A Rapid Method of Crude Oil Analysis Using FT-IR Spectroscopy

This study determines the viability of the use of Fourier Transform Infrared (FTIR) spectroscopy as a substitute to traditional petroleum geochemical methods for crude oil characterisation. IR spectra of Crude oil sample containing a mixture of both degraded (sample 151) and non-degraded (sample 145) oils at different concentrations were determined. The IR fingerprints agree with results obtained from GC analysis. Partial least square regression analysis was used to predict saturates for omitted mixtures (10 and 80% 151) and also saturates of five other samples (i.e. 145, 149, 172, H1 and AL10) within acceptable error limits. It therefore, follows, that although some improvements might still need to be made, FTIR spectroscopy can indeed be a viable, simple, cheaper and faster technique of crude oil characterisation compared with the traditional fractionation methods.Keywords: FTIR-ATR spectroscopy; GC-MS; Partial least squares (PLSR). Rapid analysis

Antioxidant and Antipyretic Activities of Adansonia Digitata (African Baobab) Fruit, Leaf And Bark Extracts

The   study   was   conducted   to   evaluate the   antioxidant   and antipyretic activity of Adansonia digitata (African Baobab) fruit, leaf and bark extracts.  Antioxidant activity of plant part extracts were determined by free radical   Diphenylpicrylhydrazyl (DPPH) assay   while   the   antipyretic activity was assessed using experimental animals. Antioxidant activity of leaf extract showed a value of 13.40±0.77, bark extract 29.23±1.69 while fruit extract gave a value of 39.21±2.26. For the Antipyretic activity results, the average temperature of Albino Wister rats was   21.65±0.96 oC   before   fever   inducement   and 30.64±1.37 oC   after inducement. Following the administration of the leaf extract (400 mg/kg and 800 mg/kg), bark   extract (400 mg/kg   and   800 mg/kg) and   fruit   extract (400 mg/kg and 800 mg/kg), the body temperature of the albino rats fell to25.96±1.16 oC vs.   25.28±1.13 oC, 26.06±1.17 oC vs. 25.02±1.12 oC, and 25.78±1.15 oC vs. 24.30±1.09 oC respectively. The   results   showed   that   the   fruit   extract   has   a   higher antioxidant and antipyretic activity than bark and leaf extracts

Structure and conduct of risk returns-characteristics of residential property investment in Kaduna metropolis, Nigeria

Residential property investment is one of the most subscribed investments in the world. However, its risk-return characteristics is least understood especially in the Nigeria context. Though past studies have critically established the performance of mostly isolated  residential and commercial properties in southern regions of Nigeria. Disentangling and identifying empirically risk-return characteristic of residential property in Kaduna metropolis Northwest Nigeria is an unresolved challenge. This paper presents an empirical analysis of the performance of residential properties to gain a better understanding of the property market dynamics in Nigeria, survey research approach was employed to collect quantitative data required for the study. To determine residential property returns and asset risk, descriptive (weighted means, standard deviation and percentages) and inferential statistics were utilised. The outcome demonstrated that residential properties have diverse total returns and riskreturn characteristic. Furthermore, this study  established that total returns from residential properties ranged between 7.93% to 12.68 % and the risk features ranged from 2.37% to6.81% among the classes of properties. The result demonstrates a direct positive relationship between total returns and risk profile. Hence, recommends that Malali market is the most desirable location for risk-averse investors. Keywords: Risk- return analysis, residential investment, total return, portfolio, propert

Proximate composition and the mineral contents of soya beans (Glycine max) available in Kano State, Nigeria

Soya bean is an important source of high-quality protein and oil, as well as other nutritious substances. The higher the content of these nutritious substances in a given soya bean, the higher it’s quality. The mineral and proximate contents of the variety of soya beans available in Kano state, Nigeria, were determined using standard procedures. The percentage (%) proximate composition was found to be Moisture 8.13%, Crude Protein 39.24%, Crude Fibre 6.84%, Crude Lipid 30.31%, Ash 4.61%, and Carbohydrate 5.08%. While the average mineral contents (%) were found to be 0.003 (Na), 0.216 (K), 0.281 (Mg), 0.324 (Ca), 0.722 (P), 0.003 (Zn), 0.002 (Cu), 0.291 (Mn) and 0.018 (Fe). The result is an indication of the nutritional importance of soya beans, and thus its production and quality require to be improved.Keywords: Mineral content, Nutritional value, Proximate composition, Soya bean

