturbation theory (CPT) in the case where one of the nucleons is off its mass shell. We calculate the leading nonanalytic contributions to relevant measures for the off-shell dependence in the limited kinematical range allowed.Comment: 3 pages LaTeX with worldsci.sty (available by mailing [email protected] and typing "get worldsci.sty" in the subject line), invited talk given at the International Symposium on Medium Energy Physics, Beijing, August 199

A generalized approach for the calculation and automation of potentiometric titrations Part 2. Redox Titrations

The very fast calculation procedure described earlier is applied to calculate the titration curves of complicated redox systems. The theory is extended slightly to cover inhomogeneous redox systems. Titrations of iodine or 2,6-dichloroindophenol with ascorbic acid are described. It is shown that correspondence between theory and practice is good as long as the relevant stability constants and redox potentials are known with sufficient accuracy

A generalized approach for the calculation and automation of potentiometric titrations Part 1. Acid-Base Titrations

Fast and accurate calculation procedures for pH and redox potentials are required for optimum control of automatic titrations. The procedure suggested is based on a three-dimensional titration curve V = f(pH, redox potential). All possible interactions between species in the solution, e.g., changes in activity coefficients and influences of redox potential on pH variations, are taken into account. The number of titrant additions can be reduced considerably without loss of precision, by using the fact that the pH of a protolyte or mixture of protolytes at some fraction titrated does not depend strongly on the actual concentration

Turbulence and turbulent pattern formation in a minimal model for active fluids

Active matter systems display a fascinating range of dynamical states, including stationary patterns and turbulent phases. While the former can be tackled with methods from the field of pattern formation, the spatio-temporal disorder of the active turbulence phase calls for a statistical description. Borrowing techniques from turbulence theory, we here establish a quantitative description of correlation functions and spectra of a minimal continuum model for active turbulence. Further exploring the parameter space, we also report on a surprising type of turbulence-driven pattern formation far beyond linear onset: the emergence of a dynamic hexagonal vortex lattice state after an extended turbulent transient, which can only be explained taking into account turbulent energy transfer across scales.Comment: Supplemental videos available at https://youtu.be/gbf6cRho03w https://youtu.be/n0qUUhAUJFQ https://youtu.be/LGmamkM012

Extreme Lagrangian acceleration in confined turbulent flow

A Lagrangian study of two-dimensional turbulence for two different geometries, a periodic and a confined circular geometry, is presented to investigate the influence of solid boundaries on the Lagrangian dynamics. It is found that the Lagrangian acceleration is even more intermittent in the confined domain than in the periodic domain. The flatness of the Lagrangian acceleration as a function of the radius shows that the influence of the wall on the Lagrangian dynamics becomes negligible in the center of the domain and it also reveals that the wall is responsible for the increased intermittency. The transition in the Lagrangian statistics between this region, not directly influenced by the walls, and a critical radius which defines a Lagrangian boundary layer, is shown to be very sharp with a sudden increase of the acceleration flatness from about 5 to about 20