Studies of compositional variations in the thermosphere and ionosphere using far-ultraviolet images from DE-1

Thesis (Ph.D.) University of Alaska Fairbanks, 1998The Dynamics Explorer mission returned a wealth of information from its two orbiting platforms. Of interest here are the three scanning photometers aboard the high-altitude platform DE-1, which obtained hundreds of thousands of global images of Earth, beginning in September of 1981, while using broad- and narrow-band filters to isolate particular terrestrial emissions. The far-ultraviolet (FUV) emissions include the line emissions of OI (130.4 and 135.6 nm) and the band emissions of \rm N\sb2 LBH, the brightness of each yielding information on the composition of the upper atmosphere. The OI emissions are related to the column density of atomic oxygen in the upper-atmosphere as well as the abundance of thermospheric \rm N\sb2, both of which are affected by geomagnetic processes. This thesis presents a model of the DE-1 response to the OI emissions during periods of low geomagnetic activity and uses this model for studies of thermospheric response to geomagnetic storms and substorms. Variations in brightness observed after geomagnetic events are most often seen as decreases corresponding to reduced thermospheric O column densities. The relation between compositional variations in the morning sector at middle latitudes and the orientation of the magnetic field embedded in the solar wind is investigated. The orientation, which strongly affects the circulation of the thermosphere at high latitudes where these variations originate, is shown to be a significant parameter. Variations in brightness within the southern polar cap are investigated in the first study of its kind, demonstrating 20-30% decreases in brightness with the onset of magnetic activity and revealing structure in composition over distances on the order of ${\sim}300$ km. Compositional disturbances are observed immediately after heating takes place, demonstrating for the first time that an FUV instrument can detect changes in thermospheric composition on time scales under one hour. During these events, mid-latitude composition often remains relatively unperturbed. The first survey of FUV images to include ground-based measurements of ionospheric properties demonstrates that decreases in OI brightness correspond to decreases in peak F2 electron densities, known to be related to the ratio of the densities of O and $\rm N\sb2.

Population genetic data for 17 Y STR markers from Benghazi (East Libya)

The seventeen Y-STR loci included in the AmpF‘STR1 YfilerTM PCR Amplification kit (DYS19, DYS389I,DYS389II, DYS390, DYS391, DYS392, DYS393, DYS385a/b, DYS438, DYS439, DYS437, DYS448, DYS458,DYS456, DYS635, and Y-GATA-H4) were used to type a sample population of 238 males from eastern Libya (Benghazi region). Of 238 observed haplotypes, 214 were unique (90%) and 24 (10%) were found more than once. The 17 loci gave a discriminating power of 0.999. DYS458 showed the highest diversity as a single-locus marker (0.73). Allelic frequencies and gene diversities for each Y-STR locus were determined. The high haplotype diversity and discrimination capacity (0.996) demonstrate the utility of these loci for human identification in forensic applications. Comparative analysis with Y-STR datasets of relevant populations and submission of the haplotypes to the Y-STR Haplotype Reference Database (YHRD) was undertaken

Ionosphere-thermosphere coupling via global-scale waves: new insights from two-years of concurrent in situ and remotely-sensed satellite observations

Growing evidence indicates that a selected group of global-scale waves from the lower atmosphere constitute a significant source of ionosphere-thermosphere (IT, 100–600 km) variability. Due to the geometry of the magnetic field lines, this IT coupling occurs mainly at low latitudes (< 30°) and is driven by waves originating in the tropical troposphere such as the diurnal eastward propagating tide with zonal wave number s = −3 (DE3) and the quasi-3-day ultra-fast Kelvin wave with s = −1 (UFKW1). In this work, over 2 years of simultaneous in situ ion densities from Ion Velocity Meters (IVMs) onboard the Ionospheric Connection Explorer (ICON) near 590 km and the Scintillation Observations and Response of the Ionosphere to Electrodynamics (SORTIE) CubeSat near 420 km, along with remotely-sensed lower (ca. 105 km) and middle (ca. 220 km) thermospheric horizontal winds from ICON’s Michelson Interferometer for Global High-resolution Thermospheric Imaging (MIGHTI) are employed to demonstrate a rich spectrum of waves coupling these IT regions. Strong DE3 and UFKW1 topside ionospheric variations are traced to lower thermospheric zonal winds, while large diurnal s = 2 (DW2) and zonally symmetric (D0) variations are traced to middle thermospheric winds generated in situ. Analyses of diurnal tides from the Climatological Tidal Model of the Thermosphere (CTMT) reveal general agreement near 105 km, with larger discrepancies near 220 km due to in situ tidal generation not captured by CTMT. This study highlights the utility of simultaneous satellite measurements for studies of IT coupling via global-scale waves