Nigella sativa oil attenuates aluminum-induced behavioral changes, oxidative stress and cortico-hippocampal neuronal degeneration in rats

Background: Aluminum (AlCl3) usage in both the industrial and domestic arena has dramatically risen over time owing to its ubiquity and utility for many activities despite frequent reporting of its neurotoxic effects over wide range of concentrations. The neuro-protective effects of Nigella sativa Oil (NSO) following intermediate exposure to aluminum salts has largely been unexplored. The present study explores the ameliorative and neuro-protective functions of NSO on aluminum chloride (AlCl3)-induced damages in the frontal cortices and hippocampus of exposed rats. Methods: The study involved the use of thirty two adult male Wistar rats weighing 180 ± 20 g, randomly divided into four groups, in which group 1 received saline, group 2 received AlCl3 (100 mg/kg), group 3 received AlCl3 (100 mg/kg) followed by NSO (1 ml/kg) 30 min later, while group 4 received NSO (1 ml/kg) only. All administrations were done orally for 14 days. Standardized behavioural tests for anxiety and cognitive performance were carried on after the treatments prior to euthanizing (Ketamine 10 mg/kg, ip). On day 15, the rats were euthanized, and their brains excised, with the frontal cortex and hippocampus removed. Five of these samples were homogenized and centrifuged to analyze nitric oxide (NO) metabolites and total reactive oxygen species (ROS), and the other three were processed for histology (cresyl violet stain) and proliferative markers (Ki-67 immunohistochemistry). Results: Increased Transfer latency, time in dark box, escape latency and reduced rearing frequency, percentage alternation and time in platform quadrant were observed in the AlCl3 exposed rats. There was also an increased level of ROS and NO in the brain regions with marked inhibition of neuronal cell proliferation as evidenced by reduced Ki-67 protein expression in the brain of AlCl3 only rats. However, rats co-administered AlCl3 and NSO showed significantly reduced ROS and NO levels, improved anxiety-like and cognitive behaviors and increased Ki-67 expression when compared with AlCl3 only treated rats. Conclusion: AlCl3 exposure causes neuronal damage and impaired anxiety-like and memory indices which are associated with increased free radical generation and inhibited neuronal proliferation, whereas the antioxidant and neuro-protective properties of NSO were efficacious against the observed effects. Keywords: Aluminum chloride, memory impairment, neuronal damage, Ki-67, nigella sativa oi

Sero Prevalence of Brucellosis in Goat in Sokoto, Nigeria

Abstract: Serum samples were collected from goats slaughtered at the Sokoto metropolis abattoir and were screened using Rose Bengal Plate Test (RBPT), the Serum Agglutination Test (SAT) and the Competitive Elisa (complisa) for brucellosis. A seroprevalence of 22.93% was recorded. The female had more prevalence (28.35%) than the male while the age band of 13-24 months had the highest prevalence of 22.46% Sokoto red was the breed with the highest prevalence of 34.12% while the hot season had the highest prevalence of 28.57%. Due to the zoonotic implications of the disease, there is the urgent need to consider the vaccination of small ruminants against brucellosis in addition to other recommendations suggested

Local Rice Production Trend Analyses and Consumption in Benue State, Nigeria: 1980 – 2016

