423 research outputs found
Dynamic Optical Grating Device and Associated Method for Modulating Light
A dynamic optical grating device and associated method for modulating light is provided that is capable of controlling the spectral properties and propagation of light without moving mechanical components by the use of a dynamic electric and/or magnetic field. By changing the electric field and/or magnetic field, the index of refraction, the extinction coefficient, the transmittivity, and the reflectivity fo the optical grating device may be controlled in order to control the spectral properties of the light reflected or transmitted by the device
Ultrasonication of Bismuth Telluride Nanocrystals Fabricated by Solvothermal Method
The objective of this study is to evaluate the effect of ultrasonication on bismuth telluride nanocrystals prepared by solvothermal method. In this study, a low dimensional nanocrystal of bismuth telluride (Bi2Te3) was synthesized by a solvothermal process in an autoclave at 180 C and 200 psi. During the solvothermal reaction, organic surfactants effectively prevented unwanted aggregation of nanocrystals in a selected solvent while controlling the shape of the nanocrystal. The atomic ratio of bismuth and tellurium was determined by energy dispersive spectroscopy (EDS). The cavitational energy created by the ultrasonic probe was varied by the ultrasonication process time, while power amplitude remained constant. The nanocrystal size and its size distribution were measured by field emission scanning electron microscopy (FESEM) and a dynamic light scattering system. When the ultrasonication time increased, the average size of bismuth telluride nanocrystal gradually increased due to the direct collision of nanocrystals. The polydispersity of the nanocrystals showed a minimum when the ultrasonication was applied for 5 min. Keywords: bismuth telluride, nanocrystal, low-dimensional, ultrasonication, solvotherma
Low-Power Upconversion in Poly(Mannitol-Sebacate) Networks with Tethered Diphenylanthracene and Palladium Porphyrin
[EN] Efforts to fabricate low-power up converting solid-state systems have rapidly increased in the past decade because of their possible application in several fields such as
bio-imaging, drug delivery, solar harvesting or displays. The synthesis of upconverting cross-linked polyester rubbers with covalently tethered chromophores is presented here.
Cross-linked films were prepared by reacting a poly(mannitol- sebacate) pre-polymer with 9,10-bis(4-hydroxymethylphenyl) anthracene (DPA-(CH2OH)2) and palladium
mesoporphyrin IX. These chromophores served as emitters and sensitizers, respectively, and through a cascade of photophysical events, resulted in an anti-Stokes shifted emission. Indeed, blue emission (*440 nm) of these solid materials was detected upon excitation at 543 nm with a green laser and the power dependence of integrated unconverted intensity versus excitation was examined. The new materials display upconversion at power densities as low as 32 mW/cm2, and do not display phase de-mixing, which has been identified as an obstacle in rubbery blends comprising untethered chromophores.The authors are thankful for the financial support of the Swiss National Science Foundation (200021_13540/1 and 200020_152968), Spanish Ministry of Economy and Competitiveness (Project MAT2010/21494-C03) and the Adolphe Merkle Foundation. The authors thank Prof. Christoph Weder for his help and support.Lee, S.; Sonseca, A.; Vadrucci, R.; Giménez Torres, E.; Foster, E.; Simon, YC. (2014). Low-Power Upconversion in Poly(Mannitol-Sebacate) Networks with Tethered Diphenylanthracene and Palladium Porphyrin. Journal of Inorganic and Organometallic Polymers. 