Antimony-doped graphene nanoplatelets

Heteroatom doping into the graphitic frameworks have been intensively studied for the development of metal-free electrocatalysts. However, the choice of heteroatoms is limited to non-metallic elements and heteroatom-doped graphitic materials do not satisfy commercial demands in terms of cost and stability. Here we realize doping semimetal antimony (Sb) at the edges of graphene nanoplatelets (GnPs) via a simple mechanochemical reaction between pristine graphite and solid Sb. The covalent bonding of the metalloid Sb with the graphitic carbon is visualized using atomic-resolution transmission electron microscopy. The Sb-doped GnPs display zero loss of electrocatalytic activity for oxygen reduction reaction even after 100,000 cycles. Density functional theory calculations indicate that the multiple oxidation states (Sb3+ and Sb5+) of Sb are responsible for the unusual electrochemical stability. Sb-doped GnPs may provide new insights and practical methods for designing stable carbon-based electrocatalystsclose0

Production and optical properties of liquid scintillator for the JSNS2^{2} experiment

The JSNS$^{2}$ (J-PARC Sterile Neutrino Search at J-PARC Spallation Neutron Source) experiment will search for neutrino oscillations over a 24 m short baseline at J-PARC. The JSNS$^{2}$ inner detector will be filled with 17 tons of gadolinium-loaded liquid scintillator (LS) with an additional 31 tons of unloaded LS in the intermediate $\gamma$-catcher and outer veto volumes. JSNS$^{2}$ has chosen Linear Alkyl Benzene (LAB) as an organic solvent because of its chemical properties. The unloaded LS was produced at a refurbished facility, originally used for scintillator production by the RENO experiment. JSNS$^{2}$ plans to use ISO tanks for the storage and transportation of the LS. In this paper, we describe the LS production, and present measurements of its optical properties and long term stability. Our measurements show that storing the LS in ISO tanks does not result in degradation of its optical properties.Comment: 7 pages, 4 figures

Blockchain-based DDoS attack mitigation protocol for device-to-device interaction in smart homes

Smart home devices are vulnerable to a variety of attacks. The matter gets more complicated when a number of devices collaborate to launch a colluding attack (e.g. Distributed-Denial-of-Service (DDoS)) in a network (e.g., Smart home). To handle these attacks, most studies have hitherto proposed authentication protocols that cannot necessarily be implemented in devices, especially during Device-to-Device (D2D) interactions. Tapping into the potential of Ethereum blockchain and smart contracts, this work proposes a lightweight authentication mechanism that enables safe D2D interactions in a smart home. The Ethereum blockchain enables the implementation of a decentralized prototype as well as a peer-to-peer distributed ledger system. The work also uses a single server queuing system model and the authentication mechanism to curtail DDoS attacks by controlling the number of service requests in the system. The simulation was conducted twenty times, each with varying number of devices chosen at random (ranging from 1 to 30). Each requester device sends an arbitrary request with a unique resource requirement at a time. This is done to measure the system’s consistency across a variety of device capabilities. The experimental results show that the proposed protocol not only prevents colluding attacks, but also outperforms the benchmark protocols in terms of computational cost, message processing, and response time

Condensation in randomly perturbed zero-range processes

The zero-range process is a stochastic interacting particle system that exhibits a condensation transition under certain conditions on the dynamics. It has recently been found that a small perturbation of a generic class of jump rates leads to a drastic change of the phase diagram and prevents condensation in an extended parameter range. We complement this study with rigorous results on a finite critical density and quenched free energy in the thermodynamic limit, as well as quantitative heuristic results for small and large noise which are supported by detailed simulation data. While our new results support the initial findings, they also shed new light on the actual (limited) relevance in large finite systems, which we discuss via fundamental diagrams obtained from exact numerics for finite systems.Comment: 18 pages, 6 figure

Charge fluctuations and electric mass in a hot meson gas

Net-Charge fluctuations in a hadron gas are studied using an effective hadronic interaction. The emphasis of this work is to investigate the corrections of hadronic interactions to the charge fluctuations of a non-interacting resonance gas. Several methods, such as loop, density and virial expansions are employed. The calculations are also extended to SU(3) and some resummation schemes are considered. Although the various corrections are sizable individually, they cancel to a large extent. As a consequence we find that charge fluctuations are rather well described by the free resonance gas.Comment: 32 pages, 18 figure

Ramond-Ramond Cohomology and O(D,D) T-duality

In the name of supersymmetric double field theory, superstring effective actions can be reformulated into simple forms. They feature a pair of vielbeins corresponding to the same spacetime metric, and hence enjoy double local Lorentz symmetries. In a manifestly covariant manner --with regard to O(D,D) T-duality, diffeomorphism, B-field gauge symmetry and the pair of local Lorentz symmetries-- we incorporate R-R potentials into double field theory. We take them as a single object which is in a bi-fundamental spinorial representation of the double Lorentz groups. We identify cohomological structure relevant to the field strength. A priori, the R-R sector as well as all the fermions are O(D,D) singlet. Yet, gauge fixing the two vielbeins equal to each other modifies the O(D,D) transformation rule to call for a compensating local Lorentz rotation, such that the R-R potential may turn into an O(D,D) spinor and T-duality can flip the chirality exchanging type IIA and IIB supergravities.Comment: 1+37 pages, no figure; Structure reorganized, References added, To appear in JHEP. cf. Gong Show of Strings 2012 (http://wwwth.mpp.mpg.de/members/strings/strings2012/strings_files/program/Talks/Thursday/Gongshow/Lee.pdf