95 research outputs found
Polarization-analyzed resonant inelastic x-ray scattering of the orbital excitations in KCuF3
We report a Cu K-edge resonant inelastic x-ray scattering (RIXS) study of
orbital excitations in KCuF3 . By performing the polarization analysis of the
scattered photons, we disclose that the excitation between the eg orbitals and
the excitations from t2g to eg exhibit distinct polarization dependence. The
polarization dependence of the respective excitations is interpreted based on a
phenomenological consideration of the symmetry of the RIXS process that yields
a necessary condition for observing the excitations. In addition, we show that
the orbital excitations are dispersionless within our experimental resolution.Comment: 5 pages, 3 figure
Resonant inelastic x-ray scattering in single-crystal superconducting PrFeAsO0.7
Resonant inelastic x-ray scattering (RIXS) spectra at the Fe K-edge were
measured for a single crystal of the iron oxypnictide superconductor PrFeAsO0.7
(Tc=42 K). They disclose a weak, broad feature centered around 4.5 eV energy
loss, which is slightly resonantly enhanced when the incident energy is tuned
in the vicinity of the 4p white line. We tentatively ascribe it to the
charge-transfer excitation between As 4p and Fe 3d.Comment: 2 pages, 2 figure
Resonant inelastic x-ray scattering in electronically quasi-zero-dimensional CuB2O4
We explore the general phenomenology of resonant inelastic scattering (RIXS)
using CuB2O4, a network of CuO4 plaquettes electronically isolated by B+3 ions.
Spectra show a small number of well-separated features, and we exploit the
simple electronic structure to explore RIXS phenomenology by developing a
calculation which allows for intermediate-state effects ignored in standard
approaches. These effects are found to be non-negligible and good
correspondence between our model and experiment leads to a simple picture of
such phenomenology as the genesis of d-d excitations at the K edge and
intermediate-state interference effects.Comment: Phys. Rev. B 80, 092509 (2009
Recommended from our members
Analysis of the EMCCD point-source response using x-rays
Electron Multiplying Charge Coupled Devices, EMCCD are used as x-ray detectors. The NSLS-II Soft Inelastic x-ray Scattering (SIX) beam line has two EMCCDs for x-ray detection in the spectrometer arm. The spectrometer with high resolving power disperses x-rays vertically. The x-ray vertical position on the sensor plane is related to its energy. This allows for very accurate x-ray energy measurements through x-ray coordinates. X-rays interact with silicon and create a number of electron–hole pairs proportional to the x-ray energy. Electrons drift and diffuse toward pixel gates and are collected there. The diffused electrons form a charge cloud distributed over several neighboring pixels. This charge sharing enables coordinate measurements with accuracy better than the pixel pitch. The charge distribution shape has to be taken into account to achieve ultimate accuracy in coordinate measurements. In this paper, we present a method of the charge distribution shape analysis and demonstrate its applications.
The drift and diffusion of electrons from the point of generation to pixel gates results in the bell-shaped electron cloud usually approximated by Gaussian shape. The number of electrons collected under a pixel is proportional to the shape function integral. These electron packets get transferred to the sense node of the output amplifier. The transfer process could introduce distortions to the original charge distribution. For example, during transfers, electrons in the packet could be exposed to traps if they are present in the sensor. The trapping and later the release processes distort the apparent shape of the charge distribution. Therefore, deviations of the charge distribution shape from the originally symmetrical form can indicate the presence of trap centers in the sensor and can be used for sensor diagnostics
Pressure-induced valence anomaly in TmTe probed by resonant inelastic x-ray scattering
The pressure-induced valence transition in TmTe was investigated by resonant inelastic x-ray scattering at the Tm L(3) edge, a powerful probe of the rare-earth valent state. The data are analyzed within the Anderson impurity model which yields key parameters such as the Tm 4f-5d hybridization. In addition to the general tendency of the f electrons towards delocalization, we find a plateau in both the Tm valence and hybridization pressure dependences between 4.3 and 6.5 GPa which is interpreted in terms of an n-channel Kondo (NCK) screening process. This behavior is at odds with the usually continuous, single-channel Kondo-like f delocalization while being supported by the seminal calculations of the NCK temperature in Tm ion by Saso et al. Our study raises the interesting possibility that an NCK effect realized in a compressed mixed-valent f system could impede the concomitant electron delocalization
Investigation of the thermal stability of Mg/Co periodic multilayers for EUV applications
We present the results of the characterization of Mg/Co periodic multilayers
and their thermal stability for the EUV range. The annealing study is performed
up to a temperature of 400\degree C. Images obtained by scanning transmission
electron microscopy and electron energy loss spectroscopy clearly show the good
quality of the multilayer structure. The measurements of the EUV reflectivity
around 25 nm (~49 eV) indicate that the reflectivity decreases when the
annealing temperature increases above 300\degreeC. X-ray emission spectroscopy
is performed to determine the chemical state of the Mg atoms within the Mg/Co
multilayer. Nuclear magnetic resonance used to determine the chemical state of
the Co atoms and scanning electron microscopy images of cross sections of the
Mg/Co multilayers reveal changes in the morphology of the stack from an
annealing temperature of 305\degreee;C. This explains the observed reflectivity
loss.Comment: Published in Applied Physics A: Materials Science \& Processing
Published at
http://www.springerlink.com.chimie.gate.inist.fr/content/6v396j6m56771r61/ 21
page
- …