24(5):898-903. https://doi.org/10.1007/s10904-014-0063-7S898903245C. A. Parker, C. G. Hatchard. P. Chem. Soc. London, 386–387 (1962)Y.C. Simon, C. Weder, J. Mater. Chem. 22, 20817–20830 (2012)J.Z. Zhao, S.M. Ji, H.M. Guo, Rsc Adv. 1, 937–950 (2011)C. Reinhard, R. Valiente, H.U. Gudel, J. Phys. Chem. B 106, 10051–10057 (2002)M. Haase, H. Schafer, Angew. Chem. Int. Edit. 50, 5808–5829 (2011)W.H. Wu, J.Z. Zhao, J.F. Sun, S. Guo, J. Org. Chem. 77, 5305–5312 (2012)T.T. Zhao, X.Q. Shen, L. Li, Z.P. Guan, N.Y. Gao, P.Y. Yuan, S.Q. Yao, Q.H. Xu, G.Q. Xu, Nanoscale 4, 7712–7719 (2012)C. Cepraga, T. Gallavardin, S. Marotte, P.H. Lanoe, J.C. Mulatier, F. Lerouge, S. Parola, M. Lindgren, P.L. Baldeck, J. Marvel, O. Maury, C. Monnereau, A. Favier, C. Andraud, Y. Leverrier, M.T. Charreyre, Polym. Chem. 4, 61–67 (2013)J. Qian, D. Wang, F.H. Cai, Q.Q. Zhan, Y.L. Wang, S.L. He, Biomaterials 33, 4851–4860 (2012)S. Baluschev, V. Yakutkin, T. Miteva, G. Wegner, T. Roberts, G. Nelles, A. Yasuda, S. Chernov, S. Aleshchenkov, A. Cheprakov, New J. Phys. 10, 013007 (2008)S. Baluschev, T. Miteva, V. Yakutkin, G. Nelles, A. Yasuda, G. Wegner, Phys. Rev. Lett. 97, 143903 (2006)M. Samoc, A. Samoc, B. Luther-Davies, Opt. Express 11, 1787–1792 (2003)A. Monguzzi, J. Mezyk, F. Scotognella, R. Tubino, F. Meinardi, Phys. Rev. B 78(195112), 1–5 (2008)A. Monguzzi, R. Tubino, F. Meinardi, Phys. Rev. B 77, 155122-1-4 (2008)T.N. Singh-Rachford, R.R. Islangulov, F.N. Castellano, J. Phys. Chem. A 112, 3906–3910 (2008)C. Wohnhaas, A. Turshatov, V. Mailander, S. Lorenz, S. Baluschev, T. Miteva, K. Landfester, Macromol. Biosci. 11, 772–778 (2011)R.R. Islangulov, J. Lott, C. Weder, F.N. Castellano, J. Am. Chem. Soc. 129, 12652–12653 (2007)Y.C. Simon, C. Weder, Chimia 66, 878 (2012)Y.C. Simon, S. Bai, M.K. Sing, H. Dietsch, M. Achermann, C. Weder, Macromol. Rapid Commun. 33, 498–502 (2012)S.H. Lee, J.R. Lott, Y.C. Simon, C. Weder, J. Mater. Chem. C 1, 5142–5148 (2013)S. Baluschev, P.E. Keivanidis, G. Wegner, J. Jacob, A.C. Grimsdale, K. Mullen, T. Miteva, A. Yasuda, G. Nelles, Appl. Phys. Lett. 86, 1–3 (2005)S. Baluschev, J. Jacob, Y.S. Avlasevich, P.E. Keivanidis, T. Miteva, A. Yasuda, G. Nelles, A.C. Grimsdale, K. Mullen, G. Wegner, ChemPhysChem 6, 1250–1253 (2005)P.C. Boutin, K.P. Ghiggino, T.L. Kelly, R.P. Steer, J. Phys. Chem. Lett. 4, 4113–4118 (2013)C.A. Sundback, J.Y. Shyu, Y.D. Wang, W.C. Faquin, R.S. Langer, J.P. Vacanti, T.A. Hadlock, Biomaterials 26, 5454–5464 (2005)Z.J. Sun, C. Chen, M.Z. Sun, C.H. Ai, X.L. Lu, Y.F. Zheng, B.F. Yang, D.L. Dong, Biomaterials 30, 5209–5214 (2009)A. Mahdavi, L. Ferreira, C. Sundback, J.W. Nichol, E.P. Chan, D.J.D. Carter, C.J. Bettinger, S. Patanavanich, L. Chignozha, E. Ben-Joseph, A. Galakatos, H. Pryor, I. Pomerantseva, P.T. Masiakos, W. Faquin, A. Zumbuehl, S. Hong, J. Borenstein, J. Vacanti, R. Langer, J.M. Karp, Proc. Natl. Acad. Sci. USA 105, 2307–2312 (2008)A. Sonseca, S. Camarero-Espinosa, L. Peponi, C. Weder, E.J. Foster, J.M. Kenny, E. Giménez, J. Polym. Sci. Part A. (2014). doi: 10.1002/pola.27367R. Vadrucci, C. Weder, Y.C. Simon, J. Mater. Chem. C 2, 2837–2841 (2014)F.A. Lara, U. Lins, G.H. Bechara, P.L. Oliveira, J. Exp. Biol. 208, 3093–3101 (2005)R. Maliger, P.J. Halley, J.J. Cooper-White, J. Appl. Polym. Sci. 127, 3980–3986 (2013)S. H. Lee, M. A. Ayer, R. Vadrucci, C. Weder, Y. C. Simon, Polym. Chem. (2014)T.W. Schmidt, Y.Y. Cheng, B. Fuckel, T. Khoury, R.G.C.R. Clady, M.J.Y. Tayebjee, N.J. Ekins-Daukes, M.J. Crossley, J. Phys. Chem. Lett. 1, 1795–1799 (2010)R. R. Islangulov, T. N. Singh, J. Lott, C. Weder, F. N. Castellano. Abstr. Pap. Am. Chem. Soc. 235 (2008
The First Year IceCube-DeepCore Results
The IceCube Neutrino Observatory includes a tightly spaced inner array in the
deepest ice, called DeepCore, which gives access to low-energy neutrinos with a
sizable surrounding cosmic ray muon veto. Designed to be sensitive to neutrinos
at energies as low as 10 GeV, DeepCore will be used to study diverse physics
topics with neutrino signatures, such as dark matter annihilations and
atmospheric neutrino oscillations. The first year of DeepCore physics
data-taking has been completed, and the first observation of atmospheric
neutrino-induced cascades with IceCube and DeepCore are presented.Comment: 4 pages, 3 figures, TAUP 2011 (Journal of Physics: Conference Series
(JCPS)
Is it possible to formulate least action principle for dissipative systems?
