Nicalon/siliconoxycarbide ceramic composites

A series of silsesquioxane copolymers was synthesized by acid hydrolysis and condensation of trimethoxysilanes of the form RSi(OCH3)3, where R = methyl or phenyl. By varying pH, water/methoxy and methyl/phenyl ratios, the molecular structure, polymer rheology and ceramic composition can be controlled. The polymers form an amorphous siliconoxycarbide on pyrolysis. Composites of Nicalon/siliconoxycarbide were fractured in four-point flexure and in tension to evaluate the influence of matrix composition, final fabrication temperature and use of filler on composite mode of failure, modulus, strain capability and strength. Incorporation of filler was found to increase matrix compressive strength. Employment of processing temperatures of 1375 to 1400 C enhanced strain to failure and reduced the tendency toward brittle fracture. Mixed mode (compression/shear and tension/shear) failures were observed in flexural samples processed to the higher temperatures, giving rise to nonlinear stress-strain curves. Tensile samples pyrolyzed to 1400 C showed linear-elastic behavior and failed by fracture of fiber bundles. Matrix material was found to be adherent to the fiber surface after failure. These results demonstrate the need for tensile testing to establish composite behavior

Polymeric routes to silicon carbide and silicon oxycarbide CMC

An overview of two approaches to the formation of ceramic composite matrices from polymeric precursors is presented. Copolymerization of alkyl- and alkenylsilanes (RSiH3) represents a new precursor system for the production of Beta-SiC on pyrolysis, with copolymer composition controlling polymer structure, char yield, and ceramic stoichiometry and morphology. Polysilsesquioxanes which are synthesized readily and can be handled in air serve as precursors to Si-C-O ceramics. Copolymers of phenyl and methyl silsesquioxanes display rheological properties favorable for composite fabrication; these can be tailored by control of pH, water/methoxy ratio and copolymer composition. Composites obtained from these utilize a carbon coated, eight harness satin weave Nicalon cloth reinforcement. The material exhibits nonlinear stress-strain behavior in tension

Far-UV Observations of NGC 4151 during the ORFEUS-SPAS II Mission

We observed the Seyfert 1 galaxy NGC 4151 on eleven occasions at 1-2 day intervals using the Berkeley spectrometer during the ORFEUS-SPAS II mission in 1996 November. The mean spectrum covers 912-1220 A at ~0.3 A resolution with a total exposure of 15,658 seconds. The mean flux at 1000 A was 4.7e-13 erg/cm^2/s/A. We identify the neutral hydrogen absorption with a number of components that correspond to the velocity distribution of \ion{H}{1} seen in our own Galaxy as well as features identified in the CIV 1549 absorption profile by Weymann et al. The main component of neutral hydrogen in NGC 4151 has a total column density of log N_HI = 18.7 +/- 1.5 cm^{-2} for a Doppler parameter b=250 +/- 50 km/s, and it covers 84 +/- 6% of the source. This is consistent with previous results obtained with the Hopkins Ultraviolet Telescope. Other intrinsic far-UV absorption features are not resolved, but the CIII* 1176 absorption line has a significantly higher blueshift relative to NGC 4151 than the CIII 977 resonance line. This implies that the highest velocity region of the outflowing gas has the highest density. Variations in the equivalent width of the CIII* 1176 absorption line anticorrelate with continuum variations on timescales of days. For an ionization timescale <1 day, we set an upper limit of 25 pc on the distance of the absorbing gas from the central source. The OVI 1034 and HeII 1085 emission lines also vary on timescales of 1-2 days, but their response to the continuum variations is complex. For some continuum variations they show no response, while for others the response is instantaneous to the limit of our sampling interval.Comment: 4 pages, 2 PostScript figures, uses emulateapj.sty, apjfonts.sty. To appear in the Astrophysical Journal (Letters) special issue for ORFEU

