Wholly Aromatic Ether-Imides as n-Type Semiconductors

Some wholly aromatic ether-imides consisting of rod-shaped, relatively-low-mass molecules that can form liquid crystals have been investigated for potential utility as electron-donor-type (ntype) organic semiconductors. It is envisioned that after further research to improve understanding of their physical and chemical properties, compounds of this type would be used to make thin film semiconductor devices (e.g., photovoltaic cells and field-effect transistors) on flexible electronic-circuit substrates. This investigation was inspired by several prior developments: Poly(ether-imides) [PEIs] are a class of engineering plastics that have been used extensively in the form of films in a variety of electronic applications, including insulating layers, circuit boards, and low-permittivity coatings. Wholly aromatic PEIs containing naphthalene and perylene moieties have been shown to be useful as electrochromic polymers. More recently, low-molecular-weight imides comprising naphthalene-based molecules with terminal fluorinated tails were shown to be useful as n-type organic semiconductors in such devices as field-effect transistors and Schottky diodes. Poly(etherimide)s as structural resins have been extensively investigated at NASA Langley Research Center for over 30 years. More recently, the need for multi-functional materials has become increasingly important. This n-type semiconductor illustrates the scope of current work towards new families of PEIs that not only can be used as structural resins for carbon-fiber reinforced composites, but also can function as sensors. Such a multi-functional material would permit so-called in-situ health monitoring of composite structures during service. The work presented here demonstrates that parts of the PEI backbone can be used as an n-type semiconductor with such materials being sensitive to damage, temperature, stress, and pressure. In the near future, multi-functional or "smart" composite structures are envisioned to be able to communicate such important parameters to the flight crew and provide vital information with respect to the operational status of their aircraft

The MOSDEF survey: a stellar mass-SFR-metallicity relation exists at z∼2.3z\sim2.3

We investigate the nature of the relation among stellar mass, star-formation rate, and gas-phase metallicity (the M$_*$-SFR-Z relation) at high redshifts using a sample of 260 star-forming galaxies at $z\sim2.3$ from the MOSDEF survey. We present an analysis of the high-redshift M$_*$-SFR-Z relation based on several emission-line ratios for the first time. We show that a M$_*$-SFR-Z relation clearly exists at $z\sim2.3$. The strength of this relation is similar to predictions from cosmological hydrodynamical simulations. By performing a direct comparison of stacks of $z\sim0$ and $z\sim2.3$ galaxies, we find that $z\sim2.3$ galaxies have $\sim0.1$ dex lower metallicity at fixed M$_*$ and SFR. In the context of chemical evolution models, this evolution of the M$_*$-SFR-Z relation suggests an increase with redshift of the mass-loading factor at fixed M$_*$, as well as a decrease in the metallicity of infalling gas that is likely due to a lower importance of gas recycling relative to accretion from the intergalactic medium at high redshifts. Performing this analysis simultaneously with multiple metallicity-sensitive line ratios allows us to rule out the evolution in physical conditions (e.g., N/O ratio, ionization parameter, and hardness of the ionizing spectrum) at fixed metallicity as the source of the observed trends with redshift and with SFR at fixed M$_*$ at $z\sim2.3$. While this study highlights the promise of performing high-order tests of chemical evolution models at high redshifts, detailed quantitative comparisons ultimately await a full understanding of the evolution of metallicity calibrations with redshift.Comment: 19 pages, 8 figures, accepted to Ap

The MOSDEF Survey: Kinematic and Structural Evolution of Star-Forming Galaxies at 1.4≤z≤3.81.4\leq z\leq 3.8

