2,235 research outputs found
Density-functional studies of tungsten trioxide, tungsten bronzes, and related systems
Tungsten trioxide adopts a variety of structures which can be intercalated
with charged species to alter the electronic properties, thus forming `tungsten
bronzes'. Similar optical effects are observed upon removing oxygen from WO_3,
although the electronic properties are slightly different. Here we present a
computational study of cubic and hexagonal alkali bronzes and examine the
effects on cell size and band structure as the size of the intercalated ion is
increased. With the exception of hydrogen (which is predicted to be unstable as
an intercalate), the behaviour of the bronzes are relatively consistent. NaWO_3
is the most stable of the cubic systems, although in the hexagonal system the
larger ions are more stable. The band structures are identical, with the
intercalated atom donating its single electron to the tungsten 5d valence band.
Next, this was extended to a study of fractional doping in the Na_xWO_3 system
(0 < x < 1). A linear variation in cell parameter, and a systematic change in
the position of the Fermi level up into the valence band was observed with
increasing x. In the underdoped WO_3-x system however, the Fermi level
undergoes a sudden jump into the conduction band at around x = 0.2. Lastly,
three compounds of a layered WO_4×a,wdiaminoalkane hybrid series were
studied and found to be insulating, with features in the band structure similar
to those of the parent WO_3 compound which relate well to experimental
UV-visible spectroscopy results.Comment: 12 pages, 16 figure
PMS67 FREQUENCY OF SELECT ANTI-TNF ADMINISTRATION OR RE-FILL IN PATIENTS WITH RHEUMATOID ARTHRITIS
Out-of-plane behavior of one-way spanning unreinforced masonry walls
An analytical model is developed to describe the out-of-plane response of one-way spanning unreinforced masonry (URM) walls by investigating the effects of various parameters. Horizontal crack height, masonry compressive strength, and diaphragm support stiffness properties are assumed as variables, and sensitivity analyses are performed to study the influence of these parameters on the cracked wall characteristic behavior. The parametric studies show that crack height significantly influences wall stability by affecting both the instability displacement and the wall lateral resistance. The reduction in cracked wall lateral resistance and in the instability displacement caused by finite masonry compressive strength is shown to be significantly amplified by the applied overburden. A study using the typical configuration of flexible diaphragms and URM walls indicates that the wall top support flexibility does not significantly influence cracked wall out-of-plane response. An existing simplified wall behavioral model is improved, and a procedure is proposed for calculation of the wall out-of-plane response envelope.Hossein Derakhshan; Michael C. Griffith; and Jason M. Ingha
The Mersey Estuary : sediment geochemistry
This report describes a study of the geochemistry of
the Mersey estuary carried out between April 2000 and
December 2002. The study was the first in a new programme
of surveys of the geochemistry of major British estuaries
aimed at enhancing our knowledge and understanding of the
distribution of contaminants in estuarine sediments.
The report first summarises the physical setting, historical
development, geology, hydrography and bathymetry of the
Mersey estuary and its catchment. Details of the sampling
and analytical programmes are then given followed by a
discussion of the sedimentology and geochemistry. The
chemistry of the water column and suspended particulate
matter have not been studied, the chief concern being with
the geochemistry of the surface and near-surface sediments
of the Mersey estuary and an examination of their likely
sources and present state of contamination
'Selling it as a holistic health provision and not just about condoms ?' Sexual health services in school settings: current models and their relationship with sex and relationships education policy and provision
In this article we discuss the findings from a recent study of UK policy and practice in relation to sexual health services for young people, based in - or closely linked with - schools. This study formed part of a larger project, completed in 2009, which also included a systematic review of international research. The findings discussed in this paper are based on analyses of interviews with 51 service managers and questionnaire returns from 205 school nurses. Four themes are discussed. First, we found three main service permutations, in a context of very diverse and uneven implementation. Second, we identified factors within the school context that shaped and often constrained service provision; some of these also have implications for sex and relationships education (SRE). Third, we found contrasting approaches to the relationship between SRE input and sexual health provision. Fourth, we identified some specific barriers that need to be addressed in order to develop 'young people friendly' services in the school context. The relative autonomy available to school head teachers and governors can represent an obstacle to service provision - and inter-professional collaboration - in a climate where, in many schools, there is still considerable ambivalence about discussing 'sex' openly. In conclusion, we identify areas worthy of further research and development, in order to address some obstacles to sexual health service and SRE provision in schools
