Wetland restoration and nitrate reduction: the example of the periurban wetland of Vitoria-Gasteiz (Basque Country, North Spain)

Changes in land use and agricultural intensification caused wetlands on the quaternary aquifer of Vitoria-Gasteiz (Basque Country) to disappear some years ago and nitrate concentration in groundwaters increased very quickly. The Basque Government recently declared the East Sector of this aquifer a Vulnerable Zone according to the 91/676/CEE European Directive. Recently, the wetlands have been restored through the closure of the main drainage ditches, the consequent elevation of the water table and the abondonment of agricultural practices near the wetlands. This is the case of the Zurbano wetland. Restoration has allowed the recovery of its biogeochemical function, which has reduced nitrate concentrations in waters. Nitrate concentrations which exceed 50 mg l–1 in groundwaters entering into the wetland are less than 10 mg l–1 at the outlet. Conditions in the wetland are conducive to the loss of nitrates: organic matter rich wetted soils, clay presence allowing a local semiconfined flow and very low hydraulic gradient. Water quality monitoring at several points around the wetland showed the processes involved in nitrate loss, although some aspects still remain unresolved. However, during storm events, the wetland effectively reduces the nitrate concentration entering the Alegria River, the most important river on the quaternary aquifer

A Gaia view of the optical and X-ray luminosities of compact binary millisecond pulsars

In this paper, we study compact binary millisecond pulsars with low- and very low-mass companion stars (spiders) in the Galactic field, using data from the latest Gaia data release (DR3). We infer the parallax distances of the optical counterparts to spiders, which we use to estimate optical and X-ray luminosities. We compare the parallax distances to those derived from radio pulse dispersion measures and find that they have systematically larger values, by 40% on average. We also test the correlation between X-ray and spin-down luminosities, finding that most redbacks have a spin-down to X-ray luminosity conversion efficiency of $\sim$0.1%, indicating a contribution from the intrabinary shock. On the other hand, most black widows have an efficiency of $\sim$0.01%, similar to the majority of the pulsar population. Finally, we find that the bolometric optical luminosity significantly correlates with the orbital period, with a large scatter due to different irradiated stellar temperatures and binary properties. We interpret this correlation as the effect of the increasing size of the Roche Lobe radius with the orbital period. With this newly found correlation, an estimate of the optical magnitude can be obtained from the orbital period and a distance estimate.Comment: 24 pages, 17 figures, 9 tables. This article has been accepted for publication in MNRAS published by Oxford University Press on behalf of the Royal Astronomical Societ

Isotopic constraints on the age and source of ore-forming fluids of the Bou Azzer arsenide ores (Morocco)

The authors greatly acknowledge the geological survey of CTT-Bou Azzer mine for facilitating our geological field campaigns and specially to Clemente Recio (University of Salamanca) for his invaluable help to IS during the development of the analytical procedure to mea-sure S isotope compositions from the minor amounts of S extracted from arsenides and sulfarsenides. Authors would like to acknowledge the use of Servicio General de Apoyo a la Investigacion-SAI, Universidad de Zaragoza. This research was financially supported by the Spanish project RTI2018-099157-A-I00 granted by the "Ministerio de Ciencia, Innovacion y Universidades". The Swedish Research Council (infra-structure grant: Dnr. 2017-00671) is thanked for financial support to the Vegacenter national laboratory. This is Vegacenter publication number 124The Bou Azzer district in Morocco has a long mining history since the beginning of the XXst century during which it has become the only world producer of Co from primary, hydrothermal Co arsenide ores. Orebodies are structurally controlled, and mainly distributed along fault contacts between Cryogenian ophiolite-related serpentinite bodies and intrusive quartz diorite or, locally, ophiolitic gabbros or Ediacaran volcanic rocks. Ore formation took place through a multi-stage mineralizing process that included an early stage composed by gold, quartz, chlorite, muscovite and calcite, followed by the main arsenide and sulfarsenide stage (subdivided into three substages, IIa: Ni-rich, Co ores, IIb: Co-Fe ores and IIc: Fe-Co ores), and ending with an epithermal stage characterized by the precipitation of sulfides along with quartz and calcite. Field relations and most previous geochronologic dating pointed to a post Pan-African age of ore formation, mainly coincident with the Hercynian orogeny. The isotopic study presented in this paper includes S, Pb, Rb/Sr and Sm/Nd data of a set of ore mineral samples from three deposits (Aghbar, Tamdrost and Aït Ahmane), as well as of regional samples representative of the different lithologies occurring in the Bou Azzer area. The isotope data set was completed with S isotope analyses of arsenide and sulfarsenide minerals from five ore deposits (Filon 7/5, Aghbar, Tamdrost, Ightem and Aït- Ahmane) and of some whole-rock regional samples. Results show that ores formed during multi-episodic hydrothermal events connected with hercynian reactivation of Devonian-Carboniferous faults, supporting previous geochronologic dating. The obtained Pb, Sr, Nd and S isotopic signatures of ore minerals and regional rocks further show that ophiolite-related lithologies became isotopically modified by interaction with crustal material and afterwards acted as the main source of ore-forming elements. Nevertheless, isotopic data do not fully concur with such a simple scenario but are quite consistent with a rather complex interpretation based on multi-source origin of some elements and isotopes scavenged from a number of isotopically different lithologies both from the inferred basement and the volcanic and sedimentary cover.Spanish Government RTI2018-099157-A-I00Swedish Research Council European Commission Dnr. 2017-0067

