45 research outputs found
The heart of a convex body
We investigate some basic properties of the {\it heart}
of a convex set It is a subset of
whose definition is based on mirror reflections of euclidean
space, and is a non-local object. The main motivation of our interest for
is that this gives an estimate of the location of the
hot spot in a convex heat conductor with boundary temperature grounded at zero.
Here, we investigate on the relation between and the
mirror symmetries of we show that
contains many (geometrically and phisically) relevant points of
we prove a simple geometrical lower estimate for the diameter of
we also prove an upper estimate for the area of
when is a triangle.Comment: 15 pages, 3 figures. appears as "Geometric Properties for Parabolic
and Elliptic PDE's", Springer INdAM Series Volume 2, 2013, pp 49-6
One Pot Grafting of Tetrairon(III) Single Molecule Magnets on Silicon
Herein we report on the Si grafting of two Fe4 derivatives, [Fe4(Li)2(tmhd)6], in which tmhd is 2,2,6,6-tetramethylheptane-3,5-dionate and H3Li = R–C(CH2OH)3 is a tripodal ligand with R = CH2=CH–CH2–O–CH2 (H3L1) and CH2=CH–(CH2)9–O–CH2 (H3L2). These complexes were specifically designed to be directlyanchored on the H-terminated silicon surface via the hydrosilylation reaction. The complexes were grafted by a one pot route based on the photoinduced hydrosilylation followed by a ligand exchange step in the same reaction solution. The resulting decorated surfaces were characterized using X-ray photoelectronspectroscopy (XPS), attenuated total reflection infrared spectroscopy (ATR-IR) and atomic force microscopy (AFM)