We present ionized gas kinematics for 681 galaxies at $z\sim 1.4-3.8$ from the MOSFIRE Deep Evolution Field survey, measured using models which account for random galaxy-slit misalignments together with structural parameters derived from CANDELS Hubble Space Telescope (HST) imaging. Kinematics and sizes are used to derive dynamical masses. Baryonic masses are estimated from stellar masses and inferred gas masses from dust-corrected star formation rates (SFRs) and the Kennicutt-Schmidt relation. We measure resolved rotation for 105 galaxies. For the remaining 576 galaxies we use models based on HST imaging structural parameters together with integrated velocity dispersions and baryonic masses to statistically constrain the median ratio of intrinsic ordered to disordered motion, $V/\sigma_{V,0}$. We find that $V/\sigma_{V,0}$ increases with increasing stellar mass and decreasing specific SFR (sSFR). These trends may reflect marginal disk stability, where systems with higher gas fractions have thicker disks. For galaxies with detected rotation we assess trends between their kinematics and mass, sSFR, and baryon surface density ($\Sigma_{\mathrm{bar},e}$). Intrinsic dispersion correlates most with $\Sigma_{\mathrm{bar},e}$ and velocity correlates most with mass. By comparing dynamical and baryonic masses, we find that galaxies at $z\sim 1.4-3.8$ are baryon dominated within their effective radii ($R_E$), with Mdyn/Mbaryon increasing over time. The inferred baryon fractions within $R_E$, $f_{\mathrm{bar}}$, decrease over time, even at fixed mass, size, or surface density. At fixed redshift, $f_{\mathrm{bar}}$ does not appear to vary with stellar mass but increases with decreasing $R_E$ and increasing $\Sigma_{\mathrm{bar},e}$. For galaxies at $z\geq2$, the median inferred baryon fractions generally exceed 100%. We discuss possible explanations and future avenues to resolve this tension.Comment: Accepted to ApJ. Added Figure 9, corrected sample size (main results unchanged). 28 pages, 13 figure

The MOSDEF Survey: An Improved Voronoi Binning Technique on Spatially Resolved Stellar Populations at z~2

We use a sample of 350 star-forming galaxies at $1.25<z<2.66$ from the MOSFIRE Deep Evolution Field survey to demonstrate an improved Voronoi binning technique that we use to study the properties of resolved stellar populations in $z\sim2$ galaxies. Stellar population and dust maps are constructed from the high-resolution CANDELS/3D-HST multi-band imaging. Rather than constructing the layout of resolved elements (i.e., Voronoi bins) from the S/N distribution of the $H_{160}$-band alone, we introduce a modified Voronoi binning method that additionally incorporates the S/N distribution of several resolved filters. The SED-derived resolved E(B-V)$_{\text{stars}}$, stellar population ages, SFRs, and stellar masses that are inferred from the Voronoi bins constructed from multiple filters are generally consistent with the properties inferred from the integrated photometry within the uncertainties, with the exception of the inferred E(B-V)$_{\text{stars}}$ from our $z\sim1.5$ sample due to their UV slopes being unconstrained by the resolved photometry. The results from our multi-filter Voronoi binning technique are compared to those derived from a "traditional" single-filter Voronoi binning approach. We find that single-filter binning produces inferred E(B-V)$_{\text{stars}}$ that are systematically redder by 0.02 mag on average, but could differ by up to 0.20 mag, and could be attributed to poorly constrained resolved photometry covering the UV slope. Overall, we advocate that our methodology produces more reliable SED-derived parameters due to the best-fit resolved SEDs being better constrained at all resolved wavelengths--particularly those covering the UV slope.Comment: 23 pages, 15 figures, accepted for publication in MNRA

En busca del consenso: encuentro usando Wooclap para la reflexión sobre la Innovación Docente

La innovación docente desempeña un papel fundamental en la educación universitaria porque, gracias a ella, se preserva la calidad de la enseñanza y se promueven aprendizajes significativos. Durante la Semana de la Innovación Docente de la Universidad Rey Juan Carlos se organizó un encuentro para buscar un consenso entre expertos en torno al paradigma de la innovación educativa universitaria. Mediante el uso de la plataforma interactiva Wooclap, se llevó a cabo un debate de tres horas donde los participantes compartieron sus perspectivas e ideas. El objetivo de este trabajo es mostrar una estrategia de dinamización utilizando herramientas digitales de interacción y presentar los resultados de las reflexiones de los expertos en torno a la innovación docente, buscando proporcionar una base sólida para futuros desarrollos en este campo en constante evolución. De los resultados se infiere, como conclusión principal, que realizar acciones de innovación docente mejora el proceso de enseñanza-aprendizaje en el estudiantado universitario

The MOSDEF Survey: The First Direct Measurements of the Nebular Dust Attenuation Curve at High Redshift

We use a sample of 532 star-forming galaxies at redshifts z ≃ 1.4–2.6 with deep rest-frame optical spectra from the MOSFIRE Deep Evolution Field (MOSDEF) survey to place the first constraints on the nebular attenuation curve at high redshift. Based on the first five low-order Balmer emission lines detected in the composite spectra of these galaxies (Hα through Hε), we derive a nebular attenuation curve that is similar in shape to that of the Galactic extinction curve, suggesting that the dust covering fraction and absorption/scattering properties along the lines of sight to massive stars at high redshift are similar to those of the average Milky Way sight line. The curve derived here implies nebular reddening values that are, on average, systematically larger than those derived for the stellar continuum. In the context of stellar population synthesis models that include the effects of stellar multiplicity, the difference in reddening of the nebular lines and stellar continuum may imply molecular cloud crossing timescales that are a factor of ≳ 3x longer than those inferred for local molecular clouds, star formation rates that are constant or increasing with time such that newly formed and dustier OB associations always dominate the ionizing flux, and/or that the dust responsible for reddening the nebular emission may be associated with nonmolecular (i.e., ionized and neutral) phases of the interstellar medium. Our analysis points to a variety of investigations of the nebular attenuation curve that will be enabled with the next generation of ground- and space-based facilities