Discourses of sexual relationships in a sample of German and British young people: a Q methodological study
Young people live in an environment which sexualises young people, particularly women, along traditional gender roles. This, in parallel with a silence about positive sexuality in policy development, means that sexual double standards prevail in young peopleâs lives. The aim of this study was to explore the discourses young women and men from two European countries, Germany and England, draw on when making sense of sexual relationships, and how these are steeped in the local cultural climate and messages. The study used Q methodology and included 65 German and English young people between 16 and 19 years of age. Six accounts emerged: sex as responsible, intimate and shared experience; sex as joint fun; ideal versus reality; sex has to be responsible, consensual and shared; caring relationships offer the perfect context for fulfilling sex; and equality between partners. The importance of cultural context in the availability of specific dominant and alternative discourses is discussed with a focus on how this influences young peopleâs sense-making with regard to sexuality and sexual relationships. Future directions for research are highlighted
A systematic review of supervisory relationships in general practitioner training:a qualitative synthesis
New Measurements of the Motion of the Zodiacal Dust
Using the Wisconsin H-Alpha Mapper (WHAM), we have measured at high spectral
resolution and high signal-to-noise the profile of the scattered solar Mg I
5184 absorption line in the zodiacal light. The observations were carried out
toward 49 directions that sampled the ecliptic equator from solar elongations
of 48\dg (evening sky) to 334\dg (morning sky) plus observations near +47\dg
and +90\dg ecliptic latitude. The spectra show a clear prograde kinematic
signature that is inconsistent with dust confined to the ecliptic plane and in
circular orbits influenced only by the sun's gravity. In particular, the
broadened widths of the profiles, together with large amplitude variations in
the centroid velocity with elongation angle, indicate that a significant
population of dust is on eccentric orbits. In addition, the wide, flat-bottomed
line profile toward the ecliptic pole indicates a broad distribution of orbital
inclinations extending up to about 30\dg - 40\dg with respect to the ecliptic
plane. The absence of pronounced asymmetries in the shape of the profiles
limits the retrograde population to less than 10% of the prograde population
and also places constraints on the scattering phase function of the particles.
These results do not show the radial outflow or evening--morning velocity
amplitude asymmetry reported in some earlier investigations. The reduction of
the spectra included the discovery and removal of extremely faint, unidentified
terrestrial emission lines that contaminate and distort the underlying Mg I
profile. This atmospheric emission is too weak to have been seen in earlier,
lower signal-to-noise observations, but it probably affected the line centroid
measurements of previous investigations.Comment: 24 pages, 8 figures, 1 table, to appear in ApJ v612; figures appear
low-res only on scree
A "superstorm": When moral panic and new risk discourses converge in the media
This is an Author's Accepted Manuscript of an article published in Health, Risk and Society, 15(6), 681-698, 2013, copyright Taylor & Francis, available online at: http://www.tandfonline.com/10.1080/13698575.2013.851180.There has been a proliferation of risk discourses in recent decades but studies of these have been polarised, drawing either on moral panic or new risk frameworks to analyse journalistic discourses. This article opens the theoretical possibility that the two may co-exist and converge in the same scare. I do this by bringing together more recent developments in moral panic thesis, with new risk theory and the concept of media logic. I then apply this theoretical approach to an empirical analysis of how and with what consequences moral panic and new risk type discourses converged in the editorials of four newspaper campaigns against GM food policy in Britain in the late 1990s. The article analyses 112 editorials published between January 1998 and December 2000, supplemented with news stories where these were needed for contextual clarity. This analysis shows that not only did this novel food generate intense media and public reactions; these developed in the absence of the type of concrete details journalists usually look for in risk stories. Media logic is important in understanding how journalists were able to engage and hence how a major scare could be constructed around convergent moral panic and new risk type discourses. The result was a media âsuperstormâ of sustained coverage in which both types of discourse converged in highly emotive mutually reinforcing ways that resonated in a highly sensitised context. The consequence was acute anxiety, social volatility and the potential for the disruption of policy and social change
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