266 research outputs found

    Comparison of topologies on *-algebras of locally measurable operators

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    We consider the locally measure topology t(M)t(\mathcal{M}) on the *-algebra LS(M)LS(\mathcal{M}) of all locally measurable operators affiliated with a von Neumann algebra M\mathcal{M}. We prove that t(M)t(\mathcal{M}) coincides with the (o)(o)-topology on LSh(M)={TLS(M):T=T}LS_h(\mathcal{M})=\{T\in LS(\mathcal{M}): T^*=T\} if and only if the algebra M\mathcal{M} is σ\sigma-finite and a finite algebra. We study relationships between the topology t(M)t(\mathcal{M}) and various topologies generated by faithful normal semifinite traces on M\mathcal{M}.Comment: 21 page

    Global exponential convergence to variational traveling waves in cylinders

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    We prove, under generic assumptions, that the special variational traveling wave that minimizes the exponentially weighted Ginzburg-Landau functional associated with scalar reaction-diffusion equations in infinite cylinders is the long-time attractor for the solutions of the initial value problems with front-like initial data. The convergence to this traveling wave is exponentially fast. The obtained result is mainly a consequence of the gradient flow structure of the considered equation in the exponentially weighted spaces and does not depend on the precise details of the problem. It strengthens our earlier generic propagation and selection result for "pushed" fronts.Comment: 23 page

    Nonlinear electro-hydrodynamics of liquid crystals

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    We present nonlinear dynamic equations for nematic and smectic AA liquid crystals in the presence of an alternating electric field and explain their derivation in detail. The local electric field acting in any liquid-crystalline system is expressed as a sum of external electric field and the fields originating from feedback of liquid crystal order parameter, and a field, created by charged impurities. The system tends to decrease the total electric field, because it lowers the energy density. This basically nonlinear problem is not a pure academic interest. In the realm of liquid crystals and their applications, utilized nowadays modern experimental techniques have progressed to the point where even small deviations from the linear behavior can be observed and measured with a high accuracy. Hydrodynamics is the macroscopic description of condensed matter systems in the low frequency, long wavelength limit. Nonlinear hydrodynamic equations are well established to describe simple fluids. Similar approaches (with degrees of freedom related to the broken orientational or translational symmetry included) have been used also for liquid crystals. However to study behavior of strongly perturbed well above the thresholds of various electro-hydrodynamic instabilities of liquid crystals the nonlinear equations should include soft electromagnetic degrees of freedom as well. The self-consistent derivation of the complete set of the nonlinear electro-hydrodynamic equations for liquid crystals became an actual task. The aim of our work is to present these equations, which is a mandatory step to handle any nonlinear phenomenon in liquid crystals.Comment: 12 pages, no figure

    The effects of liquid-phase oxidation of multiwall carbon nanotubes on their surface characteristics

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    The development of new sorbents based on nanostructured carbon materials recently became a perspective field of research. Main topic of current study is to investigate the effect of different regimes of multiwall carbon nanotubes (MWCNT) surface modification process on their structural characteristics. MWCNT samples were treated with nitric acid at high temperature. Structural properties were studied using low temperature nitrogen adsorption and acid-base back titration methods. The study showed that diluted nitric acid does not affect MWCNT structure. Concentrated nitric acid treatment leads to formation of 2.8 carboxylic groups per 1 nm{2} of the sample surface

    Synthesis and characterisation of nanocrystalline ZrN PVD coatings on AISI 430 stainless steel

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    The nanocrystalline films of zirconium nitride have been synthesized using ion-plasma vacuum-arc deposition technique in combination with high-frequency discharge (RF) on AISI 430 stainless steel at 150oC. Structure examinations X-ray fluorescent analysis (XRF), X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) with microanalysis (EDS), and transmission electron microscopy (TEM), nanoidentation method – were performed to study phase and chemical composition, surface morphology, microstructure and nanohardness of coatings. The developed technology provided low-temperature coatings synthesis, minimized discharge breakdown decreasing formation of macroparticles (MPs) and allowed to deposit ZrN coatings with hardness variation 26.6…31.5 GPa. It was revealed that ZrN single-phase coatings of cubic modification with finecrystalline grains of 20 nm in size were formed

    Amorphous VOx_x films with high temperature coefficient of the resistivity grown by reactive e-beam evaporation of V metal

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    Amorphous VOx_x films without a hysteretic phase transition are stable with respect to thermal cycling and highly demanded as sensitive elements of the resistive thermometers and microbolometers. In this paper we present simple and low-temperature growth of amorphous vanadium oxide films by reactive electron beam evaporation of vanadium metal in 104\sim 10^{-4} mBar oxygen atmosphere. The temperature coefficient of the resistivity (TCR) of the films is weakly sensitive to substrate material and temperature and could be tuned by oxygen pressure in the growth chamber up to -2.2\% /K. The resistivity value is stable for months. It depends on the substrate material and substrate temperature during the evaporation. Simplicity and controllability of the method should lead to various laboratory and industrial applications

    Self-similar dynamics of morphogen gradients

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    We discovered a class of self-similar solutions in nonlinear models describing the formation of morphogen gradients, the concentration fields of molecules acting as spatial regulators of cell differention in developing tissues. These models account for diffusion and self-induced degration of locally produced chemical signals. When production starts, the signal concentration is equal to zero throughout the system. We found that in the limit of infinitely large signal production strength the solution of this problem is given by the product of the steady state concentration profile and a function of the diffusion similarity variable. We derived a nonlinear boundary value problem satisfied by this function and used a variational approach to prove that this problem has a unique solution in a natural setting. Using the asymptotic behavior of the solutions established by the analysis, we constructed these solutions numerically by the shooting method. Finally, we demonstrated that the obtained solutions may be easily approximated by simple analytical expressions, thus providing an accurate global characterization of the dynamics in an important class of non-linear models of morphogen gradient formation. Our results illustrate the power of analytical approaches to studying nonlinear models of biophysical processes.Comment: 17 pages, 5 figure

    The N-ary in the Coal Mine: Avoiding Mixture Model Failure with Proper Validation

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    Modeling the properties of chemical mixtures is a difficult but important part of any modeling process intended to be applicable to the often messy and impure phenomena of everyday life, including food and environmental safety, healthcare, etc. Part of this difficulty stems from the increased complexity of designing suitable model validation schemes for mixture data, a fact which has been elucidated in previous work only in the case of binary mixture models. We extend these previously defined validation strategies for QSAR modeling of binary mixtures to the more complex case of general, NN-ary mixtures and argue that these strategies are applicable to many modeling tasks beyond simple chemical mixtures. Additionally, we propose a method of establishing a baseline model performance for each mixture dataset to be in used in model selection comparisons. This baseline is intended to account for the statistical dependence generically present between the properties of mixtures that share constituents. We contend that without such a baseline, estimates of model performance can be dramatically overestimated, and we demonstrate this with multiple case studies using real and simulated data.Comment: 22 pages, 1 figur
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