Mechanically triggered on-demand degradation of polymers synthesized by radical polymerizations

Polymers that degrade on demand have the potential to facilitate chemical recycling, reduce environmental pollution and are useful in implant immolation, drug delivery or as adhesives that debond on demand. However, polymers made by radical polymerization, which feature all carbon-bond backbones and constitute the most important class of polymers, have proven difficult to render degradable. Here we report cyclobutene-based monomers that can be co-polymerized with conventional monomers and impart the resulting polymers with mechanically triggered degradability. The cyclobutene residues act as mechanophores and can undergo a mechanically triggered ring-opening reaction, which causes a rearrangement that renders the polymer chains cleavable by hydrolysis under basic conditions. These cyclobutene-based monomers are broadly applicable in free radical and controlled radical polymerizations, introduce functional groups into the backbone of polymers and allow the mechanically gated degradation of high-molecular-weight materials or cross-linked polymer networks into low-molecular-weight species. (Figure presented.

Quasi‐2‐Day Wave in Low‐Latitude Atmospheric Winds as Viewed From the Ground and Space During January–March, 2020

Horizontal winds from four low-latitude (±15°) specular meteor radars (SMRs) and the Michelson Interferometer for Global High-resolution Thermospheric Imaging (MIGHTI) instrument on the ICON satellite, are combined to investigate quasi-2-day waves (Q2DWs) in early 2020. SMRs cover 80–100 km altitude whereas MIGHTI covers 95–300 km. Q2DWs are the largest dynamical feature of the summertime middle atmosphere. At the overlapping altitudes, comparisons between the derived Q2DWs exhibit excellent agreement. The SMR sensor array analyses show that the dominant zonal wavenumbers are s = +2 and + 3, and help resolve ambiguities in MIGHTI results. We present the first Q2DW depiction for s = +2 and s = +3 between 95 and 200 km, and show that their amplitudes are almost invariant between 80 and 100 km. Above 106 km, Q2DW amplitudes and phases present structures that might result from the superposition of Q2DWs and their aliased secondary waves

Daily Variability in the Terrestrial UV Airglow

New capability for observing conditions in the upper atmosphere comes with the implementation of global ultraviolet (UV) imaging from geosynchronous orbit. Observed by the NASA GOLD mission, the emissions of atomic oxygen (OI) and molecular nitrogen (N2) in the 133&ndash;168-nm range can be used to characterize the behavior of these major constituents of the thermosphere. Observations in the ultraviolet from the first 200 days of 2019 indicate that the oxygen emission at 135.6 nm varies much differently than the broader Lyman-Birge-Hopfield (LBH) emission of N2. This is determined from monitoring the average instrument response from two roughly 1000 km2 areas, well separated from one another, at the same time of each day. Variations in the GOLD response to UV emissions in the monitored regions are determined, both in absolute terms and relative to a running 7-day average of GOLD measurements. We find that variations in N2 emissions in the two separate regions are significantly correlated, while oxygen emissions, observed in the same fixed geographic regions at the same universal time each day, exhibit a much lower correlation, and exhibit no correlation with the N2 emissions in the same regions. This indicates that oxygen densities in the airglow-originating altitude range of 150&ndash;200 km vary independently from the variations in nitrogen, which are so well correlated across the dayside to suggest a direct connection to variation in solar extreme-UV flux. The relation of the atomic oxygen variations to solar and geomagnetic activity is also shown to be low, suggesting the existence of a regional source that modifies the production of atomic oxygen in the thermosphere.</p