Entropy-driven phase transition in a system of long rods on a square lattice

The isotropic-nematic (I-N) phase transition in a system of long straight rigid rods of length k on square lattices is studied by combining Monte Carlo simulations and theoretical analysis. The process is analyzed by comparing the configurational entropy of the system with the corresponding to a fully aligned system, whose calculation reduces to the 1D case. The results obtained (1) allow to estimate the minimum value of k which leads to the formation of a nematic phase and provide an interesting interpretation of this critical value; (2) provide numerical evidence on the existence of a second phase transition (from a nematic to a non-nematic state) occurring at density close to 1 and (3) allow to test the predictions of the main theoretical models developed to treat the polymers adsorption problem.Comment: 14 pages, 6 figures. Accepted for publication in JSTA

Study of the one-dimensional off-lattice hot-monomer reaction model

Hot monomers are particles having a transient mobility (a ballistic flight) prior to being definitely absorbed on a surface. After arriving at a surface, the excess energy coming from the kinetic energy in the gas phase is dissipated through degrees of freedom parallel to the surface plane. In this paper we study the hot monomer-monomer adsorption-reaction process on a continuum (off-lattice) one-dimensional space by means of Monte Carlo simulations. The system exhibits second-order irreversible phase transition between a reactive and saturated (absorbing) phases which belong to the directed percolation (DP) universality class. This result is interpreted by means of a coarse-grained Langevin description which allows as to extend the DP conjecture to transitions occurring in continuous media.Comment: 13 pages, 5 figures, final version to appear in J. Phys.

Datos sobre la edad de las secciones del Mioceno Inferior de Port d'es Canonge y Randa (Mallorca)

Abstract not availabl

The impact of corporate social responsibility performance on earnings management: Family versus non-family firms

The study analyses the impact of corporate social responsibility performance on earnings management in family firms as compared with non-family firms. We analysed 650 Spanish firms, listed and unlisted, in the period 2011-2016. The result shows a higher quality of financial information in family firms, a relationship which is reinforced by good governance factors, including the participation of women in management. The factors analysed are supported by agency and institutional theories. The study contributes to reducing the gap in the literature on the quality of financial information associated with family firms vs. non family firms.info:eu-repo/semantics/acceptedVersio

The effect of corporate governance factors on the quality of financial reporting in family and non-family firms

The objective of this study is to explore the quality of financial information of Spanish firms, by comparing family firms with non-family firms, and relating this quality with corporate governance practices. For this purpose, a sample of 650 Spanish firms was analysed during the period 2011-2016. Based on agency theory and socioemotional wealth literature, the results show a higher quality of financial information in family firms, a relationship which is reinforced by corporate governance factors. Our results are consistent with the scant previous research, and with the premises of agency theory, which indicate lower asymmetry of information between owners and managers in the singular context of family firms. Additionally, our work provides evidence that the participation of women on the board boosts the quality of financial information in family firms, contributing to the justification of family firm heterogeneity in terms of earnings management. This study contributes to reducing the gap in the literature on the influence of the family business context and the influence of women on the board on the quality of financial reporting.info:eu-repo/semantics/publishedVersio

Governação das sociedades e qualidade da informação financeira em empresas familiares versus não familiares

O presente estudo analisa a qualidade da informação financeira em empresas familiares versus não familiares, relacionando medidas de transparência na governação das sociedades. Foram analisadas 650 empresas espanholas, cotadas e não cotadas, no período de 2011-2016. O resultado demonstra a maior qualidade da informação financeira em empresas familiares, relação que é reforçada pela participação de mulheres na administração, experiência da empresa e intangibilidade de ativos. Os fatores analisados estão suportados nas teorias da agência, da riqueza socio-emocional e institucional. O estudo contribui para reduzir a lacuna na literatura sobre qualidade da informação financeira associada à governação familiar versus não familiar.info:eu-repo/semantics/acceptedVersio