The MOSDEF Survey: the Variation of the Dust Attenuation Curve with Metallicity

We derive the UV-optical stellar dust attenuation curve of galaxies at z=1.4-2.6 as a function of gas-phase metallicity. We use a sample of 218 star-forming galaxies, excluding those with very young or heavily obscured star formation, from the MOSFIRE Deep Evolution Field (MOSDEF) survey with H$\alpha$, H$\beta$, and [NII]$\lambda 6585$ spectroscopic measurements. We constrain the shape of the attenuation curve by comparing the average flux densities of galaxies sorted into bins of dust obscuration using Balmer decrements, i.e., H$\alpha$-to-H$\beta$ luminosities. The average attenuation curve for the high-metallicity sample (12+log(O/H)>8.5, corresponding to $M_*\gtrsim10^{10.4}\,M_{\odot}$) has a shallow slope, identical to that of the Calzetti local starburst curve, and a significant UV 2175A extinction bump that is $\sim 0.5\times$ the strength of the Milky Way bump. On the other hand, the average attenuation curve of the low-metallicity sample (12+log(O/H) $\sim 8.2-8.5$) has a steeper slope similar to that of the SMC curve, only consistent with the Calzetti slope at the $3\sigma$ level. The UV bump is not detected in the low-metallicity curve, indicating the relative lack of the small dust grains causing the bump at low metallicities. Furthermore, we find that on average the nebular reddening (E(B-V)) is a factor of 2 times larger than that of the stellar continuum for galaxies with low metallicities, while the nebular and stellar reddening are similar for galaxies with higher metallicities. The latter is likely due to a high surface density of dusty clouds embedding the star forming regions but also reddening the continuum in the high-metallicity galaxies.Comment: 20 pages and 9 figures and 1 appendix, accepted for publication in Ap

The MOSDEF Survey: Significant Evolution in the Rest-Frame Optical Emission Line Equivalent Widths of Star-Forming Galaxies at z=1.4-3.8

We use extensive spectroscopy from the MOSFIRE Deep Evolution Field (MOSDEF) survey to investigate the relationships between rest-frame optical emission line equivalent widths ($W$) and a number of galaxy and ISM characteristics for a sample of $1134$ star-forming galaxies at redshifts $1.4\lesssim z\lesssim 3.8$. We examine how the equivalent widths of [OII]$\lambda\lambda 3727, 3730$, H$\beta$, [OIII]$\lambda\lambda 4960, 5008$, [OIII]$+$H$\beta$, H$\alpha$, and H$\alpha$+[NII]$\lambda\lambda 6550, 6585$, depend on stellar mass, UV slope, age, star-formation rate (SFR) and specific SFR (sSFR), ionization parameter and excitation conditions (O32 and [OIII]/H$\beta$), gas-phase metallicity, and ionizing photon production efficiency ($\xi_{\rm ion}$). The trend of increasing $W$ with decreasing stellar mass is strongest for [OIII] (and [OIII]+H$\beta$). More generally, the equivalent widths of all the lines increase with redshift at a fixed stellar mass or fixed gas-phase metallicity, suggesting that high equivalent width galaxies are common at high redshift. This redshift evolution in equivalent widths can be explained by the increase in SFR and decrease in metallicity with redshift at a fixed stellar mass. Consequently, the dependence of $W$ on sSFR is largely invariant with redshift, particularly when examined for galaxies of a given metallicity. Our results show that high equivalent width galaxies, specifically those with high $W({\rm [OIII]})$, have low stellar masses, blue UV slopes, young ages, high sSFRs, ISM line ratios indicative of high ionization parameters, high $\xi_{\rm ion}$, and low metallicities. As these characteristics are often attributed to galaxies with high ionizing escape fractions, galaxies with high $W$ are likely candidates for the population that dominates cosmic reionization.Comment: 34 pages, 8 tables, 28 figures; submitted 2018 August 23, accepted 2018 October 29 to the Astrophysical Journa