Bypass of a protein roadblock by a replicative DNA helicase

Replicative DNA helicases generally unwind DNA as a single hexamer that encircles and translocates along one strand of the duplex while excluding the complementary strand (“steric exclusion”). In contrast, large T antigen (T-ag), the replicative DNA helicase of the Simian Virus 40 (SV40), is reported to function as a pair of stacked hexamers that pumps double-stranded DNA through its central channel while laterally extruding single-stranded DNA. Here, we use single-molecule and ensemble assays to show that T-ag assembled on the SV40 origin unwinds DNA efficiently as a single hexamer that translocates on single-stranded DNA in the 3′ to 5′ direction. Unexpectedly, T-ag unwinds DNA past a DNA-protein crosslink on the translocation strand, suggesting that the T-ag ring can open to bypass bulky adducts. Together, our data underscore the profound conservation among replicative helicase mechanisms while revealing a new level of plasticity in their interactions with DNA damage

Polarization of tightly focused laser beams

The polarization properties of monochromatic light beams are studied. In contrast to the idealization of an electromagnetic plane wave, finite beams which are everywhere linearly polarized in the same direction do not exist. Neither do beams which are everywhere circularly polarized in a fixed plane. It is also shown that transversely finite beams cannot be purely transverse in both their electric and magnetic vectors, and that their electromagnetic energy travels at less than c. The electric and magnetic fields in an electromagnetic beam have different polarization properties in general, but there exists a class of steady beams in which the electric and magnetic polarizations are the same (and in which energy density and energy flux are independent of time). Examples are given of exactly and approximately linearly polarized beams, and of approximately circularly polarized beams.Comment: 9 pages, 6 figure

Towards cloud based big data analytics for smart future cities

© 2015, Khan et al.; licensee Springer. A large amount of land-use, environment, socio-economic, energy and transport data is generated in cities. An integrated perspective of managing and analysing such big data can answer a number of science, policy, planning, governance and business questions and support decision making in enabling a smarter environment. This paper presents a theoretical and experimental perspective on the smart cities focused big data management and analysis by proposing a cloud-based analytics service. A prototype has been designed and developed to demonstrate the effectiveness of the analytics service for big data analysis. The prototype has been implemented using Hadoop and Spark and the results are compared. The service analyses the Bristol Open data by identifying correlations between selected urban environment indicators. Experiments are performed using Hadoop and Spark and results are presented in this paper. The data pertaining to quality of life mainly crime and safety & economy and employment was analysed from the data catalogue to measure the indicators spread over years to assess positive and negative trends

Induced measures in the space of mixed quantum states

We analyze several product measures in the space of mixed quantum states. In particular we study measures induced by the operation of partial tracing. The natural, rotationally invariant measure on the set of all pure states of a N x K composite system, induces a unique measure in the space of N x N mixed states (or in the space of K x K mixed states, if the reduction takes place with respect to the first subsystem). For K=N the induced measure is equal to the Hilbert-Schmidt measure, which is shown to coincide with the measure induced by singular values of non-Hermitian random Gaussian matrices pertaining to the Ginibre ensemble. We compute several averages with respect to this measure and show that the mean entanglement of $N \times N$ pure states behaves as lnN-1/2.Comment: 12 latex pages, 2 figures in epsf, submited to J. Phys. A. ver.3, some improvements and a few references adde

Inhibition of Nucleotide Excision Repair by the Cyclin-dependent Kinase Inhibitor p21

p21, a p53-induced gene product that blocks cell cycle progression at the G1 phase, interacts with both cyclin-dependent kinases and proliferating cell nuclear antigen (PCNA). PCNA functions as a processivity factor for DNA polymerases delta and epsilon and is required for both DNA replication and nucleotide excision repair. Previous studies have shown that p21 inhibits simian virus 40 (SV40) DNA replication in HeLa cell extracts by interacting with PCNA. In this report we show that p21 blocks nucleotide excision repair of DNA that has been damaged by either ultraviolet radiation or alkylating agents, and that this inhibition can be reversed following addition of PCNA. We have determined that p21 is more effective in blocking DNA resynthesis than in inhibiting the excision step. We further show that a peptide derived from the carboxyl terminus of p21, which specifically interacts with PCNA, inhibits polymerase delta-catalyzed elongation of DNA chains almost stoichiometrically relative to the concentration of PCNA. When added at higher levels, this peptide also blocks both SV40 DNA replication and nucleotide excision repair in HeLa cell extracts. These results indicate that p21 interferes with the function of PCNA in both in vitro DNA replication and nucleotide excision repair