A longstanding open question in classical mechanics is to formulate the least
action principle for dissipative systems. In this work, we give a general
formulation of this principle by considering a whole conservative system
including the damped moving body and its environment receiving the dissipated
energy. This composite system has the conservative Hamiltonian
where is the kinetic energy of the moving body, its potential
energy and the energy of the environment. The Lagrangian can be derived
by using the usual Legendre transformation where is the
total kinetic energy of the environment. An equivalent expression of this
Lagrangian is where is the energy dissipated by the
friction from the moving body into the environment from the beginning of the
motion. The usual variation calculus of least action leads to the correct
equation of the damped motion. We also show that this general formulation is a
natural consequence of the virtual work principle.Comment: 11 pages, no figur
High altitude airship configuration and power technology and method for operation of same
A new High Altitude Airship (HAA) capable of various extended applications and mission scenarios utilizing inventive onboard energy harvesting and power distribution systems. The power technology comprises an advanced thermoelectric (ATE) thermal energy conversion system. The high efficiency of multiple stages of ATE materials in a tandem mode, each suited for best performance within a particular temperature range, permits the ATE system to generate a high quantity of harvested energy for the extended mission scenarios. When the figure of merit 5 is considered, the cascaded efficiency of the three-stage ATE system approaches an efficiency greater than 60 percent
Wnt5 signaling in vertebrate pancreas development
BACKGROUND: Signaling by the Wnt family of secreted glycoproteins through their receptors, the frizzled (Fz) family of seven-pass transmembrane proteins, is critical for numerous cell fate and tissue polarity decisions during development. RESULTS: We report a novel role of Wnt signaling in organogenesis using the formation of the islet during pancreatic development as a model tissue. We used the advantages of the zebrafish to visualize and document this process in living embryos and demonstrated that insulin-positive cells actively migrate to form an islet. We used morpholinos (MOs), sequence-specific translational inhibitors, and time-lapse imaging analysis to show that the Wnt-5 ligand and the Fz-2 receptor are required for proper insulin-cell migration in zebrafish. Histological analyses of islets in Wnt5a(-/- )mouse embryos showed that Wnt5a signaling is also critical for murine pancreatic insulin-cell migration. CONCLUSION: Our results implicate a conserved role of a Wnt5/Fz2 signaling pathway in islet formation during pancreatic development. This study opens the door for further investigation into a role of Wnt signaling in vertebrate organ development and disease
Re-evaluation of the optimum dietary protein level for maximum growth of juvenile barred knifejaw Oplegnathus fasciatus reared in cages
Abstract We determined the optimum dietary protein level in juvenile barred knifejaw Oplegnathus fasciatus in cages. Five semi-purified isocaloric diets were formulated with white fish meal and casein-based diets to contain 35, 40, 45, 50, and 60 % crude protein (CP). Fish with an initial body weight of 7.1 ± 0.06 g (mean ± SD) were randomly distributed into 15 net cages (each size: 60 cm × 40 cm × 90 cm, W × L × H) as groups of 20 fish in triplicates. The fish were fed at apparent satiation level twice a day. After 8 weeks of feeding, the weight gain (WG) of fish fed 45, 50, and 60 % CP diets were significantly higher than those of fish fed 35 and 40 % CP diets. However, there were no significant differences in WG among fish fed 45, 50, and 60 % CP diets. Generally, feed efficiency (FE) and specific growth rate (SGR) showed a similar trend as WG. However, the protein efficiency ratio (PER) was inversely related to dietary protein levels. Energy retention efficiency increased with the increase of dietary protein levels by protein sparing from non-protein energy sources. Blood hematocrit content was not affected by dietary protein levels. However, a significantly lower amount of hemoglobin was found in fish fed 35 % CP than in fish fed 40, 45, 50, and 60 % CP diets. Fish fed 60 % CP showed the lowest survival rate than the fish fed 35, 40, 45, and 50 % CP diets. Broken-line analysis of WG showed the optimum dietary protein level was 45.2 % with 18.8 kJ/g diet for juvenile barred knifejaw. This study has potential implication for the successful cage culture of barred knifejaw
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