Simultaneously optimizing the interdependent thermoelectric parameters in Ce(Ni1−x_{1-x}Cux_x)2_2Al3_3

Substitution of Cu for Ni in the Kondo lattice system CeNi$_2$Al$_3$ results in a simultaneous optimization of the three interdependent thermoelectric parameters: thermoelectric power, electrical and thermal conductivities, where the electronic change in conduction band induced by the extra electron of Cu is shown to be crucial. The obtained thermoelectric figure of merit $zT$ amounts to 0.125 at around 100 K, comparable to the best values known for Kondo compounds. The realization of ideal thermoelectric optimization in Ce(Ni$_{1-x}$Cu$_x$)$_2$Al$_3$ indicates that proper electronic tuning of Kondo compounds is a promising approach to efficient thermoelectric materials for cryogenic application.Comment: 4 pages, 4 figures. Accepted for publication in Physical Review

Pionic Atom Spectroscopy in the (d,3He) reaction at finite angles

We study the formation of deeply bound pionic atoms in the (d,3He) reactions theoretically and show the energy spectra of the emitted 3He at finite angles, which are expected to be observed experimentally. We find that the different combinations of the pion-bound and neutron-hole states dominate the spectra at different scattering angles because of the matching condition of the reaction. We conclude that the observation of the (d,3He) reaction at finite angles will provide the systematic information of the pionic bound states in each nucleus and will help to develop the study of the pion properties and the partial restoration of chiral symmetry in nuclei.Comment: 7 pages, 4 figures, 1 tabl

Kummiluokkatoiminnan arviointi

Tämän opinnäytetyön tarkoituksena oli kuvata ja arvioida kummiluokkatoimintaa ja sen vaikutuksia sairaanhoitajaopiskelijan/terveydenhoitajaopiskelijan opintoihin sekä työelämään pääsemiseen ja sopeutumiseen. Tämä opinnäytetyö toteutettiin empiirisenä tutkimuksena. Kummiluokkatoimintaa arvioitiin kyselyn avulla. Kysely tehtiin sähköisenä Webropol-kyselynä. Kysely lähetettiin sähköpostitse 55 hoitoalan opiskelijalle, jotka olivat olleet mukana kummiluokkatoiminnassa. Kyselyyn vastasi yhdeksän opiskelijaa, vastausprosentti oli 16,36 %. Kysely sisälsi sekä avoimia kysymyksiä että monivalintakysymyksiä. Vastausten analysointiin käytettiin sisällönanalyysiä sekä tilastointia. Kyselyn tulokseksi saatiin, että opiskelijat eivät pääosin olleet tyytyväisiä kummiluokkatoimintaan sellaisena kuin se oli toteutunut. Kummiluokkatapaamisia oli ollut liian vähän, eikä niillä ollut vaikutusta työn saantiin. Kuitenkin se toiminta, mitä opiskelijoille oli tarjottu, oli mieleistä. Muutaman opiskelijan mielestä toiminta oli lisännyt halua työskennellä Varsinais-Suomen sairaanhoitopiirissä ja yhden mielestä se oli tehnyt työnhausta helpompaa. Myös vierailukäynnit ja esitykset olivat olleet kiinnostavia, niitä olisi vain pitänyt olla enemmän. Tämän opinnäytetyön tuomaa tietoa voidaan käyttää kummiluokkatoiminnan kehittämiseen, jotta hoitoalan opiskelijat saadaan yhä enemmän sitoutumaan ja kiinnostumaan tulevasta ammatistaan. Saadut tulokset antavat myös lisää syitä kummiluokkatoiminnan jatkamiselle. Jatkotutkimuksina voisi selvittää, miten kummiluokkatoiminta vaikuttaa Turun Yliopistolliseen sairaalaan ja VSSHP:in, eli hyötyykö toiminnasta opiskelijoiden lisäksi myös organisaatio.The purpose of this study was to describe and evaluate the godparent activities and its effects on nursing studies, as well as to work to reach and adjust. This thesis has been implemented by empirical research. Godparent activity was assessed using an inquiry. The inquiry was conducted by Webropol survey. The inquiry was sent by e-mail of 55 nursing students, who had been involved in godparent activities. Nine students responded to the inquiry, the response rate was 16.36%. The inquiry contained both open questions and multiple choice questions. Content analysis and statistics were used for the analysis of the responses. The inquiry led to the result that students are not generally been satisfied with the godparent activities as it had been. Godparent meetings were only few, nor did they have the effect of employment. However, it is low, what activities were offered to students was worthwhile. A few view, the activities had added desire to work in Hospital District of Southwest Finland, and one thought it was done work search easier. Also, visits and information lectures were interesting; they would only have been more. This thesis can be used to develop the godparent activities, to get nursing students to increasingly commit to and interested in their future profession. The information obtained will also provide more reasons to continuation of godparent activities. Possible further studies could figure out how godparent activities affect the Turku University Hospital and in Hospital District of Southwest Finland, to benefit for the students, but also the organization

Multiplet ligand-field theory using Wannier orbitals

We demonstrate how ab initio cluster calculations including the full Coulomb vertex can be done in the basis of the localized, generalized Wannier orbitals which describe the low-energy density functional (LDA) band structure of the infinite crystal, e.g. the transition metal 3d and oxygen 2p orbitals. The spatial extend of our 3d Wannier orbitals (orthonormalized Nth order muffin-tin orbitals) is close to that found for atomic Hartree-Fock orbitals. We define Ligand orbitals as those linear combinations of the O 2p Wannier orbitals which couple to the 3d orbitals for the chosen cluster. The use of ligand orbitals allows for a minimal Hilbert space in multiplet ligand-field theory calculations, thus reducing the computational costs substantially. The result is a fast and simple ab initio theory, which can provide useful information about local properties of correlated insulators. We compare results for NiO, MnO and SrTiO3 with x-ray absorption, inelastic x-ray scattering, and photoemission experiments. The multiplet ligand field theory parameters found by our ab initio method agree within ~10% to known experimental values

MesonNet 2013 International Workshop. Mini-proceedings

The mini-proceedings of the MesonNet 2013 International Workshop held in Prague from June 17th to 19th, 2013, are presented. MesonNet is a research network within EU HadronPhysics3 project (1/2012 -- 12/2014). The web page of the conference, which contains all talks, can be found at http://ipnp.mff.cuni.cz/mesonnet13Comment: 106 pages, 53 contributions. Mini-proceedings of the MesonNet 2013 International Workshop. Editors: K. Kampf, A. Kupsc, and P. Masjua