The research examined local rice production trends and factors inhibiting the consumption of local rice from 1980 to 2016 in Benue State. Primary data were collected with the aid of questionnaire in Benue State, while secondary data were obtained from Benue Agricultural and Rural Development Authority (BNARDA) in 2017. Multistage random sampling method was employed in selecting respondents. Primary data were collected from one hundred and fifty six (156) respondents. Descriptive statistics, Z – test, Growth model and Kendal’s coefficient of concordance were used for the analysis. The results revealed that from 1980 to 2016, a total of 9.5mt of local rice was produced in Benue State. The result also shows that the respondents were all married (99%), with household size of 1 - 10 persons (95%) and mean household size of about 8 persons. The result further indicated that majority of respondents’ attained tertiary school level. The result also shows that the respondents had low income (40.3%).  The mean quantity of local rice production was 257,333.06mt per year. The instantaneous growth trends of local rice production and price were 0.00122 and 0.01103, and compound growth rate as 3.72 and 3.76 respectively. The result also indicated that many of the respondents were above the age of 41 years (49%) with the mean age of 47 and all respondents male. The presence of stones, poor aroma, impure rice and broken grain were some of the factors inhibiting consumption of local rice in Benue State. The study recommended that the policies that focus on increasing growth rate of local rice in Benue State should be intensified. Breeders and Scientists should make effort in breeding rice with aroma. The processors of local rice should use modern processing mills like rice polisher and des-stoners to mill quality local rice that will be acceptable to consumers

Environmental risk perceptions of residential and commercial neighborhoods of petrol stations in Maiduguri Metropolis, Nigeria

Environment for decades has been subjected to varied degree of degradations majorly by anthropogenic activities at the detriment of its full potentials. In light of this, the paper evaluates environmental risk perceptions of residential and commercial outfits in the neighborhoods of petrol stations in Maiduguri metropolis. Data were collected quantitatively and qualitatively with the aid of questionnaires, interview schedules and literatures. Seventy (70) residential houses and 28 commercial shops within 100m radius proximity to 14 petrol stations were targeted at random; given 5 houses and 2 shops around each sampled station picked along 7 routes. From each sample, 1 respondent was picked purposively and issued questionnaire or administered interview. The results as revealed, 73.5% respondents complained of persistent inhalation of fuel-polluted air at their location due to their close proximities to the facilities. Whilst 67.5% claimed they do not derive benefits directly from the neighbourhood facilities. However, 81.9% respondents were compelled to live with the risk and hazard challenges perceived to be associated with the neighbourhood facilities, since they lack effective voice that could help to make a change. Given this, location and activities of petrol stations within human settlements are playing significant role in adding pollutants into the environment. Consequently, it seems obvious that in most of urban Nigeria, location of many obnoxious facilities like petrol stations have compromised stipulated guidelines; thereby heightening challenges confronting the weak. As such their presences are evidently chaotic and this is likely to continue without regards to basic environmental best practices

Relationship between obesity, ethnicity and risk of late stillbirth: a case control study

<p>Abstract</p> <p>Background</p> <p>In high income countries there has been little improvement in stillbirth rates over the past two decades. Previous studies have indicated an ethnic disparity in the rate of stillbirths. This study aimed to determine whether maternal ethnicity is independently associated with late stillbirth in New Zealand.</p> <p>Methods</p> <p>Cases were women with a singleton, late stillbirth (≥28 weeks' gestation) without congenital abnormality, born between July 2006 and June 2009 in Auckland, New Zealand. Two controls with ongoing pregnancies were randomly selected at the same gestation at which the stillbirth occurred. Women were interviewed in the first few weeks following stillbirth, or at the equivalent gestation for controls. Detailed demographic data were recorded. The study was powered to detect an odds ratio of 2, with a power of 80% at the 5% level of significance, given a prevalence of the risk factor of 20%. A multivariable regression model was developed which adjusted for known risk factors for stillbirth, as well as significant risk factors identified in the current study, and adjusted odds ratios and 95% confidence intervals were calculated.</p> <p>Results</p> <p>155/215 (72%) cases and 310/429 (72%) controls consented. Pacific ethnicity, overweight and obesity, grandmultiparity, not being married, not being in paid work, social deprivation, exposure to tobacco smoke and use of recreational drugs were associated with an increased risk of late stillbirth in univariable analysis. Maternal overweight and obesity, nulliparity, grandmultiparity, not being married and not being in paid work were independently associated with late stillbirth in multivariable analysis, whereas Pacific ethnicity was no longer significant (adjusted Odds Ratio 0.99; 0.51-1.91).</p> <p>Conclusions</p> <p>Pacific ethnicity was not found to be an independent risk factor for late stillbirth in this New Zealand study. The disparity in stillbirth rates between Pacific and European women can be attributed to confounding factors such as maternal obesity and high parity.</p